EXTRACTION OF Zn AND Cd FROM CHLORIDE LIQUORS BY TRI-n-BUTYL PHOSPHATE

Studies have been made on the extraction of Zn and Cd by TBP(tri-n-butyl phosphate)from diluent hydrochloric acid solutions of soldium chloride.The experiments show that thespecies extracted from diluent HCI solutions of NaCl appear to be predominantly ZnCl_2·2TBP and CdCl_2·2TBP.For Cd,at lower acidities,anionic complexes of the typeH_2CdCl_3 are also extracted.As the acidity is increased,H_2CdCl_4 appear to be predominantcomplexes in organic phase.For Zn,the acidocomplexes of the type HZnCl_3 appear in organ-ic phase after the acidity of solutions reaching a certain value([HCl]>0.1 mol/L).Furthermore,the ultraviolet absorption spectra of both aqueous and organic phases have beenstudied,and the infrared spectra of the organic phases have been exomined.The extractionmechanism and temperature effect are also discussed.     

Fe-B基微晶材料晶粒大小与高温硬度的关系SCIEI

本文对Fe-B基微晶材料的反玻璃化热处理条件,组织精细程度和硬度(HV_(RT),HV_(500℃),HV_(600℃))三者之间关系作了系统的研究。在晶粒尺寸不太小时,HV与d^(-1/2)呈直线关系,但在超细晶粒尺寸时,直线发生偏离。     

DYNAMIC MECHANICAL BEHAVIOURS OF HIGH Mo AUSTENITIC STAINLESS STEEL DURING HOT DEFORMATION

The dynamic mechanical behaviours of super low carbon high Mo austenitic stainless steel(00Cr20Nil8Mo6CuN)during hot deformation have been studied by using Formaster-Presshot working simulator. The hot deformation equation, as well as the relationship between peakstrain, peak stress and Zener-Hollman parameter, together with the deformation activationenergy have been resulted through the experiments.     

Al原子在非晶合金Fe78Si9B13中的扩散

利用二次离子质谱(SIMS)并结合离子剥落研究了Al原子在非晶Fe_(78)Si_9B_(13)合金中的扩散。实验结果表明:在320-380℃温区内,扩散系数D位于2.43×10~(-22)-2.01×10~(-21)m~2s~(-1)之间,且它随温度的变化符合Arrhenius关系,D=D_0 exp(-Q/kT),其中指数前因子D_0=2.02×10~(-12)m~2s~(-1)。扩散激活能Q=1.17eV。     

Ti合金中ω相的形成规律

Ti-Al-V,Ti-Al-Mo和Ti-Al-Nb合金系的实验结果表明,ω相的形成是遵守电子浓度规律的。过渡族元素Ti,V,Mo,Nb的价电子数分别为4(s~2d~2),5(s~2d~3),6(s~1d~5),5(s~1d~4)非过渡族元素Al的价电子数为3(s~2p~1)。此外,合金元素的化学负电性和原子半径对ω相的形成也有影响。综合合金元素的价电子数、化学负电性和原子半径三个因素,钛合金中ω相形成的特征值可定为4.223,其表达式为4.223=∑Nf_i+0.310Δx/x_(Ti)+0.551Δr/r_(Ti)     

镍基高温合金定向凝固过程中MC型碳化物的分形分析

利用分形物理分析的方法定量地描述了定向凝固过程中MC型碳化物的生长形态发现随着凝固速率的增加,MC由宽大的枝叶状演化为三级分支的枝簇状,其信息维数随凝固速率呈指数规律上升,并结合非平衡热力学分析了在改变外界控制参数时MC型碳化物形态变化的物理机制     

表面强化件的疲劳强度分析及金属的内部疲劳极限

本文通过对喷丸，渗氮及碳氮共渗试样疲劳行为的研究，提出了金属内部疲劳极限的概念，指出内部疲劳极限约为表面疲劳极限（一般意义上的疲劳极限）的１．３５倍，并利用这个概念分析了表面强化件的疲劳强度。     

ESTIMAING AMOUNT OF EXPLOSIVE FOR FRACTURE PLANE CONTROL BLASTING WITH NOTCHED BOREHOLES

With the development of fracture mechanics,the fracture plane control blasting with notched borcholes hascome into being.This technique is used to create a satisfactory presplit along the contour of an excavation inrock.However,the amount of explosive loaded in each hol usually is determined by trial and error.Because ofthis,two approaches estimating the amount of explosive for the blasting technique are suggested.     

多层膜界面粗糙度的低角X射线衍射研究

对磁控溅射方法制备的Ｗ／Ｓｉ周期多层膜在Ｘ射线衍时仪上进行了低角Ｘ射线衍射实验，并用动力学理论分析了膜层的周期结构和界面粗糙度，在对实验谱线的拟合过程中，考虑了界面的不对称性、周期的随机涨落及系统偏差等因素对衍射强度的影响，并讨论了各个参量对衍射强度影响的程度．     

EFFECT OF INITIAL CRYSTALLIZATION ON MAGNETIZATION OF METALLIC GLASSES(Fe_(1-x)Co_x)_(78)Si_(10)B_(12)

<正> 文献[1]曾对金属玻璃(Fe_(1-x)Co_x),_(78)Si_(10)B_(12)的晶化,作过X射线衍射和透射电镜研究,指出初期晶化相为相应晶态Fe_(1-x)Co_x的室温平衡相.本工作将在验证这一结论的基础上,研究初期晶化对一定磁场强度下磁化强度(定场磁化)的影响。 一、样品和实验方法 成分为(Fe_(1-x)Co_x)_(78)Si_(10)B_(12)(x=0.1,0.5,0.7,1)的合金用单辊快淬法制成截面为～1×0.3mm的金属玻璃窄带,用示差扫描热分析法测定其晶化温度T_(cr)(升温速率10℃/min)分别为505,490,440和420℃.磁性试样在石英管式炉中依次进行退火,退火温度T_a=350-500℃,除了x=0.7的样品在T_a≥450℃退火10min外,T_a≤450℃退火20min,