全文获取类型
收费全文 | 1446篇 |
免费 | 49篇 |
国内免费 | 6篇 |
专业分类
电工技术 | 76篇 |
综合类 | 1篇 |
化学工业 | 378篇 |
金属工艺 | 31篇 |
机械仪表 | 28篇 |
建筑科学 | 29篇 |
能源动力 | 79篇 |
轻工业 | 179篇 |
水利工程 | 1篇 |
石油天然气 | 2篇 |
无线电 | 97篇 |
一般工业技术 | 264篇 |
冶金工业 | 140篇 |
原子能技术 | 57篇 |
自动化技术 | 139篇 |
出版年
2024年 | 2篇 |
2023年 | 9篇 |
2022年 | 29篇 |
2021年 | 40篇 |
2020年 | 19篇 |
2019年 | 24篇 |
2018年 | 36篇 |
2017年 | 26篇 |
2016年 | 62篇 |
2015年 | 36篇 |
2014年 | 59篇 |
2013年 | 95篇 |
2012年 | 79篇 |
2011年 | 109篇 |
2010年 | 88篇 |
2009年 | 88篇 |
2008年 | 92篇 |
2007年 | 66篇 |
2006年 | 46篇 |
2005年 | 51篇 |
2004年 | 57篇 |
2003年 | 43篇 |
2002年 | 26篇 |
2001年 | 14篇 |
2000年 | 20篇 |
1999年 | 25篇 |
1998年 | 61篇 |
1997年 | 30篇 |
1996年 | 29篇 |
1995年 | 26篇 |
1994年 | 18篇 |
1993年 | 17篇 |
1992年 | 8篇 |
1991年 | 9篇 |
1990年 | 10篇 |
1989年 | 6篇 |
1988年 | 3篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1971年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有1501条查询结果,搜索用时 15 毫秒
31.
Dynamic mechanical properties of photopolymerizable poly(vinyl alcohol) (PVA)–monoacrylate blends were investigated by measuring dynamic shear modulus G′ and loss tangent, tan δ. The dynamic mechanical properties of the blends before being exposed to UV irradiation were governed by the weight percent of the monomers which act as plasticizers. On the other hand, the UV-irradiated blends seemed to be typical two-phase materials since they revealed two tan δ maxima whose positions were independent of the monomer content. Those two maxima were assigned to PVA and photopolymerized acrylates with reference to the dynamic mechanical data of PVA and a PVA-polyacrylamide polyblend. Those dynamic mechanical data suggested that insolubilization of the blend type photopolymers should be caused by a decrease in solubility due to graft polymerization of acrylate monomers onto PVA. 相似文献
32.
Meng Guo Masakoto Kanezashi Hiroki Nagasawa Liang Yu Kazuki Yamamoto Takahiro Gunji Toshinori Tsuru 《American Institute of Chemical Engineers》2020,66(4):e16850
Fine-tuned, molecular-composite, organosilica membranes were fabricated via the co-condensation of organosilica precursors bis(triethoxysilyl)acetylene (BTESA) and bis(triethoxysilyl)benzene (BTESB). Fourier transform infrared and UV–vis spectra confirmed the co-condensation behaviors of BTESA and BTESB. The evolution of the network structure indicated that the incorporated BTESB decreased the membrane pore size, which was determined by a modified gas translation model according to the steric effect of the phenyl groups. The incorporation of BTESB to BTESA finely tuned the membrane structure and endowed the resultant composite membrane with improved separation properties. The BTESAB 9:1 membrane (molar ratio of BTESA/BTESB was 9:1) exhibited high C3H6 permeance at 4.5 × 10−8 mol m−2 s−1 Pa−1 and a C3H6/C3H8 permeance ratio of 33 at 50°C. One of the most important developments of this study involved clearly defining the relationship between membrane pore size and C3H6/C3H8 separation performance for organosilica membranes in single and binary separation systems. 相似文献
33.
Morphology‐dependent electrocatalytic activity of nanostructured Pt/C particles from hybrid aerosol–colloid process 下载免费PDF全文
Ratna Balgis Aditya F. Arif Takahiro Mori Takashi Ogi Kikuo Okuyama Gopinathan M. Anilkumar 《American Institute of Chemical Engineers》2016,62(2):440-450
An optimum nanostructure and pore size of catalyst supports is very important in achieving high catalytic performances. In this instance, we evaluated the effects of various carbon nanostructures on the catalytic performances of carbon‐supported platinum (Pt/C) electrocatalysts experimentally and numerically. The Pt/C catalysts were prepared using a hybrid method involving the preparation of dense, hollow, and porous nanostructured carbon particle via aerosol spray pyrolysis followed by microwave‐assisted Pt deposition. Electrochemical characterization of the catalysts showed that the porous Pt/C catalyst gave the best performance; its electrochemical surface area was much higher, more than twice than those of hollow or dense Pt/C. The effects of pore size on electrocatalysis were also studied. The results showed the importance of a balance between mesopores and macropores for effective catalysis with a high charge transfer rate. A fluid flow model showed that good oxygen transport contributed to the catalytic activity. © 2015 American Institute of Chemical Engineers AIChE J, 62: 440–450, 2016 相似文献
34.
Youichirou Higashi Takaaki Aratake Takahiro Shimizu Shogo Shimizu Motoaki Saito 《International journal of molecular sciences》2021,22(15)
Stroke is a major cause of death worldwide, leading to serious disability. Post-ischemic injury, especially in the cerebral ischemia-prone hippocampus, is a serious problem, as it contributes to vascular dementia. Many studies have shown that in the hippocampus, ischemia/reperfusion induces neuronal death through oxidative stress and neuronal zinc (Zn2+) dyshomeostasis. Glutathione (GSH) plays an important role in protecting neurons against oxidative stress as a major intracellular antioxidant. In addition, the thiol group of GSH can function as a principal Zn2+ chelator for the maintenance of Zn2+ homeostasis in neurons. These lines of evidence suggest that neuronal GSH levels could be a key factor in post-stroke neuronal survival. In neurons, excitatory amino acid carrier 1 (EAAC1) is involved in the influx of cysteine, and intracellular cysteine is the rate-limiting substrate for the synthesis of GSH. Recently, several studies have indicated that cysteine uptake through EAAC1 suppresses ischemia-induced neuronal death via the promotion of hippocampal GSH synthesis in ischemic animal models. In this article, we aimed to review and describe the role of GSH in hippocampal neuroprotection after ischemia/reperfusion, focusing on EAAC1. 相似文献
35.
Zako T Sakono M Kobayashi T Sörgjerd K Nilsson KP Hammarström P Lindgren M Maeda M 《Chembiochem : a European journal of chemical biology》2012,13(3):358-363
Needles and noodles: Studying amyloid toxicity is important for understanding protein misfolding diseases. Using a luminescent conjugated polythiophene, we found that cell binding of nontoxic filamentous amyloids of insulin and β2-microglobulin was less efficient than that of toxic fibrillar amyloids; this suggests a correlation between amyloid toxicity and cell binding. 相似文献
36.
Bulk glass having a calcium-mica composition (Ca0.5Mg3AlSi3O10F2) is homogeneous glass. The crystallization mechanism of the mica is surface crystallization and transparency is lost completely when crystallization occurs on the surface. In this study, by decreasing SiO2 and increasing CaO and Al2O3 from the chemical composition of Ca0.5Mg3AlSi3O10F2, and moreover by replacing a small amount of K2O instead of CaO, the phase separation appears in the glasses. Because of this phase separation, the mica begins to be crystallized not only on the surface but also in the bulk at lower temperatures. Consequently, the novel transparent machinable mica glass-ceramic can be obtained by heating the glasses having the chemical composition of Ca0.6Mg3Al1.2Si2.8O10F2 and K0.01Ca0.595Mg3Al1.2Si2.8O10F2. As a larger amount of calcium-mica is separated, the bending strength decreases and the fracture toughness increases. Furthermore, by replacing K+ ion instead of Ca2+ ion in the interlayer of calcium-mica, the interlayer bonding strength becomes high, resulting in the increase of the bending strength. 相似文献
37.
Increasing the reaction temperature of the living cationic polymerization of isobutylene is crucial for industrial production due to the cost of refrigeration. The reaction temperature increase was achieved with an accelerated reaction rate using a flow reaction system. The polymerization conditions, including the flow reactor design, were based on the results of kinetic studies. Utilizing a milli‐scale flow reactor, polyisobutylene, which has a narrow molecular weight distribution, was obtained within a considerably short residence time at a high temperature. Furthermore, it was confirmed that the value of Mw/Mn correlates with the product of the Reynolds number and the angle of collision. 相似文献
38.
39.
Takahiro Kochi Masahito Shimizu Tomohiko Ohno Atsushi Baba Takafumi Sumi Masaya Kubota Yohei Shirakami Hisashi Tsurumi Takuji Tanaka Hisataka Moriwaki 《International journal of molecular sciences》2013,14(7):14700-14711
Metabolic syndrome is associated with an increased risk of colorectal cancer. This study investigated the impact of hypertension, a component of metabolic syndrome, on azoxymethane (AOM)-induced colorectal carcinogenesis using SHRSP/Izm (SHRSP) non-diabetic/hypertensive rats and SHRSP.Z-Leprfa/IzmDmcr (SHRSP-ZF) diabetic/hypertensive rats. Male 6-week-old SHRSP, SHRSP-ZF, and control non-diabetic/normotensive Wister Kyoto/Izm (WKY) rats were given 2 weekly intraperitoneal injections of AOM (20 mg/kg body weight). Two weeks after the last injection of AOM, the SHRSP and SHRSP-ZF rats became hypertensive compared to the control WKY rats. Serum levels of angiotensin-II, the active product of the renin-angiotensin system, were elevated in both SHRSP and SHRSP-ZF rats, but only the SHRSP-ZF rats developed insulin resistance, dyslipidemia, and hyperleptinemia and exhibited an increase in adipose tissue. The development of AOM-induced colonic preneoplastic lesions and aberrant crypts foci, was significantly accelerated in both SHRSP and SHRSP-ZF hypertensive rats, compared to WKY normotensive rats. Furthermore, induction of oxidative stress and exacerbation of inflammation were observed in the colonic mucosa and systemically in SHRSP and SHRSP-ZF rats. Our findings suggest that hypertension plays a role in the early stage of colorectal carcinogenesis by inducing oxidative stress and chronic inflammation, which might be associated with activation of the renin-angiotensin system. 相似文献
40.
Preparation of porous carbons from thermoplastic precursors and their performance for electric double layer capacitors 总被引:2,自引:0,他引:2
Porous carbons with high surface area were successfully prepared from thermoplastic precursors, such as poly(vinyl alcohol) (PVA), hydroxyl propyl cellulose and poly(ethylene terephthalate), by the carbonization of a mixture with MgO at 900 °C in an inert atmosphere. After carbonization the MgO was dissolved out using a diluted sulfuric acid and the carbons formed were isolated. The mixing of the PVA carbon precursor with the MgO precursors (reagent grade MgO, magnesium acetate or citrate) was done either in powder form or in an aqueous solution. The BET surface area of the carbons obtained via solution mixing could reach a very high value, such as 2000 m2/g, without any activation process. The pore structure of the resultant carbons was found to depend strongly on the mixing method; the carbons prepared via solution mixing were rich in mesopores, but those produced via powder mixing were rich in micropores. The size of mesopores was found to be almost the same as that of the MgO particles, suggesting a way of controlling the mesopore size in the resultant carbons. Measurement of capacitance was carried out in 1 mol/L H2SO4 electrolyte. The porous carbon with a BET surface area of 1900 m2/g prepared at 900 °C through solution mixing of Mg acetate with PVA showed a fairly high EDLC capacitance, about 250 F/g with a current density of 20 mA/g and 210 F/g with 1000 mA/g. The rate performance was closely related to the mesoporous surface area. 相似文献