Degradation of direct‐tunneling gate oxide under hot hole injection

The degradation of ultrathin SiO₂ films accompanied by the hole direct tunneling is investigated using a substrate hot hole (SHH) injection technique. Hot holes from the substrate as well as cold holes in the inversion layer are injected into the gate oxides in p‐channel MOSFETs with p⁺ poly‐Si gates, while the gate bias is kept low enough to avoid simultaneous electron injection from the gate. During the SHH stress, in contrast to the case of thicker oxide films, a strong correlation is observed between the oxide film degradation and the injected hole energy, whereas no degradation occurs due to the hole direct tunneling from the inversion layer. These experimental findings indicate the existence of threshold energy for trap creation process, which has been predicted by the theoretical study of hole‐injection‐induced structural transformation of oxygen vacancy in SiO₂. © 2002 Wiley Periodicals, Inc. Electr Eng Jpn, 140(4): 54–61, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.2008     

Development of a new blue CaMgSi2O6:Eu2+ phosphor for PDPs

Abstract— A blue‐light‐emitting Eu²⁺‐doped CaMgSi₂O₆ phosphor having a long lifetime for a plasma‐display panel (PDP) was developed. The CaMgSi₂O₆:Eu²⁺(CMS:Eu) phosphors show no luminance degradation during the baking process, and an equivalent photoluminescence peak intensity compared to that of the conventional blue‐phosphor BaMgAl₁₀O₁₇:Eu²⁺ (BAM) after baking. CMS: Eu shows a poor luminescent characteristic for the Xe excimer band excitation due to the lack of absorption. To introduce the absorption center for the Xe excimer band, we performed Gd‐codoping of CMS: Eu as a sensitizer and found a new excitation band around 172 nm, which originated from Gd³⁺. The test PDPs panels using synthesized CMS: Eu phosphor and CMS: Eu, Gd phosphor were examined to investigate the luminescent and aging characteristics of a Xe‐discharge excitation source. The CMS: Eu panel shows an emission peak intensity comparable to that of the BAM panel (i.e., a comparable stimuli L/CIEy, 93% of BAM), while the CMS: Eu, Gd panel shows poorer blue emission intensity compared to the BAM panel (up to 53% of total stimuli of BAM). The CMS: Eu panel and the CMS: Eu, Gd panel show less luminance degradation than the BAM panel under the aging test, and the panel retains 90% of its luminance after 300 hours of driving. It was found that CMS: Eu appears to be a candidate for a new blue PDP phosphor because of its longevity in a Xe‐discharge plasma environment.     

Atrovenetin as a potent antioxidant compound from penicillium species

We have established a program to screen large numbers of wild-type fungi isolated from soil for potential producers of antioxidants and synergists for tocopherol (Toe). An antioxidant and potent Toc synergist was isolated from mycelial mats ofPenicillium paraherquei. It was one of the deoxyherqueinone-type phenalenones and has been identified as atrovenetin. Under autoxidation conditions, the induction periods of this compound (0.025%) tested by the active oxygen method were 571 and 171 hr in lard with and without Toc (0.04%), respectively. It was also capable of stabilizing vegetable oils such as soybean, rapeseed and palm oils.     

Synthesis and properties of polycyclic quinones condensed with 1,6-methano[10]annulene

Two types of polycyclic quinones condensed with 1,6-methano[10]annulenes as type A: 1,6-methanonaphtho[2,3-c][10]annulene-7,12-dione 5a, and type B: 1,6-methanonaphtho[2,3-c][10]annulene-5,14-dione 18, bis(1,6-methano[10]annuleno[3,4-b; 3,4-g])anthracene-10,21-dione 20, 1,6-methanoanthraceno[2,3-c][10]annulene-5,16-dione 22, 1,6-methanotetraceno[2,3-c][10]annulene-6,17-dione 23, and 1,6-methano phenanthreno[2,3-c][10]annulene-5,6-dione 24 have been synthesized. The acene derivative 6 corresponding to that of 5a was synthesized by the reduction of quinone 5a. The physical, spectral, and chemical properties of these new compounds have been investigated.     

Synthesis and properties of polycyclic quinones condensed with 1,6-methano[10]annulene

Two types of polycyclic quinones condensed with 1,6-methano[10]annulenes as type A: 1,6-methanonaphtho[2,3-c][10]annulene-7,12-dione 5a, and type B: 1,6-methanonaphtho[2,3-c][10]annulene-5,14-dione 18, bis(1,6-methano[10]annuleno[3,4-b; 3,4-g])anthracene-10,21-dione 20, 1,6-methanoanthraceno[2,3-c][10]annulene-5,16-dione 22, 1,6-methanotetraceno[2,3-c][10]annulene-6,17-dione 23, and 1,6-methano phenanthreno[2,3-c][10]annulene-5,6-dione 24 have been synthesized. The acene derivative 6 corresponding to that of 5a was synthesized by the reduction of quinone 5a. The physical, spectral, and chemical properties of these new compounds have been investigated.     

Comparative assessment of the efficiency of Fe-doped TiO2 prepared by two doping methods and photocatalytic degradation of phenol in domestic water suspensions

Fe-doped TiO₂ particles responding to visible light were synthesized by impregnation and calcination method using TiO₂ particle and Ti element, respectively. The optical and the chemical properties were characterized by measuring the X-ray diffraction (XRD) and UV-visible spectroscopy. The onset of absorption shifted to longer wavelengths on doping TiO₂ by the calcination process, which showed a better response as compared to the impregnation method. The photocatalytic reactivity was evaluated by the degradation of phenol with impregnated Fe-doped (0.5% w/w in Fe) and calcined Fe-doped (Fe_xTi_1−xO₂, x=0.005 (Fe/Ti molar ratio)) TiO₂ separately in distilled and tap water. The characterization results have confirmed the advanced possibility of correlation between photoactivity and the special property of sulfur-containing calcined Fe-doped TiO₂. In case of the coagulation of the undoped A-I and the Fe-doped B-I, the photoactivity showed a decrease due to the presence of natural electrolytes and due to the high pH of tap water, whereas in the case of the coagulation of calcined Fe-doped TiO₂ prepared from sulfides (Fe_xTiS₂), the photoactivity showed an increase. In this study, highest catalytic activity was found to be strongly dependent both on catalyst structure and on the type of water used.