基于Blowfish和MD5的混合加密方案*

针对Blowfish算法在实际应用中存在的等价密钥、重复初始化等问题,提出Blowfish与MD5算法相结合,将MD5算法的生成值作为密钥的一部分对Blowfish算法进行初始化,使用概率统计方法证明该方案弥补了Blowfish算法的实际应用缺陷。计算结果表明,混合加密方案具有更高的安全性、更快的速度。     

新型醋酸乙烯聚合引发剂的研究

采用新型引发剂过氧化二月桂酰对醋酸乙烯聚合进行研究,通过研究它在聚合过程中的分解速率常数、半衰期等性能,得出过氧化二月桂酰的分解速率常数大,半衰期与偶氮二异丁腈相似,并且产物不含有毒物质,因此它的应用范围可以更加广泛。讨论了引发剂质量、甲醇质量、反应时间对醋酸乙烯转化率和聚合度的影响。建立正交试验得到醋酸乙烯聚合的最佳工艺条件。     

西南某水电站厂房上游侧后坡变形体稳定性研究

电站厂房上游侧后坡受施工排水、边坡开挖等综合因素的影响,形成了规模巨大的变形体,其稳定性直接威胁了厂址的安全,为此对变形体进行了地质钻探、物探、地面三维变形监测和稳定性计算等研究.结果表明:变形体为整体推移式、局部牵引式的蠕变滑移;从成因和机理分析,施工排水和降雨是诱发形成的最主要因素;其天然稳定性随着降雨量的变化而呈周期性变化,雨季的稳定性差,旱季有所提高,但在饱水或地震条件下,存在失稳的可能.     

扭断盖滚压封口机滚压封口设计

研究了扭断盖滚压封口机的滚压封口部分,参考了目前市场上使用的扭断盖滚压封口机,并提出了改进意见。     

复杂网络上的动态传播

采用一种新的方法来研究文化传播,结合动力学和复杂网络的知识对文化在不同结构社区中的传播做了数值仿真和分析。发现文化的传播速度在随机结构,BA结构,小世界结构和规则结构的社区中依次减慢,且核心人物对BA结构社区中的文化传播起着重要的作用。     

Degradation of p-nitrotoluene by 03/H2 02 process and oxidation mechanism

The degradation of p-nitrotoluene by O2/H2O2 process in a bubble contact column was investigated.Effects of the molar ratio of hydrogen peroxide to ozone, pH value and t-butanol on the oxidation process were discussed. It was found that the proper H2 O2/O3 molar ratio for the degradation of p-nitrotoluene was around O. 6, different pH values and the presence of t-butanol highly influenced the removal efficiency of p-nitrotoluene. 5-metbyl-2-nitrophenol, 2-methy1-5-nitrophenol, (4-nitrophenyl) methanol, 5-(hydroxymethyl) -2-nitro phenol, acetic acid, 2-methylpropanc diacid and 2-(hydroxylmethyl) propane diacid were identified as degradation intermediates and products through GC-MS. Radical reaction mechanism and degradation pathway were proposed based on the results of experiments. It is deduced that the benzene ring of p-nitrotoluene can be only destroyed by hydroxyl radicals through a polyhydrexy intermediate pathway. Then unstable polybydroxy intermediates can be oxidized to different acids with low molecular weight rapidly.     

Degradation of p-nitrotoluene by O3/H2O2 process and oxidation mechanism

The degradation of p-nitrotoluene by O3/H2O2 process in a bubble contact column was investigated. Effects of the molar ratio of hydrogen peroxide to ozone,pH value and t-butanol on the oxidation process were discussed. It was found that the proper H2O2/O3 molar ratio for the degradation of p-nitrotoluene was around 0.6, different pH values and the presence of t-butanol highly influenced the removal efficiency of p-nitrotoluene. 5-methyl-2-nitrophenol, 2-methyl-5-nitrophenol, (4-nitrophenyl) methanol, 5-(hydroxymethyl)-2-nitro phenol, acetic acid, 2-methylpropane diacid and 2-(hydroxylmethyl)propane diacid were identified as degradation intermediates and products through GC-MS. Radical reaction mechanism and degradation pathway were proposed based on the results of experiments. It is deduced that the benzene ring of p-nitrotoluene can be only destroyed by hydroxyl radicals through a polyhydroxy intermediate pathway. Then unstable polyhydroxy intermediates can be oxidized to different acids with low molecular weight rapidly.     

一种多元复合地基复合模量的计算方法

多元复合地基的沉降计算依赖于其复合模量的取值.目前多元复合地基复合模量计算均未考虑桩对桩间土的侧向挤密作用,因而其沉降计算结果与实际值相差较大.而考虑桩体与桩间土的侧向挤压作用,依据线弹性变形理论,推求的多元复合地基的复合模量公式应用于工程实例,结果表明,该方法是合理可行的,并且存在着参数易于确定、方法简便、机理清楚的特点.     

HPFL加固空斗墙砌体抗压强度试验研究

高性能水泥复合砂浆钢筋网薄层(HPFL)加固法是一种新型的结构加固补强技术.通过2组对比试件和3组加固试件在分级加载下的轴压试验,研究了HPFL对空斗墙砌体的抗压加固效果.实验结果表明,单面加固极限承载力提高41.7%,双面加固不仅极限承载力提高50%~53.8%,开裂荷载也提高约21.3%~27%.笔者通过实验数据拟合了空斗墙受压应力-应变曲线,并提出HPFL加固空斗墙砌体承载力计算方法,供加固设计时参考.     

新型分子筛脱除钙离子的热力学研究

实验测定了新型分子筛对钙离子的全交换容量及25℃、50℃、75℃下离子交换平衡数据.依据实验数据,绘制了Na+-Ca2+离子交换等温线以及Kielland图,计算出了该过程的焓变化,吉布斯自由能和熵变化.研究表明该新型分子筛Na+-Ca2+离子交换过程可用Langmuir吸附等温式很好的描述,且该过程为吸热反应,可自发进行,高温有利于钙离子的交换.