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81.
Grain‐Boundary “Patches” by In Situ Conversion to Enhance Perovskite Solar Cells Stability 下载免费PDF全文
Lang Liu Sheng Huang Yue Lu Pengfei Liu Yizhou Zhao Congbo Shi Siyu Zhang Jiafeng Wu Haizheng Zhong Manling Sui Huanping Zhou Haibo Jin Yujing Li Qi Chen 《Advanced materials (Deerfield Beach, Fla.)》2018,30(29)
The power conversion efficiency of organic–inorganic hybrid perovskite solar cells has increased rapidly, but the device stability remains a big challenge. Previous studies show the grain boundary (GB) can facilitate ion migration and initiate device degradation. Herein, methimazole (MMI) is employed for the first time to construct a surface “patch” by in situ converting residual PbI2 at GBs. The resultant MMI–PbI2 complex can effectively suppress ion migration and inhibit diffusion of the metal electrodes. The origin of the surface “patch” effect and their working mechanisms are investigated experimentally and theoretically at the microscopic level. It hence demonstrates a simple and effective method to prolong the device stability in the context of GB engineering, which could be extensively applied to perovskite‐based optoelectronics. 相似文献
82.
Isolated graphene nanoribbons(GNRs)usually have energy gaps,which scale with their widths,owing to the lateral quantum confinement effect of GNRs.The absence of metallic GNRs limits their applications in device interconnects or being one-dimensional physics platform to research amazing properties based on metallicity.A recent study published in Science provided a novel method to produce metallic GNRs by inserting a symmetric superlattice into other semiconductive GNRs.This finding will broader the applications of GNRs both in nanoelectronics and fundamental science. 相似文献
83.
梅山汽车运输分公司运翔码头原设计为1500吨级码头,为适应市场发展需要,要停靠5000吨级船舶。从现运翔码头前沿航行水深、码头设施、防护设施等实际出发对安全停靠5000吨级船舶进行可行性论证。 相似文献
84.
预应力混凝土柱的施工技术 总被引:5,自引:4,他引:1
偏心受压钢筋混凝土柱,采用预应力技术减小或避免钢筋混凝土柱根部裂缝,通过在钢筋混凝土柱受拉区一侧预先施加一定的力,使钢筋混凝土柱内部受力在新的条件下建立平衡.实践证明:该方法能有效地控制柱截面,解决钢筋混凝土柱偏心受压的根部裂缝问题. 相似文献
85.
采用五氧化二磷法直接酯化制备烷基磷酸酯。研究了反应机理,建立了反应动力学方程。在本实验条件下,测出反应的表观活化能为42.8 kJ.mol-1,指前因子为864 L.mol-1.min-1。同时,得到了反应的表观动力学方程。 相似文献
86.
Qi Haoliang Li Sheng Gao Jianfeng Han Zhongyuan Xia Xinsong 《电子科学学刊(英文版)》2008,25(1):120-124
This letter presents a new discriminative model for Information Retrieval (IR), referred to as Ordinal Regression Model (ORM). ORM is different from most existing models in that it views IR as ordinal regression problem (i.e. ranking problem) instead of binary classification. It is noted that the task of IR is to rank documents according to the user information needed, so IR can be viewed as ordinal regression problem. Two parameter learning algorithms for ORM are presented. One is a perceptron-based algorithm. The other is the ranking Support Vector Machine (SVM). The effectiveness of the proposed approach has been evaluated on the task of ad hoc retrieval using three English Text REtrieval Conference (TREC) sets and two Chinese TREC sets. Results show that ORM significantly outperforms the state-of-the-art language model approaches and OKAPI system in all test sets; and it is more appropriate to view IR as ordinal regression other than binary classification. 相似文献
87.
Weiti Cui Zihan Zhuang Peihao Jiang Jincheng Pan Gan Zhao Sheng Xu Wenbiao Shen 《International journal of molecular sciences》2022,23(14)
Cinnamoyl-CoA reductase (CCR) is a pivotal enzyme in plant lignin synthesis, which has a role in plant secondary cell wall development and environmental stress defense. Alfalfa is a predominant legume forage with excellent quality, but the lignin content negatively affects fodder digestibility. Currently, there is limited information on CCR characteristics, gene expression, and its role in lignin metabolism in alfalfa. In this study, we identified 30 members in the CCR gene family of Medicago sativa. In addition, gene structure, conserved motif, and evolution analysis suggested MsCCR1–7 presumably functioned as CCR, while the 23 MsCCR-likes fell into three categories. The expression patterns of MsCCRs/MsCCR-likes suggested their role in plant development, response to environmental stresses, and phytohormone treatment. These results were consistent with the cis-elements in their promoters. Histochemical staining showed that lignin accumulation gradually deepened with the development, which was consistent with gene expression results. Furthermore, recombinant MsCCR1 and MsCCR-like1 were purified and the kinetic parameters were tested under four substrates. In addition, three-dimensional structure models of MsCCR1 and MsCCR-like1 proteins showed the difference in the substrate-binding motif H212(X)2K215R263. These results will be useful for further application for legume forage quality modification and biofuels industry engineering in the future. 相似文献
88.
设计了基于TMS320C6205DSP的MPEG-4数字视频监控系统,针对软硬件特性对优化方法做了详细阐述并完成了对该系统的仿真优化,最后给出了关键的测试结果。 相似文献
89.
90.
Self-organizing Cloud is a scalable model to provide powerful computability with distributed computers. The resource allocation on it is very challenging since it not only involves various types of divisible resources but needs to cope with social competitions. We propose a novel resource allocation scheme with three features on ex-post efficiency. (1) Ex-post win–win effect: each participant (consumers and suppliers) should always feel satisfied with their ex-post payoffs. (2) Incentive compatibility: we can prove each rational participant gets its optimal payoff iff their resource demands and expected prices are truthfully declared. (3) Ex-post maximized efficiency: more powerful resources should be consumed with higher likelihood, such that the whole system runs quite efficiently with maximized resource utilization. Our simulation shows the approach significantly improves resource suppliers’ incomes by 20% compared to their expectations. Meanwhile, we can guarantee consumers’ payments below their budgets, with no any degradation of task execution performance. 相似文献