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91.
Pore structure of carbons coated on ceramic particles 总被引:1,自引:0,他引:1
Michio Inagaki Shingo Kobayashi Fumi Kojin Nobuyuki Tanaka Takahiro Morishita Beata Tryba 《Carbon》2004,42(15):3153-3158
Pore structure of carbon coated on ceramic particles by carbonization of precursor in a powder mixture at 900 °C was studied by focusing on the effects of substrate ceramics (MgO, TiO2 and various phases of Al2O3) and of carbon precursor (poly(vinyl alcohol) (PVA), poly(ethylene terephthalate) (PET) and hydroxyl propyl cellulose (HPC)). By dissolving substrate MgO particles, carbon coated was found to have a high BET surface area, more than 1000 m2/g, which was almost the same as the value estimated from apparent surface area measured on carbon-coated MgO particles under the assumption of zero surface area of the substrate. The carbon separated was found to be rich in micropores from the analyses by DFT method and αs plot. The dependence of the BET surface area on the amount of carbon coated on TiO2 with a high surface area was the same for three carbon precursors, although the carbon yields from the precursors were slightly different. Porous Al2O3 substrates, γ-Al2O3as-received and that formed from Al(OH)3 during carbonization, gave a high BET surface area, but dense Al2O3, α-Al2O3, gave a low surface area. 相似文献
92.
Amorphous carbon materials for lithium ion battery anodes which contain a small amount of Li2CO3 were prepared by three methods. The obtained materials were characterized using X-ray diffraction (XRD) analysis, Raman spectroscopy and CO2 adsorption experiments. Although the XRD profiles and Raman spectra of these materials were similar to those of carbon materials synthesized with no addition, the amount of CO2 adsorbed was largely decreased by Li2CO3 addition. These results suggest that the micropores in these materials were plugged and/or filled with Li2 CO3. Galvanostatic lithium charging and discharging experiments showed that the irreversible capacity of the material can be significantly decreased by Li2CO3 addition, which is thought to be due to the plugging of the pore inlets by Li2CO3. Moreover, it was also found that the reversible capacities of the materials can be increased by adjusting both the amount of Li2CO3 addition and carbonization temperature. 相似文献
93.
Takahiro Kawashima Tsuyoshi Kimura Takayuki Shibata Akio Kishida Takashi Mineta Eiji Makino 《Microelectronic Engineering》2010,87(5-8):704-707
In order to realize cellular network analysis on a chip-based system, our group has been developing a patterned cell culture microdevice with pillars in an array for tapping cells into space surrounded by the pillars. The pillar structures has advantages to trap both adhesive and non-adhesive cells and to precisely control positions of cells and distances between cells for understanding effects of various cell patterns on functions of a cellular network such as cell proliferation, differentiation, and network formation. In this paper, HeLa cell cultivation with the patterned cell culture microdevice having a pillar array fabricated by dry film of thick negative photoresist SU-8 on a glass substrate was executed as a feasibility study on a cellular network analysis. The results revealed that the device performance was found to be enough to culture HeLa cells for more than 48 h. In addition, relative extensibility of blocks of multiple cells compared with single cells tapped on the device was observed. Thus, the patterned cell culture microdevice proposed here could be applicable to analysis of cellular functions. 相似文献
94.
Kaname Kanai Takahiro Miyazaki Takanori Wakita Kouki Akaike Takayoshi Yokoya Yukio Ouchi Kazuhiko Seki 《Advanced functional materials》2010,20(13):2046-2052
How annealing influences the morphology of a highly regioregular poly(3‐hexylthiophene) (RR‐P3HT) film at the substrate interface as well as the lateral inhomogeneity in the electronic structure of the film are elucidated. Whereas previous studies have reported that high‐molecular‐weight (MW) RR‐P3HT films tend to show low crystallinity even after annealing, it is found that high‐MW RR‐P3HT does show high crystallinity after annealing at high temperature for a long time. Photoemission electron microscopy (PEEM), X‐ray photoemission spectroscopy, and ultraviolet photoemission spectroscopy results clearly resolve a considerable lateral inhomogeneity in the morphology of RR‐P3HT film, which results in a variation of the electronic structure depending on the local crystallinity. The PEEM results show how annealing facilitates crystal growth in a high‐MW RR‐P3HT film. 相似文献
95.
We propose a new geometric method of IR factorization in sector decomposition. The problem is converted into a set of problems in convex geometry. The latter problems are solved using algorithms in combinatorial geometry. This method provides a deterministic algorithm and never falls into an infinite loop. The number of resulting sectors depends on the algorithm of triangulation. Our test implementation shows smaller number of sectors comparing with other existing methods with iterations. 相似文献
96.
Qiang Dong Nobuhiro Kumada Yoshinori Yonesaki Takahiro Takei Nobukazu Kinomura Dan Wang 《Journal of Materials Science》2010,45(20):5685-5691
Hollow hematite (α-Fe2O3) microspheres with an average diameter of 3-4 μm and a shell thickness of approximate 150 nm was synthesized by a simple hydrothermal route using FeCl3·6H2O solution and acetic acid without using any templates. The hollow microspheres were composed of α-Fe2O3 nanoparticles with the diameter range from 20 to 40 nm. The effects of reaction parameters such as reaction time, temperature, concentration of FeCl3·6H2O solution, and initial pH on the morphology of the final products were investigated. A possible formation mechanism of hollow α-Fe2O3 microspheres was also proposed, where the acetic acid played a role of etching in the formation of hollow structure. 相似文献
97.
Satofumi Souma Matsuto Ogawa Takahiro Yamamoto Kazuyuki Watanabe 《Journal of Computational Electronics》2011,10(1-2):35-43
We show computationally that the current-voltage characteristics of the zigzag-edged graphene nanoribbon (ZGNR) with the even width exhibit remarkable current saturation behavior in spite of the absence of the bandgap. Mechanism of such current-saturation behavior can be understood to be originated from the symmetries of the wavefunctions corresponding to the edge states in ZGNR. We further demonstrate that the current-voltage characteristics of ZGNR can be drastically changed even by the presence of a single lattice vacancy, with the strong dependence on the position of the vacancy. The origin of such properties is intuitively understood by analyzing the transmission probabilities through such systems. 相似文献
98.
Takahiro Haga 《Information Sciences》1986,40(3):207-226
We have previously proposed an idea of p-valued input, q-valued output threshold logic to synthesize many-valued, p-valued, logical networks, and derived the condition for (p, q)-logical completeness for the output-closed set of (p, q)-logical functions. In this paper, the condition for (p, q)-logical completeness for the output-coherent set F of (p, q)-logical functions is described, and the proof is given in almost the same way as for the output-closed set. The output-coherent set F is applied to image processing. That is, a restoration scheme is described for images to which normal random noise is added. 相似文献
99.
Dynamic Characteristics Analysis of Two‐DOF Oscillatory Actuator and Experimental Verification of Prototype 下载免费PDF全文
Yoshimoto Takamichi Katsuhiro Hirata Yasuyoshi Asai Kenji Ueyama Eiichiro Hashimoto Takahiro Takagi 《Electrical Engineering in Japan》2014,186(1):58-65
Recently, linear oscillatory actuators have been used in a wide range of applications. In particular, small linear oscillatory actuators are expected to be used in haptic devices by being extended to provide multi‐degree‐of‐freedom motion with arbitrary acceleration. In this paper, we propose a compact two‐DOF oscillatory actuator that can move in various directions on a plane. The static and dynamic characteristics of the actuator are determined by the 3D finite element method. The effectiveness of this method is shown through a comparison of the measured results with the experimental results from a prototype. © 2013 Wiley Periodicals, Inc. Electr Eng Jpn, 186(1): 58–65, 2014; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.22312 相似文献
100.
Asymmetric capacitors composed of carbon electrodes with different pore size distributions (PSD) were constructed in order to study the fundamental relationship between the PSD of positive and negative carbon electrodes and the performance of electric double layer capacitors. The performance of asymmetric capacitors in a non-aqueous electrolyte solution (TEMA·BF4/PC) was found to be governed by the PSD of the carbon used in the negative electrode. Capacitance depends on the BET surface area of the negative electrode and the rate performance depends on its mesoporous surface area. These results were explained by the fact that it is more difficult to adsorb large solvated cations (TEMA+) in micropores (less than 2 nm wide) than in mesopores (2-50 nm wide), and that this is more difficult with a higher rate of charge-discharge. 相似文献