Low-enthalpy geothermal energy: An opportunity to meet increasing energy needs and reduce CO2 and atmospheric pollutant emissions in Piemonte,Italy

The scope for diffusion of very low-enthalpy geothermal plants in the Piemonte region of Italy, using groundwater heat pumps (GWHP), was analyzed to check environmental sustainability and the benefits in terms of reducing greenhouse gas emissions from fossil fuels. GWHP implementation seemed particularly suitable to the specific characteristics of the Piemonte plain. An important thick and productive shallow aquifer is present across the entire plain beneath the major energy users and is therefore appropriate for geothermal energy development purposes. The building stock could be adapted to heat pumps in different ways, but objective-oriented policies will be required to reach the best results in terms of environmental benefits.     

Bio-ethanol production by fermentation of ricotta cheese whey as an effective alternative non-vegetable source

The aim of the present paper is to investigate the feasibility of bio-ethanol production by batch fermentation of ricotta cheese whey (“Scotta”), a dairy industry waste characterized by lactose concentration ranging from 4.5% to 5.0% (w/w) and, with respect to traditional (raw) whey, by much lower protein content. Scotta, therefore, could represent an effective non-vegetable source for renewable energy production. The microrganism used to carry out the fermentation processes was the yeast Kluyveromyces marxianus. Preliminary experiments, performed in aerobic conditions on different volumes of scotta, have shown the actual growth of the yeast. The subsequent fermentation experiments were carried out, in anaerobic conditions, on three different substrates: scotta, raw cheese whey and deproteinized whey. The experimental data have demonstrated the process feasibility: scotta is an excellent substrate for fermentation and exhibits better performance with respect to both raw cheese whey and deproteinized whey. Complete lactose consumption, indeed, was observed in the shortest time (13 h) and with the highest ethanol yield (97% of the theoretical value).     

Influence of emulsion composition on lubrication capacity and texture perception

The role of fat content and type of surfactant for oral friction processes and texture perception of oil-in-water emulsions was assessed. Emulsions at 22% and 33% fat content containing either sodium caseinate or a sucrose ester as emulsifier were compared with viscosity-adapted aqueous solutions of dextran using both sensory evaluation and friction coefficient measurements on a tongue-palate contact model. The impact of saliva on the emulsion droplet size distribution was studied using tribology, differential interference contrast microscopy and light diffraction measurements. Emulsions at 33% and the corresponding iso-viscous aqueous solutions were discriminated in the sensory experiment whereas emulsions at 22% were not. Friction was significantly different for emulsions at 33% and the corresponding iso-viscous aqueous solutions. The difference was not significant for emulsions with 22% fat level when compared with the iso-viscous aqueous solutions. Saliva significantly decreased the friction coefficient of emulsions depending on the surfactant and amount of fat used.     

Electrocatalytic oxidation of organic molecules in alkaline solutions—I. Oxidation of 1,3 dioxolane at platinum

The electroadsorption and electrooxidation of 1,3 dioxolane at platinum in 1 M KOH solutions were investigated under a wide range of experimental conditions. The potential of maximum adsorption (E^max_ad) is ca. 0.4 V and the degree of surface coverage depends linearly with the logarithm of organic concentration as predicted by a Temkin type adsorption isotherm. The kinetics of the electroadsorption process follows a Roginskii-Zel'dovich equation. From (eps)_ad, (eps)_ox and analysis of oxidation products a mechanism is postulated which consists of an adsorption with simultaneous dehydrogenation step followed by cycle rupture and electroadsorption and dehydrogenation of further residues.     

A.c.-impedance spectroscopy study of oxygen reduction at Nafion® coated gas-diffusion electrodes in sulphuric acid: Teflon loading and methanol cross-over effects

The kinetics of oxygen reduction have been studied at Nafion®-coated dual layer gas-diffusion electrodes at 60 °C in 2.5 M H₂SO₄. A.c. impedance and steady state galvanostatic measurements have been carried out on electrodes containing various PTFE loadings. A.c. impedance spectroscopy supplied information on charge transfer resistance, series resistance and double layer capacitance of electrodes during the oxygen reduction process. These parameters, together with those derived by d.c. measurements (i.e. Tafel slopes, charge transfer coefficient, etc.), allowed a better identification of the features governing the electrode efficiency and the reduction mechanism. The best electrode was found to be one containing 30% PTFE; this showed both the lowest charge transfer resistance and the lowest overpotential for oxygen reduction. This electrode also showed lower overpotential than the same uncoated electrode at low current densities. The poisoning effect by methanol has been also investigated. Upon addition of methanol to the solution, no change was observed in the reaction mechanism at low overpotentials. In contrast, a significant variation of the Tafel slope was observed at high overpotentials. This behaviour is interpreted in terms of the variation of Pt-O bond strength as a function of electrode potential.     

Densimetry for on-line conversion monitoring in emulsion homo- and copolymerization

The use of on-line densimetry to monitor conversion in batch emulsion polymerization reactors are investigated. Some characteristics of the sampling circuit connecting the reactor to the densitometer, which allow one to obtain reliable on-line estimations of monomer conversion in the whole range of conversion, are discussed in detail. Moreover, the amount of collected data provides a practically continuous monitoring of the system evolution in time, which allows one to estimate directly the rate of conversion as a function of time. The technique has been applied both to homopolymerization systems [i.e., styrene (STY) and methyl methacrylate (MMA)] as well as to copolymerization systems [i.e., STY–MMA, acrylonitrile (ACN)–MMA, vinyl acetate (VAC)–MMA]. In the latter case, the density measurements are combined with a reliable model which provides for polymer composition as a function of conversion, in order to obtain accurate measurements of monomers conversion. © 1993 John Wiley & Sons, Inc.     

Moving beyond ‘more crop per drop’: insights from two decades of research on agricultural water productivity

ABSTRACT

Concern over increasing water scarcity has led to the introduction of the concept of agricultural water productivity and an emphasis on interventions to achieve ‘more crop per drop’. Yet, a strong debate continues on how the concept is to be defined and used. Drawing largely from the irrigation literature, the origins of the concept and its methodological developments are reviewed, and its use in applied work over two decades is discussed. Based on this analysis of conceptual and applied research, key insights into the concept’s contributions and limitations are presented, as well as opportunities for further refinements.     

The Yellow River Basin: Water Accounting,Water Accounts,and Current Issues

Abstract

There is increasing recognition of the problems facing China in meeting the growing water demand in the Yellow River basin, the “cradle of Chinese Civilization” and a critically important agricultural and industrial region. Meaningful debate on the range and relative costs of options available to policy-makers in addressing the problem depend fundamentally on an accurate understanding of basin water resources. Unfortunately, the ability of outsiders to participate in the de bate and for Chinese, with their long history of water management, to contribute to similar discussions elsewhere in the world is hindered to some extent by a lack of understanding of differences in water accounting systems and concepts. This paper attempts to address this problem by describing the water accounting system used in the Yellow River basin and elsewhere in China. The paper shows that the primary difference between water accounting methodologies in the Yellow River and those typically applied elsewhere is related to supply accounting in general and groundwater accounting in particular. Although not currently included in its water accounting system, Chinese concepts of environmental water use, when included, will also differ substantially from those familiar to outside researchers. In terms of actual Yellow River balances, the paper highlights the apparent declining trend in basin rainfall and runoff and the dramatic growth in industrial and domestic water use. Together declining supply and rising demand will increasingly cause policy-makers to face hard choices in assessing their water planning options. These choices will only become more difficult as managers in the Yellow River, as elsewhere in the world, try to incorporate ecological needs in the water accounting equation.     

Groundwater use in Spain: an overview in light of the EU Water Framework Directive

In semi-arid regions, aquifers provide a series of practical advantages that make them preferential sources of water supply. In Spain, groundwater meets about one-fifth of the total water demand and is used to irrigate over one-third of the total irrigated land. This article examines groundwater use in Spain from the perspective of the EU Water Framework Directive. Analysis of different sector uses suggests that core problems (and solutions) related to groundwater lie in agricultural uses and that the Directive's environmental requirements remain distant from reality on the ground, where economic, political and social reasons prevail on legal obligations set by national and supranational authorities.     

A Decision Support System Based on AHP for Ranking Strategies to Manage Emergencies on Drinking Water Supply Systems

Water Resources Management - The provision of critical services, such as drinking water, is crucial both in ordinary and in emergency conditions due to either natural (e.g. earthquakes, droughts,...