Carbon nanotube growth from semiconductor nanoparticles

Nanoscale metal catalysts have been indispensable for carbon nanotube (CNT) synthesis by chemical vapor deposition (CVD). We show that even semiconductor nanoparicles of SiC, Ge, and Si produce single-walled and double-walled CNTs in CVD with ethanol. This implies that nanosize structures might act as a template for the formation of CNT caps composed of five- and six-membered rings. Providing a template for cap formation is the essential role of the catalysts.     

Slippage of 4He Films and Precursor Phenomenon of Superfluidity

We have carried out quartz crystal microbalance (QCM) experiments for ⁴He films on an exfoliated single-crystalline graphite using a 32 kHz tuning fork, and have measured the temperature dependence of the resonance frequency and the Q value for various areal densities and oscillation amplitudes. Comparing with the previous experiments for Grafoil, the decoupling of the films due to the slippage or the superfluidity was larger than that of Grafoil, and the competition between the slippage and the superfluidity was observed in three-atom thick films. Furthermore, it was found that the slippage is suppressed gradually at higher temperature than the superfluid onset T _c , and that the relaxation time decreases at low temperatures while it obeys the Arrhenius law at high temperatures. These results suggest a precursor to the superfluidity of ⁴He films.     

Proton conduction at the surface of Y-doped BaCeO3 and its application to an air/fuel sensor

25 mol% Y³⁺-doped BaCeO₃ (BCY25) showed an extremely low activation energy of 0.3 eV for proton conduction at the surface. The resulting overall conductivity at the surface reached 8.24 × 10^–3 S cm^–1 at 400°C, which was 3, 8, and 28 times higher than those in the bulk of BCY25, 20 mol% Sm³⁺-doped ceria, and 8 mol% yttria-stabilized zirconia, respectively. Such fast proton conduction enabled an air/fuel (A/F ) sensor using BCY25 as the solid electrolyte to work above 150°C for H₂ and above 250°C for C₂H₄.     

Revolving Vernier Mechanism Controls Size of Linear Homomultimer

A new kind of the Vernier mechanism that is able to control the size of linear assembly of DNA origami nanostructures is proposed. The mechanism is realized by mechanical design of DNA origami, which consists of a hollow cylinder and a rotatable shaft in it connected through the same scaffold. This nanostructure stacks with each other by the shape complementarity at its top and bottom surfaces of the cylinder, while the number of stacking is limited by twisting angle of the shaft. Experiments have shown that the size distribution of multimeric assembly of the origami depends on the twisting angle of the shaft; the average lengths of the multimer are decamer, hexamer, and tetramer for 0°, 10°, and 20° twist, respectively. In summary, it is possible to affect the number of polymerization by adjusting the precise shape and movability of a molecular structure.     

Characterisation of optically driven microstructures for manipulating single DNA molecules under a fluorescence microscope

Optical tweezers are powerful tools for manipulating single DNA molecules using fluorescence microscopy, particularly in nanotechnology‐based DNA analysis. We previously proposed a manipulation technique using microstructures driven by optical tweezers that allows the handling of single giant DNA molecules of millimetre length that cannot be manipulated by conventional techniques. To further develop this technique, the authors characterised the microstructures quantitatively from the view point of fabrication and efficiency of DNA manipulation under a fluorescence microscope. The success rate and precision of the fabrications were evaluated. The results indicate that the microstructures are obtained in an aqueous solution with a precision ∼50 nm at concentrations in the order of 10⁶ particles/ml. The visibility of these microstructures under a fluorescence microscope was also characterised, along with the elucidation of the fabrication parameters needed to fine tune visibility. Manipulating yeast chromosomal DNA molecules with the microstructures illustrated the relationship between the efficiency of manipulation and the geometrical shape of the microstructure. This report provides the guidelines for designing microstructures used in single DNA molecule analysis based on on‐site DNA manipulation, and is expected to broaden the applications of this technique in the future.Inspec keywords: DNA, molecular biophysics, fluorescence, optical microscopy, radiation pressure, biological techniquesOther keywords: optically driven microstructures, single DNA molecule analysis, fluorescence microscopy, optical tweezers, nanotechnology‐based DNA analysis, manipulation technique, aqueous solution, fine tune visibility, yeast chromosomal DNA molecules, geometrical shape, on‐site DNA manipulation     

An intermittent control model of flexible human gait using a stable manifold of saddle-type unstable limit cycle dynamics

Stability of human gait is the ability to maintain upright posture during walking against external perturbations. It is a complex process determined by a number of cross-related factors, including gait trajectory, joint impedance and neural control strategies. Here, we consider a control strategy that can achieve stable steady-state periodic gait while maintaining joint flexibility with the lowest possible joint impedance. To this end, we carried out a simulation study of a heel-toe footed biped model with hip, knee and ankle joints and a heavy head-arms-trunk element, working in the sagittal plane. For simplicity, the model assumes a periodic desired joint angle trajectory and joint torques generated by a set of feed-forward and proportional-derivative feedback controllers, whereby the joint impedance is parametrized by the feedback gains. We could show that a desired steady-state gait accompanied by the desired joint angle trajectory can be established as a stable limit cycle (LC) for the feedback controller with an appropriate set of large feedback gains. Moreover, as the feedback gains are decreased for lowering the joint stiffness, stability of the LC is lost only in a few dimensions, while leaving the remaining large number of dimensions quite stable: this means that the LC becomes saddle-type, with a low-dimensional unstable manifold and a high-dimensional stable manifold. Remarkably, the unstable manifold remains of low dimensionality even when the feedback gains are decreased far below the instability point. We then developed an intermittent neural feedback controller that is activated only for short periods of time at an optimal phase of each gait stride. We characterized the robustness of this design by showing that it can better stabilize the unstable LC with small feedback gains, leading to a flexible gait, and in particular we demonstrated that such an intermittent controller performs better if it drives the state point to the stable manifold, rather than directly to the LC. The proposed intermittent control strategy might have a high affinity for the inverted pendulum analogy of biped gait, providing a dynamic view of how the step-to-step transition from one pendular stance to the next can be achieved stably in a robust manner by a well-timed neural intervention that exploits the stable modes embedded in the unstable dynamics.     

Automated 360° profilometry of a three-dimensional diffuse object and its reconstruction by use of the shading model

The 360° profilometry of a three-dimensional (3-D) diffuse object by use of the light intersection and its image reconstruction by surface shading are presented. The lack of data in one direction, which was due to occlusion, was compensated by the projection of two lines of light from different directions. Some experiments to profile objects and their reconstruction by computer are shown. The entire surface model was constructed, and a real shading image was obtained by means of computer graphics.     

Cermet-type hydrogen separation membrane obtained from fine particles of high temperature proton-conductive oxide and palladium

A mixed ionic and electronic conducting hydrogen separation membrane, which consisted of proton-conductive oxide and metallic palladium, was fabricated. A porous alumina tube was employed as a support, and proton-conductive oxide particles were introduced into a microporous top layer of the support by an impregnation method. Palladium particles were deposited into the same porous layer by chemical vapor deposition. Hydrogen permeated preferentially via the membrane thus obtained with a hydrogen permeance (PH₂) of 1.2 × 10^− 9 mol·m^− 2·s^− 1·Pa^− 1 at 873 K. Selectivity for hydrogen (PH₂/PN₂) increased with the operating temperature due to an increase in proton conductivity of the membrane, and PH₂/PN₂ = 5.7 was attained at 873 K.