The multiphase effect on crystal structure, hydrogen absorbing properties and electrode performance of Sc---Zr based Laves phase alloys

The crystal structure, hydrogen absorbing properties and electrode performance of Laves phase alloy systems, Sc---Zr---Ni---Mn and Sc---Ni---V systems, were studied by optical and scanning electron microscopy, X-ray powder diffraction, pressure-composition isotherm and electrochemical measurements. C14 and C15 Laves phases and minor ScNi-related phase were found in the Sc---Zr---Ni---Mn alloy system. The ScNi-related phase was composed of Sc, Zr and Ni elements. Two kinds of minor phase, BCC and ScNi-related phases, were identified in addition to the C15 phase in the Sc---Zr---Ni---V alloy system. The BCC contained mainly the element V. The ScNi-related phase contributed to an increase in the hydrogen capacity, but those in the V alloy system did not. The multiphase anode with a large amount of the ScNi-related phase showed a low durability against the KOH electrolyte. The substitution of Zr by Sc led to an improvement in the initial activation of the anode, but there was not a clear correlation between the presence of the multiphase in the anode and the rate capability.     

High-power hybrid plasma spraying of large yttria-stabilized zirconia powder

To testify to the advantage of large ceramic powder spraying, numerical simulations and experimental studies on the behavior of large yttria-stabilized zirconia (YSZ) powder in a high-power hybrid plasma spraying process have been carried out. Numeric predictions and experimental results showed that, with the high radio frequency (RF) input power of 100 kW, the most refractory YSZ powder with particle sizes as large as 88 μm could be fully melted and well-flattened splats could be formed. A large degree of flattening (ξ) of 4.7 has been achieved. The improved adhesive strength between the large splat and the substrate was confirmed based on the measurement of the crack density inside of the splats. A thick YSZ coating >300 μm was successfully deposited on a large CoNiCrAlY-coated Inconel substrate (50×50×4 mm in size). The ultradense microstructure without clear boundaries between the splats and the clean and crack-free interface between the top-coat and the bond-coat also indicate the good adhesion. These results showed that highpower hybrid plasma spraying of large ceramic powder is a very promising process for deposition of highquality coatings, especially in the application of thermal barrier coatings (TBCs).     

Measurement of self-diffusion coefficients in Li ionic conductors by using the short-lived radiotracer of 8Li

For the effective use of short-lived radioactive beams, soon to be available at the Tokai Radioactive Ion Accelerator Complex, the authors have developed a radiotracer method for diffusion studies in solids. The experimental test was performed by the measurement of the diffusion coefficients of Li in a sample of the compound βLiAl using an α-emitting radiotracer of ⁸Li (T_1/2=0.84 s). It was found that the time-dependent yields of the α particles from the diffusing ⁸Li that was initially implanted in the sample could be used as a measure of the diffusivity of the tracer in a nondestructive way. The method was applied to measure the self-diffusion coefficients of Li in βLiGa, and for investigating how the Li diffusion in the Li ionic conductors is affected by the concentration of atomic defects (i.e., the existence of the atomic vacancies of Li and the defects in Ga sites that are replaced by Li).     

Lyapunov-based feedback design and experimental verification of IC engine speed control

In this paper, the speed control problem of internal combustion engines is investigated based on mean-value engine models. The dynamics of internal combustion engines is a complicated nonlinear system, and usually, it is difficult to know the exact values of the physical parameters. First, a Lyapunov-based design method is shown without requiring the full information of the physical parameters. Then, to improve transient performance, the design method is extended to several cases under different operation conditions. Numerical simulation results are presented for comparing the proposed design methods. Finally, experiments are conducted on an engine test bench and the results demonstrate the validity of the proposed design methods. Recommended by Editorial Board member Myotaeg Lim under the direction of Editor Hyun Seok Yang. The authors are grateful to Kai Zheng for his assistance of the model identification experiments. Jiangyan Zhang received the B.E. and M.E. degrees in Electrical Engineering, Yanshan University, China, in 2005 and 2008, respectively. Now, she is a Ph.D. candidate with the Department of Engineering and Applied Sciences, Sophia University, Tokyo, Japan. Her current research interests include nonlinear system control theory and applications to powertrain system control. Tielong Shen received the Ph.D. degree in Mechanical Engineering from Sophia University, Tokyo, Japan, March, 1992. From April 1992, he has been a faculty member of the Chair of Control Engineering in Department of Mechanical Engineering, Sophia University, where he currently serves as professor of the Department of Engineering and Applied Science. His research interests include control theory and application in mechanical systems, power systems, and automotive powertrain. Currently, he is an Associate Editor for the IEEE Control System Society Conference Editorial Board, and is serving as Associate Editor of Journal of Control Theory and Applications, and the Regional Editor Asia-Pacific for International Journal of Modeling, Identification and Control etc. Junichi Kako received the B.E. degree from Nagoya Institute of Technology, Nagoya, Japan. He joined Toyota Motor Corporation, Tokyo, Japan in 1989. He worked on various aspects of automotive powertrain control. From 1989 to 1994, he took part in the team for the development of Laboratory Automation (LA) system, Engineering Office Automation (EOD) system, and embedded system of powertrain control. During 1995–2001, he focused on the engine control systems in Powertrain Management Engineering Division. In 2002, he was with Future Project Division in which he was responsible for the R&D of model-based engine control system. Currently, he is developing engine control systems in the Powertrain Management Engineering Division, Toyota Motor Corporation. Shozo Yoshida received the M.S. degree in Engineering from Kyoto University, Kyoto, Japan. He joined Toyota Motor Corporation, Tokyo, Japan in 2000. From 2000 to 2004, he was with Future Project Division and worked on physical combustion modeling for Model-based Control Development. Since 2005, he has been with the Powertrain Management Engineering Division Toyota Motor Corporation, and is a member of the R&D of Model-based Engine Calibration.     

Development of an epileptic seizure prediction algorithm using R–R intervals with self-attentive autoencoder

Epilepsy is a neurological disorder that may affect the autonomic nervous system (ANS) from 15 to 20 min before seizure onset, and disturbances of ANS affect R–R intervals (RRI) on an electrocardiogram (ECG). This study aims to develop a machine learning algorithm for predicting focal epileptic seizures by monitoring R–R interval (RRI) data in real time. The developed algorithm adopts a self-attentive autoencoder (SA-AE), which is a neural network for time-series data. The results of applying the developed seizure prediction algorithm to clinical data demonstrated that it functioned well in most patients; however, false positives (FPs) occurred in specific participants. In a future work, we will investigate the causes of FPs and optimize the developing seizure prediction algorithm to further improve performance using newly added clinical data.

     

Revolving Vernier Mechanism Controls Size of Linear Homomultimer

A new kind of the Vernier mechanism that is able to control the size of linear assembly of DNA origami nanostructures is proposed. The mechanism is realized by mechanical design of DNA origami, which consists of a hollow cylinder and a rotatable shaft in it connected through the same scaffold. This nanostructure stacks with each other by the shape complementarity at its top and bottom surfaces of the cylinder, while the number of stacking is limited by twisting angle of the shaft. Experiments have shown that the size distribution of multimeric assembly of the origami depends on the twisting angle of the shaft; the average lengths of the multimer are decamer, hexamer, and tetramer for 0°, 10°, and 20° twist, respectively. In summary, it is possible to affect the number of polymerization by adjusting the precise shape and movability of a molecular structure.     

CD63, a member of tetraspan transmembrane protein family, induces cellular spreading by reaction with monoclonal antibody on substrata

We cloned mouse LOX-1 cDNA to take advantage of a gene-targeting technique to clarify the role of LOX-1 in vivo. Mouse LOX-1 was composed of 363 amino acids and had a C-type lectin domain type II membrane protein structure. Mouse LOX-1 had triple repeats of the sequence in the extracellular "Neck domain," which is unlike human and bovine LOX-1. LOX-1 bound oxidized LDL with two classes of binding affinity in the presence of serum. The binding component with the higher affinity showed the lowest value of Kd among the known receptors for oxidized LDL. In the absence of serum, the high affinity component disappeared, suggesting that an unknown co-factor in serum is essential for efficient uptake of oxidized LDL by endothelial cells. A low concentration of unlabeled oxidized LDL displaced 125I-labeled oxidized LDL more efficiently in the presence of serum than in the absence of serum. The co-factor in the serum may be involved in the pathophysiology of atherosclerosis in addition to the oxidation of LDL.     

Relationship of occupation to blood pressure among middle-aged Japanese men--the significance of the differences in body mass index and alcohol consumption

To clarify how and why blood pressure differs between occupations, the proportions of hypertensives, and the measures of blood pressure, body mass index (BMI) and alcohol consumption among the individuals not taking antihypertensive drugs were compared between the eight occupational categories using the data from a health check-up for 589 middle-aged Japanese males, mostly randomly selected from five areas in Japan. After adjusting for age, the relationships of occupation to the proportion of hypertensives and the mean systolic and diastolic blood pressure substantially differed among the five areas. However, after further adjustment for residence, these blood pressure levels (the proportion of hypertensives, and the mean systolic and diastolic blood pressure) were found to be higher for the "Personnel in transport and communications", the "Clerical personnel", the "Managerial and civil personnel" and the "Professional and technical personnel", whereas these values were consistently lowest in the "Service personnel". Age and residence-adjusted mean BMI was also higher for the four occupational categories with the increased blood pressure levels. According to a weighted multiple regression analysis across the eight occupations, the age and residence-adjusted mean BMI was a significant predictor of the age and residence-adjusted mean systolic and diastolic blood pressure (p = 0.068 and 0.018, respectively). These results suggest that the occupation-related changes in BMI may largely contribute to the occupation-related changes in blood pressure.