Microwave Synthesis of Yttrium Iron Garnet Powder

A 28 GHz microwave heating method was used to react an Fe₂O₃+ Y₂O₃ powder mixture to form yttrium iron garnet (YIG, Y₃Fe₅O₁₂) powder. The minimum temperature to form YIG was lower than the conventional (external) heating method. YIG began to form after only 70 s of irradiation, which means that the solid-state reaction proceeded very rapidly. The amounts of byproducts were controlled by the starting composition and by the Y₂O₃ particle size. The resultant YIG particle size also was controlled by the Y₂O₃ particle size.     

Preference index for Japanese complexion under illuminations

This article proposes a useful evaluation method based on preferred complexion as one of color‐rendering methods of light sources. A relational equation between subjective evaluation values of preferred Japanese complexion under various illuminations and the D65 corresponding colors by adopting CIE94 chromatic adaptation transform on the CIE 1976 u′v′ chromaticity diagram was derived by using multiple regression. Then, preference index of skin color or PS was developed in order to evaluate quantitatively the degrees of preferred complexion from the equation. Furthermore, a new index PS_(ac,bc) was derived by using CAM02 color appearance model instead of the CIE94. Each relationship of R_a, R₁₅, CQS, MCRI, FCI, CCRI, and HCR to PS was examined. Then, the PS was found as an independent index which was quite different from the other indices when the PS was more than or equal to 80. Therefore, it is useful to develop and evaluate light sources to realize more comfortable lighting environments by applying the concept of the PS. © 2015 Wiley Periodicals, Inc. Col Res Appl, 41, 143–153, 2016     

盾构衬砌管片接头内力-变形统一模型及试验分析

首先在钢筋混凝土管片系列接头试验的基础上,总结提出了接头弯矩-相对转角关系的线性、双线性和非线性模型,以及接头轴力-相对轴向变形和剪力-相对剪切变形关系的分段式模型,并给出了用于描述荷载偏心距和螺栓初始扭矩对于接头刚度影响的理论模型。其次,基于平板型和弧型管片接头的受弯试验结果,分别给出了在有无防水密封垫情况下各类转动刚度模型参数的取值方法,提出了不同条件下的转动刚度模型选择依据,研究了不同螺栓初始扭矩和轴力对接头转动刚度取值的影响;基于平板型管片接头剪切试验结果,分别给出了在有无防水密封垫情况下三阶段剪切刚度模型的参数取值方法。研究结果验证了各接头刚度模型的有效性,将对盾构衬砌结构梁-接头模型计算理论的应用起到重要的推动作用。     

Variable frequency heavy-ion linac,RILAC: I. Design,construction and operation of its accelerating structure

A variable frequency linear accelerator at RIKEN (IPCR), which is named RILAC, is designed to accelerate ions of almost every element in the periodic table. In this report, the design, construction and performance of the resonator cavities of this linac are described. A new accelerating structure was developed for the variable frequency scheme. The principal aim of the development was to obtain a configuration within the cavity to keep a uniform voltage distribution along the accelerating axis over the wide range of resonant frequencies required. The final form adopted is a coaxial quarter-wave type resonator with a race-track-like cross section for its coaxial inner and outer conductors. It has a movable shorting device as a frequency tuner and its open end is enlarged and loaded with drift tubes, connected to the inner and outer conductors alternatingly. The structure can maintain the required uniformity of the accelerating voltage within 10% in spite of resonant frequency tuning between 17 and 45 MHz. A relatively modest accelerating gradient was chosen so that cw operation could be realized. The RILAC is composed of six such cavities which are independently excited and it succeeded in the acceleration of a beam through all the cavities in 1981.     

Extraction rates of amino acids by an emulsion liquid membrane with tri-n-octylmethylammonium chloride

The extraction rates of amino acids from alkaline aqueous solution into an emulsion liquid membrane containing tri-n-octylmethylammonium chloride as a carrier and Paranox 100 as an emulsifier were measured using a stirred transfer cell. The effects of agitation speed (0·33–0·66 rev s⁻¹), amino acid concentrations (0·5–50 mol m⁻³) and temperature (10–45°C) on the extraction rates were examined. The results were analyzed by a double-film model. The mass transfer coefficients of amino acids (0·26–1·58×10⁻⁵ m s⁻¹) and their complexes (0·60–1·72×10⁻⁵ m s⁻¹) were found to correlate well with the hydrophobicities of the amino acids. It was found that the surfactant layer influenced the mass transfer processes of both amino acids in the aqueous film and their complexes in the organic film. The permeation of amino acids with a large hydrophobicity through the emulsion liquid membrane was promoted by both high distribution and larger mass transfer rates. © 1998 Society of Chemical Industry     

Cross section adjustment method based on random sampling technique

A cross section adjustment method based on the random sampling technique is proposed. In the proposed method, correlations among cross sections and core parameters are used instead of sensitivity coefficients of cross sections, which are necessary in the conventional method. The correlations are statistically estimated by the random sampling technique. The proposed method is theoretically consistent with the conventional method and provides comparable adjusted cross sections when sufficient number of random sampling is taken into account. The proposed method would be suitable for practical light water reactor (LWR) core analysis since estimation of sensitivity coefficients, which requires considerable computational cost in typical LWR problems, is not necessary. Through a benchmark problem in simple pin-cell geometry, adjusted cross sections by the present and the conventional cross section adjustment method are compared. The adjusted cross sections by the present method well reproduce the conventional ones, thus the feasibility of the present method is confirmed.     

Anionic polymerization of fluorine-containing vinyl monomers

Summary The anionic polymerization of pentafluorophenylmethyl methacrylate (PFPMA) were examined with several anionic initiators. The initiators of relatively low activity such as t-C₄H₉OK, organozinc compounds and Al(C₂H₅)₃ produced poly(PFPMA) in fairly high yields though no polymer was obtained by the initiations of n-C₄H₉Li and C₂H₅MgBr within 7 days. The anionic polymerization reactivity of PFPMA was found to be strongly affected by the pentafluorophenyl group though the e-value of PFPMA is similar to those of methyl methacrylate and benzyl methacrylate.Part 7, Polym. J. 19, 958 (1987)     

Joining of SiC Fiber‐Bonded Ceramics using Silver,Copper, Nickel,Palladium, and Silicon‐Based Alloy Interlayers

SiC fiber‐bonded ceramics, SA‐Tyrannohex^®, (SA‐THX) with perpendicular and parallel fiber orientations were brazed using Ag‐, Ni‐ and Pd‐base brazes, and four Si–X (X: Ti, Cr, Y, Ta) eutectics. Outcomes were variable, ranging from bonded joints through partially bonded to un‐bonded joints. Prominent Ti‐ and Si‐rich interfaces developed with Cusil‐ABA, Ticusil, and Copper‐ABA and Ni‐ and Si‐rich layers with MBF‐20. Stress rupture tests at 650 and 750°C on Cusil‐ABA‐bonded joints revealed a temperature‐dependent behavior for the perpendicular joints but not for the parallel joints with failure occurring at brazed interface. Higher‐use temperatures can be targeted with eutectic Si–Ti and Si–Cr alloys.