Thermal stabilization effect of biphenol monoacrylate on polyamide 6

Biphenol monoacrylate (AL) was combined with a traditional hindered phenolic‐based binary antioxidant system to form a ternary stabilization system for the purpose of further improving the thermal–oxidative stability of polyamide 6 (PA6). The thermal stabilization effect of the antioxidant AL on PA6 was studied in terms of the reduced viscosity, the chemical structure, the yellow index, and the mechanical properties. The results showed that the antioxidant AL, with the proper chemical structure, could improve the thermal stability of PA6 effectively through a unique bifunctional stabilizing mechanism. The interaction of the molecules of PA6 with the antioxidant AL was investigated. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Synthesis and characterization of a novel proton‐exchange membrane for fuel cells operating at high temperatures and low humidities

The synthesis of a p‐toluidine/formaldehyde (PTF) resin was performed, and the effects of the molar ratio of the individual monomers and the polymerization conditions on the structure of the PTF resin were studied. Fourier transform infrared and ¹³C‐NMR spectra were used to characterize the PTF. Wide‐angle X‐ray diffraction patterns revealed the crystalline structures of various PTFs. Polarized optical microscopy revealed that the molar ratio of the monomers had a strong effect on the crystalline morphologies. A longer polymerization time turned out a polymer with a higher intrinsic viscosity and molecular weight, which led to differences in the proton conductivity. All of the PTFs showed a higher proton conductivity than a commercial Nafion membrane at 90–100°C and 0% relative humidity. The proton conductivity of the PTF series could be improved by sulfonation with sulfuric acid and could be maintained after blending with polyurethane. Pure methanol could be used as a fuel source because of the insolubility and nonwetting properties of PTF in methanol to increase the output current density for a PTF membrane electrode assembly. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Polysaccharide‐based artificial extracellular matrix: Preparation and characterization of three‐dimensional,macroporous chitosan,and heparin composite scaffold

Scaffold‐guided tissue engineering based on synthetic and natural occurring polymers has gained many interests in recent year. In this study, the development of a chitosan‐heparin artificial extracellular matrix (AECM) is reported. Three‐dimensional, macroporous composite AECMs composed of heparin (Hep) and chitosan (Chito) were prepared by an interpolyelectrolyte complex/lyophilization method. The Chito‐Hep composite AECMs were, respectively, crosslinked with glutaraldehyde, as well as cocrosslinked with N,N‐(3‐dimethylaminopropyl)‐N′‐ethyl carbodiimide (EDC/NHS) and N‐hydroxysuccinimide (NHS). The crosslinking reactions were examined by FT‐IR analysis. In physiological buffer solution (PBS), the EDC/NHS‐crosslinked Chito‐Hep composite AECM showed a relative lower water retention ratio than its glutaraldehyde‐crosslinked counterparts. The EDC/NHS‐crosslinked Chito‐Hep composite AECMs showed excellent biocompatibility, according to the results of the in vitro cytotoxic test. This result suggested that the EDC/NHS‐crosslinked Chito‐Hep composite AECMs might be a potential biomaterial for scaffold‐guided tissue engineering applications. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

TbFe磁性薄膜的磁力显微镜成像研究

利用磁力显微镜（MFM）对TbFe磁性薄膜进行了不同抬举距离（分别为60～780nm）的磁力成像研究．在实验中，比较了低抬举距离（100nm以下）磁力像中样品-针尖的互相干扰；同时发现在高抬举距离磁力像中，随着抬举距离的增大，出现了与高凸起形貌对应的图像衬度特征，并随抬举距离的变化也改变着位置与强度，一直到抬举距离为仪器的极限值780nm时，形貌干扰仍未消失，对其形成机制进行了分析．     

Flammability ranking of foliage species by factor analysis of physical and chemical pyric properties

In this paper, factor analysis is introduced to evaluate the flammability of 55 foliage species that may be used in China for construction of the fuel break network of forest strips with lower flammability. Six pyric parameters, i.e. air dry moisture content, absolute dry moisture content, ignition point, ash content, caloric value and extractive content, are measured and used as variables for factor analysis. The covariance analysis shows that four principal factors can be extracted to reflect the flammability in different physical and chemical senses. In terms of the contributions of the four factors to the variances and the physical significance of the relevant parameters, the four factors are, respectively, termed as ‘flaming factor,’ ‘air dry factor,’ ‘ash factor’ and ‘absolute dry factor.’ The stability of the factor analysis method is examined by a different number of samples considered, and the variation degrees of the orderings indicate that the method has high reliability to measure the total flammability of foliage species. The results of the flammability evaluation are verified by comparison with the recommended tree species in the Chinese technology standard. Copyright © 2008 John Wiley & Sons, Ltd.     

港口起重机风灾事故的防范

介绍了港口起重机所受风害的种类及其设防情况,分析了起重机结构形式与风作用的关系。介绍了上海国际港务(集团)有限公司几种常用的大型起重机防风装置的原理、功效及检测情况。     

Km高温抗蚀耐磨涂料在省煤器中的应用

锅炉省煤器磨损一直是困绕锅炉稳定运行的主要因素之一。本介绍了Km高温抗蚀耐磨涂料的性能、特点，以及在实际生产中的使用情况，通过实践充分肯定了Km高温抗蚀耐磨涂料的可行性、可靠性和经济性。     

反应温度对聚苯胺薄膜生长的影响

在不同反应温度条件下采用原位聚合法在石英基片上制备了聚苯胺薄膜．对薄膜样品进行了紫外光谱、SEM、电性能表征。实验结果表明，过高的合成温度会加速聚合反应过程，抑制膜厚的增长，引起薄膜的热降解，进而对样品的导电性产生不良影响。根据生长速率与合成温度的依赖关系，估算了聚合反应的活化能Ea=34.4kJ/mol。     

西南油气田建设用地面临的困难及其对策

从四川盆地油气勘探开发建设用地特点入手,分析了西南油气田用地现状和新形势下油气勘探开发建设用地在保证工期、控制成本、提高效率、政策支持、关系协调等方面所面临的挑战,提出了下一步为保证生产建设用地按时、有效、科学、合理、合法的取得而应采取的有效措施。