Effect of operating conditions in removal of arsenic from water by nanofiltration membrane

The removal of arsenic from synthetic waters and surface water by nanofiltration (NF) membrane was investigated. In synthetic solutions, arsenic rejection experiments included variation of arsenic retentate concentration, transmembrane pressure, crossflow velocity and temperature. Arsenic rejection increased with arsenic retentate concentration. Arsenic was removed 93-99% from synthetic feed waters containing between 100 and 382 μg/L as V, resulting in permeate arsenic concentrations of about 5 μg/L. Under studied conditions, arsenic rejection was independent of transmembrane pressure, crossflow velocity and temperature. In surface water, the mean rejection of As V was 95% while the rejection of sulfate was 97%. The co-occurrence of dissolved inorganics does not significantly influence arsenic rejection. The mean concentration of As in collected permeated was 8 μg/L. The mean rejection of TDS, total hardness and conductivity were 75, 88 and 75% respectively.     

Optimization of PACl dose to reduce RO cleaning in an IMS

In order to ensure stable treated water quality and to reduce chemical costs in any treatment plant it is necessary to study and optimize the coagulant dosing control (CDC). This research focused on the affects of coagulant in the integrated membrane (UF & RO) system employed for industrial water production. The dose of coagulant (PACl) might be associated (partly) with the frequency of cleaning in the RO units, and a value of 20 abs/m in the UF permeate is the control of the dosage process. This could suggest that organic fouling is directly and indirectly (inducing biofouling as well) the cause of fouling of the RO membranes. Nevertheless, high doses of PACl could produce scaling of aluminium and, in this work minimizing PACl to prevent operational problems in RO membranes was focused.

The approach involved the study of the treatment processes, determination of the optimum dose of coagulant, evaluation of the removal efficiency of UV and DOC by coagulation. The available data, which comprised monthly/weekly measurements for a period of six years of operation, was studied and analyzed and an attempt was made to draw some conclusions for the plant regarding the coagulant dosage and the link with UV absorbance as control.

The study of the coagulant dosing control revealed that the use of simple and robust online sensors like UV measurement allows an automatic dosing control although this parameter is not found to be sufficient to fully characterize nor predict fouling during membrane operation and there is no link between UV after the UF and the cleaning frequency of the RO. Parameters, as the added value allowed to verify the doses efficiencies in UV and DOC removal. Coagulant dose depends on the level of UV absorbance in the UF permeate and it should never be higher than 20 abs/m to ensure a RO cleaning frequency as long as possible. However, it was found that the target value of 20 abs/m produced substantial over dose of coagulant — 90% of the time – when UV removal is considered only. In the same way, for coagulant doses in excess of 5 mg/L, the additional removal of UV is less than 2.5% per mg coagulant/L, which suggests that the current dose is on the high side.

Furthermore, a coagulant dose in excess of 5 mg/L did not produce significant additional UV removal, and thus a reduction from 14 mg/L (2005 dose) to ca. 7 mg/L could be considered.     

Measurement of local specific interfacial area in bubble columns via a non-isokinetic withdrawal method coupled to electro-optical detector

Precise measurement of gas-liquid interfacial surface area is essential to reactor design and operation. Mass transfer from the gas phase to the liquid phase is often a key feature that controls the overall process. Measurement of gas-liquid interfacial area is often made through a separate measurement of the gas holdup and bubble size with complex and/or sophisticated methods. In this work, an inexpensive method is presented for the simultaneous determination of both local gas holdup and bubble diameter. The method is based on the withdrawal of the air-liquid dispersion under non-isokinetic conditions and on bubble counting via a simple optical device. The method was calibrated in a bubble column with several withdrawal pressures using coalescing and non-coalescing media. During the same calibration experiment, gas holdup was also measured manometrically and individual bubble diameters were measured by a photographic method. With a vacuum pressure of 3 kPa, local interfacial area measured with the withdrawal method produced a relative error below 13%, compared to the manometric/photographic method. The method was then used to characterize local specific interfacial area in a bubble column under several operating conditions with coalescing and non-coalescing media. In coalescing media and with superficial gas velocities (v_g) from 0.25 to 3.5 cm/s, the average interfacial area ranged from 17 to . With non-coalescing media the average interfacial area ranged from 40 to . Under the test condition it was observed that gas holdup is a parameter that has a greater distribution (standard deviation from 30% to 70%) than the volume-mean bubble diameter (standard deviation from 6% to 12%). It is shown that a model previously developed for characterizing gas holdup homogeneity is also suitable for characterizing interfacial area homogeneity.     

Examination of organic coatings on metallic substrates by scanning electrochemical microscopy in feedback mode: Revealing the early stages of coating breakdown in corrosive environments

Scanning electrochemical microscopy in feedback mode was used to monitor changes in the surface state of a polymeric film applied on a metallic substrate when exposed to an aqueous electrolytic environment. The protected metal consisted of a carbon steel substrate coated with a polyurethane-based polymeric film. SECM measurements performed in the presence and absence of chloride anions permitted a specific effect caused by Cl⁻ anions at early exposures to be detected. Significant surface roughening is observed for immersion times shorter than 1 day when the electrolyte contains chloride ions. Additionally, the growth of an individual blister could also be investigated.     

The Social Sustainable Aquifer Yield: An Indicator for the Analysis and Assessment of the Integrated Aquifers Management

Integrated Aquifers Management (IAM) demands innovative tools and methods that are able to consider as much perspectives as possible. This research is aimed to design, apply and provide an indicator named Social Sustainable Aquifer Yield (SSAY), expressed in units of time that includes pure hydrological variables as well as social ones. The indicator is defined as the relation between the Residence Time, which is the relation between aquifer Storage (S) and Recharge (R) (S/R), and the relation between the aquifer Pumping (P) and the new variable named Aquifer Social Yield (ASY). The whole indicator is defined by this formula: (S/R)/(P/ASY). The assessment of the residence time is essential in aquifers with at least one of the following features: i) high hydraulic diffusivity, and ii) small volume of reserves. Finally, the variable ASY is defined as the average perception from the stakeholders about the maximum acceptable aquifer exploitation. This indicator has been successfully applied in the aquifers located in southern Jaen province (South Spain) belonging to the Water System SE4-Jaén Water Supply. The results probe the high utility of the indicator, especially in regards to the public participation processes.     

Power consumption reduction through elastic data rate adaptation in survivable multi-layer optical networks

Network survivability requires the provisioning of backup resources in order to protect active traffic against any failure scenario. Backup resources, however, can remain unused most of the time while the network is not in failure condition, inducing high power consumption wastage, if fully powered on. In this paper, we highlight the power consumption wastage of the additional resources for survivability in IP/multi-protocol label switching (MPLS) over dense wavelength division multiplexing multi-layer optical networks. We assume MPLS protection switching as the failure recovery mechanism in the network, a solution interesting for current network operators to ensure fast recovery as well as fine-grained recovery treatment per label switched path. Next, we quantitatively show how elastic optical technologies can effectively reduce such a power consumption by dynamically adjusting the data rate of the transponders to the carried amount of traffic.     

Optimized Prototype Filter Based on the FRM Approach for Cosine-Modulated Filter Banks

A design procedure for frequency-response masking (FRM) prototype filters of cosine-modulated filter banks (CMFBs) is proposed. In the given method, we perform minimization of the maximum attenuation level in the filters stopband, subject to intersymbol interference (ISI) and intercarrier interference (ICI) constraints. For optimization, a quasi-Newton algorithm with line search is used, and we provide simplified analytical expressions to impose the interference constraints, which greatly reduce the computational complexity of the optimization procedure. The result is lower levels of ISI and ICI for a predetermined filter order, or a reduced filter complexity for given levels of interferences. It is then illustrated how the FRM-CMFB structure is suitable for implementing filter banks with a large number of bands, yielding sharp transition bands and small roll-off factors, which is an attractive feature for a wide range of practical applications.     

A linearized model for estimating the performance of submerged resonant wave energy converters

A realistic performance analysis of oscillating water column wave energy converters (WECs) addresses to a set of non-linear differential equations that need to be integrated in time, by using a stochastic approach, under the hypothesis of random wind-generated sea waves, for all the sea states which characterize the location of the system. Non-linearities of the differential equations have several origins:

• minor and major losses of the unsteady flow of water and air;

• compressibility of air and heat exchange with the walls of the air chamber;

• non-linear characteristics of the turbine.

Under the hypothesis of random sea waves with Gaussian distribution, the authors propose an original methodology for linearizing the differential equations that describe the flow motion inside a wholly submerged WEC. Under such hypothesis, the linearized model can be used for predicting the power output by means of the calculations in the frequency domain and for control design. The developed methodology has been applied to the estimation of the performance of the new “resonant sea wave energy converters”, called REWEC, patented by Boccotti in 1998, and consisting of several caissons, characterized by a structure similar to the caissons of the traditional breakwaters and placed on the seabed, close one to each other, to form a submerged breakwater. Each caisson is connected to a vertical duct wholly beneath the sea level, where a hydraulic Wells turbine is placed.The matching between turbine and resonance characteristic of the system is carefully analysed in order to maximize the energy conversion efficiency.Some results, given for a small installation in the Mediterranean sea, confirm that the REWEC system is able to absorb a large share of the incident wave energy due to a very simple regulation system which permits the tuning on sea states with different significant heights.     

Numerical Simulation of Matrix Reinforced Composite Materials Subjected to Compression Loads

This paper reviews the most common formulations to obtain the compression strength of long fiber composites due to fiber buckling. This failure mode was first studied by Rosen (Fibre Composite Materials, pp. 37–45, 1965) who defined two different fiber buckling modes, extensional and transverse. Further studies improved the first model proposed by Rosen by defining with more accuracy the mechanics of the problem. Although each formulation use a different approach to solve the problem, all of them agree in the dependence of fiber buckling on three main parameters: matrix shear strength, fiber initial misalignments and volumetric participation of the fibers in the composite. Once having described the different approaches used, and the parameters on which they depend, this paper describes a new formulation capable of obtaining the compression strength of composites taking into account the fiber buckling phenomenon. This formulation uses the serial/parallel mixing theory developed by Rastellini et al. (Comput. Struct. 86(9):879–896, 2008) to simulate the composite, and takes advantage of knowing the mechanical performance of the composite constituents to simulate the fiber buckling phenomenon. This is done with an homogenization procedure. It consists in introducing the interaction between fibers and matrix into their respective constitutive equations. The interaction between fiber and matrix takes into account fiber initial misalignments, its volumetric participation and the mechanical properties of both constituents.