Numerical and experimental investigation of three-dimensional flow in extrusion dies

The univariant element, Q₁ P₀, and the multivariant elements, QP₀ and R P₀, are compared for the numerical simulation of the flow in extrusion dies. The pressure distribution obtained by using the Q₁ P₀ element was found to be afflicted with the checkerboard pressure mode. On the other hand, the multivariant elements, Q P₀ and R P₀, gave accurate and physically reasonable velocity and pressure distributions. The computed values of the pressure drop across extrusion dies matched well with the pressure drop determined experimentally.     

Unique molecular aggregation of novel naphthalocyanine (near IR absorbing dye)

A series of organic-soluble naphthalocyanine derivatives (Y_mMNcX₄) have been synthesized. Their spectroscopic properties in organic solutions and in thin films were studied. MNcX₄ such as MNc(t-Bu)₄ (5a-5c) and MNc(On-Bu)₄ (5j) formed H-aggregates even in dilute solutions. MNc(CO₂R')₄ (5d-5i) had much stronger H-aggregation properties compared with those ofMNc(t-Bu)₄ and MNc(On-Bu)₄. Especially, MNc(CO₂R')₇ complexes (M=Cu, Pd and Ni) existed exclusively without monomers in the aggregated state even in highly dilute solutions. MNcX₄, which has strong H-aggregation properties, showed merely H- aggregate absorption maxima in thin films. In contrast, Y₂MNcX₄ (4), which has sterically hindered Y groups, showed monomerically pure characteristics in solution. However, thin films of Y₂MNcX₄ have a J-type molecular arrangement, exhibiting a red shift of Q-band absorption. The monomeric properties of Y₂MNcX₄ in solutions and J-type molecular arrangement in thin films arise from steric hindrance of two Y groups, such as R₃SiO-in Y₂MNcX₄, which prevents strong H-aggregation of naphthalocyanine.     

Molecular simulation of hydrogen adsorption in organic zeolite

The adsorption of molecular hydrogen on model zeolites has been simulated employing Grand Canonical Monte Carlo (GCMC) procedure. The effects of cation type, available volume, surface area, temperature, pressure and pre-adsorbed organics such as benzene on the hydrogen uptake are analyzed. The hydrogen adsorption can be affected mainly by the available volume and surface area per g-zeolite at the same temperature and pressure. Increase of temperature results in the decrease of sorption intensity and capacity. The adsorption capacity correlates well with the pressure with high linearity at room temperature. Adsorption is lowered by the pre-adsorbed benzene molecule. The orientation and the number of benzene molecule in zeolite affect the adsorption capacity. The organic zeolite with larger available volume shows larger adsorption capacity.     

Synthesis and physicochemical characterization of amphiphilic block copolymer self‐aggregates formed by poly(ethylene glycol)‐block‐poly(ϵ‐caprolactone)

Diblock copolymers with different poly(ε‐caprolactone) (PCL) block lengths were synthesized by ring‐opening polymerization of ε‐caprolactone in the presence of monomethoxy poly(ethylene glycol) (mPEG‐OH, MW 2000) as initiator. The self‐aggregation behaviors and microscopic characteristics of the diblock copolymer self‐aggregates, prepared by the diafiltration method, were investigated by using ¹H NMR, dynamic light scattering (DLS), and fluorescence spectroscopy. The PEG–PCL block copolymers formed the self‐aggregate in an aqueous environment by intra‐ and/or intermolecular association between hydrophobic PCL chains. The critical aggregation concentrations of the block copolymer self‐aggregate became lower with increasing hydrophobic PCL block length. On the other hand, reverse trends of mean hydrodynamic diameters were measured by DLS owing to the increasing bulkiness of the hydrophobic chains and hydrophobic interaction between the PCL microdomains. The partition equilibrium constants (K_v) of pyrene, measured by fluorescence spectroscopy, revealed that the inner core hydrophobicity of the nanoparticles increased with increasing PCL chain length. The aggregation number of PCL chain per one hydrophobic microdomain, investigated by the fluorescence quenching method using cetylpyridinium chloride as a quencher, revealed that 4–20 block copolymer chains were needed to form a hydrophobic microdomain, depending on PCL block length. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3520–3527, 2006     

基于机械臂运动的组合航天器惯性参数在轨辨识

随着空间技术发展,交会对接任务越来越多,服务航天器与目标航天器对接形成组合航天器后惯性参数会发生明显变化。因此,提出一种基于机械臂运动的组合航天器惯性参数在轨辨识方法。该方法可以分为2步:第一步辨识组合航天器的质量和质心;第二步辨识组合航天器的惯性张量。该方法优点是实现了质量、质心与惯性张量等辨识参数的相互解耦,不需要消耗航天器上宝贵的喷气燃料,仅需要测量航天器的速度,而不是加速度和力。仿真结果验证了方法的有效性。     

注气井井筒结垢预测研究

在油田开发过程中,油、气、水和泥浆在地层或管道中流动,当达到一定条件时,油垢、水垢或泥垢便会产生。在实际生产过程中,油垢和泥垢通常伴随着水垢而生成,所以对水垢结垢趋势的预测研究显得至关重要。介绍了Oddo-Tomos饱和指数法的理论预测模型,以及在生产过程中利用Oddo-Tomos饱和指数法预测油田结垢趋势的方法,阐述并分析了油田结垢对油田开采的影响。研究结果可为下一步的生产作业提供理论依据。     

基于混合参数蚁群算法的移动机器人路径规划北大核心

针对传统蚁群算法因初期信息素分布不均导致算法初期路径选择概率随机性大、搜索速度慢等缺陷,设计一种使用混合参数的蚁群改进算法。在算法开始阶段引入遗传算法,对遗传算法的适应度函数进行改进;设置一个评价点使遗传算法在合适的时机进入蚁群算法,并对算法的信息素挥发因子p采用一种自适应调整方式;对遗传算法的交叉率和变异率以及蚁群算法的信息因子和期望因子采用变异的混合参数,发挥4个参数因子在算法中的优点;在蚁群算法后面设置一个路径进化率的评价点判定是否再次进行遗传变异操作,目的是使蚁群算法跳出局部最优;算法最后引入B样条曲线光滑机制。实验结果表明:改进算法在简单和复杂的环境里找到的路径长度和路径拐点数明显减少,有比其他3种算法更快更准的寻找全局最优能力。     

钨粉表面化学镀铜研究

为了提高钨粉制品的性能,采用正交实验方法,利用SEM、XRD、EDS等分析手段,系统研究了化学镀铜主要工艺参数对钨粉表面化学镀铜的影响规律。结果表明:在温度固定条件下,各因素对镀液稳定性影响的显著性顺序是:硫代硫酸钠加入量>pH值>χ(Tar2-/Cu2 )>甲醛加入量,而对镀速影响的显著性顺序是:χ(Tar2-/Cu2 )>pH值>甲醛加入量>硫代硫酸钠加入量;较佳的钨粉表面化学镀铜工艺为:五水硫酸铜8g/L;酒石酸钾钠28g/L;EDTA0.75g/L;NaOH8.5g/L;硫代硫酸钠10mg/L;甲醛7.5ml/L;pH=12;温度40℃。采用所推荐的工艺,成功的在钨粉上获得了化学镀铜层。     

一种基于蚁群算法的呼叫中心人力需求计算方法

针对呼叫中心人力需求优化这一离散约束问题,基于Dantzig提出的集合覆盖模型,建立了单技能呼叫中心的人力需求计算线性规划模型,并提出一种基于改进蚁群算法的求解方法.在该方法中,对算法的信息素更新规则进行了修改,并基于MATLAB编程针对实例进行仿真分析.选取统计学指标将算法的仿真结果与遗传算法进行对比,结果表明:基于蚁群算法的方法计算复杂度可行;能够节约人力,且话务员匹配度可满足实际运营需求;为智能算法在呼叫中心人力需求计算问题上的应用研究提供了一种新的解决思路.     

新形势下计算机教学的创新思维培养刍议

随着科学技术的进步与信息社会的到来,计算机成为社会中不可缺少的重要组成部分.新课改形势下,计算机教学如何与创新型人才培养结合.如何利用计算机教学的特点建构学生的创新思维是本文研究的重点.