A comparative study of English viseme recognition methods and algorithms

Multimedia Tools and Applications - An elementary visual unit – the viseme is concerned in the paper in the context of preparing the feature vector as a main visual input component of...     

The VFO-Driven Motion Planning and Feedback Control in Polygonal Worlds for a Unicycle with Bounded Curvature of Motion

Integrated motion planning and control for the purposes of maneuvering mobile robots under state- and input constraints is a problem of vital practical importance in applications of mobile robots such as autonomous transportation. Those constraints arise naturally in practice due to specifics of robot mechanical construction and the presence of obstacles in motion environment. In contrast to approaches focusing on feedback control design under the assumption of given reference motion or motion planning with neglection of subsequent feedback motion execution, we adopt a controller-driven motion planning paradigm, which has recently gained attention of many researchers. It postulates design of motion planning algorithms dedicated to specific feedback control policies, which compute a sequence of feedback control subtasks instead of classically planned open-loop controls or parametric paths. In this spirit, we propose a motion planning algorithm driven by the VFO (Vector Field Orientation) control law for the waypoint-following task. Presented analysis of the VFO control law reveals its beneficial properties, which are subsequently utilized to solve a generally nonlinear and non-convex optimal motion planning problem by formulating it as a mixed-integer linear program (MILP). The solution proposed in this paper yields a waypoint sequence, which is designed for execution by application of the VFO control law to drive a robot to a prescribed final configuration under an input constraint imposed by bounded curvature of robot motion and state constraints resulting from a convex decomposition of task space. Satisfaction of these constraints is guaranteed analytically and exactly, i.e., without utilization of numerical approximations. Moreover, for a given discrete set of possible waypoint orientations, the proposed algorithm computes plans optimal w.r.t. given cost functional, which can be any convex linear combination of quantities such as robot path length, curvature of robot motion, distance to imposed state constraints, etc. Furthermore, the planning algorithm exploits the possibility of both forward or backward movement of the robot to allow maneuvering in demanding environments. Generated waypoint sequences are a compact representation of a motion plan, which can be immediately executed with the VFO controller without any additional post-processing. Validity of the proposed approach has been confirmed by simulation studies and experimental motion execution with a laboratory-scale mobile robot.     

Thermal diffusivity in polymers oriented uniaxially in the solid and in the molten state

Measurements of thermal diffusivity were carried out with semicrystalline and amorphous polymers stretched in the solid and in the molten state to different elongations. For semi-crystalline materials two regions in the curves of the diffusivity versus the elongation can be detected. The change occurs at an elongation of 1.4 for the polymers stretched in the solid state and at an elongation of 3 for the polymers stretched in the molten state. For amorphous polystyrene the shape of the curves of thermal diffusivity versus elongation also depends on the mode of stretching. Along with thermal diffusivity measurements, wide angle X-ray scattering investigations were also performed and give explanations for the differences in thermal behavior.     

The Palladium(II) Complex of Aβ4−16 as Suitable Model for Structural Studies of Biorelevant Copper(II) Complexes of N-Truncated Beta-Amyloids

The Aβ4−42 peptide is a major beta-amyloid species in the human brain, forming toxic aggregates related to Alzheimer’s Disease. It also strongly chelates Cu(II) at the N-terminal Phe-Arg-His ATCUN motif, as demonstrated in Aβ4−16 and Aβ4−9 model peptides. The resulting complex resists ROS generation and exchange processes and may help protect synapses from copper-related oxidative damage. Structural characterization of Cu(II)Aβ4−x complexes by NMR would help elucidate their biological function, but is precluded by Cu(II) paramagneticism. Instead we used an isostructural diamagnetic Pd(II)-Aβ4−16 complex as a model. To avoid a kinetic trapping of Pd(II) in an inappropriate transient structure, we designed an appropriate pH-dependent synthetic procedure for ATCUN Pd(II)Aβ4−16, controlled by CD, fluorescence and ESI-MS. Its assignments and structure at pH 6.5 were obtained by TOCSY, NOESY, ROESY, 1H-13C HSQC and 1H-15N HSQC NMR experiments, for natural abundance 13C and 15N isotopes, aided by corresponding experiments for Pd(II)-Phe-Arg-His. The square-planar Pd(II)-ATCUN coordination was confirmed, with the rest of the peptide mostly unstructured. The diffusion rates of Aβ4−16, Pd(II)-Aβ4−16 and their mixture determined using PGSE-NMR experiment suggested that the Pd(II) complex forms a supramolecular assembly with the apopeptide. These results confirm that Pd(II) substitution enables NMR studies of structural aspects of Cu(II)-Aβ complexes.     

Real-time background generation and foreground object segmentation for high-definition colour video stream in FPGA device

The processing of a high-definition video stream in real-time is a challenging task for embedded systems. However, modern FPGA devices have both a high operating frequency and sufficient logic resources to be successfully used in these tasks. In this article, an advanced system that is able to generate and maintain a complex background model for a scene as well as segment the foreground for an HD colour video stream (1,920 × 1,080 @ 60 fps) in real-time is presented. The possible application ranges from video surveillance to machine vision systems. That is, in all cases, when information is needed about which objects are new or moving in the scene. Excellent results are obtained by using the CIE Lab colour space, advanced background representation as well as integrating information about lightness, colour and texture in the segmentation step. Finally, the complete system is implemented in a single high-end FPGA device.     

Design,Synthesis, and Evaluation of ω‐(Isothiocyanato)alkylphosphinates and Phosphine Oxides as Antiproliferative Agents

A series of 21 novel, structurally diverse ω‐(isothiocyanato)alkylphosphinates and phosphine oxides (ITCs) were designed and synthesized in moderate to good yields. The synthesized compounds were evaluated for in vitro antiproliferative activity using LoVo and LoVo/DX cancer cell lines. The biological activity of the synthesized compounds was higher than that of natural isothiocyanates such as benzyl isothiocyanate or sulforaphane. The antiproliferative activity of selected ITCs was also tested on selected cancer cell lines: A549, MESSA and MESSA/DX‐5, HL60 and HL60MX2, BALB/3T3, and 4T1. These compounds were assessed for their mechanism of action as inducers of cell‐cycle arrest and apoptosis. Ethyl (6‐isothiocyanatohexyl)(phenyl)phosphinate ( 71 ) was tested in vivo on the 4T1 cell line and demonstrated moderate antitumor activity, similar to that benzyl isothiocyanate and cyclophosphamide.     

Authenticity Assessment of the “Onisiówka” <Emphasis Type="Italic">Nalewka</Emphasis> Liqueurs Using Two-Dimensional Gas Chromatography and Sensory Evaluation

The “Onisiówka” nalewka liqueur is a regional Polish alcoholic beverage, which is inscribed on the list of regional and traditional products of the Ministry of Agriculture and Rural Development in Poland. It is produced from multiflower honey, black elderberry flower syrup, and spirit. Due to fact that the “Onisiówka” nalewka liqueur has never been investigated, these studies are the foundation for further work on this regional alcoholic beverage. The main aim of this work is the authenticity assessment of the “Onisiówka” nalewka liqueurs by means of qualitative characteristics of volatile fraction and sensory evaluation. Tentative identification has been performed using two-dimensional gas chromatography coupled with time-of-flight mass spectrometry (GC×GC-TOFMS). Application of GC×GC-TOFMS allowed for detection of around 350 compounds present in the volatile fraction of the “Onisiówka” from which 102 compounds were tentatively identified. PCA results showed that the first two principal components constitute 96.98% of total variance. Statistical analysis was used to visualize relations between tentatively identified compounds; therefore, it has been demonstrated that 23 chemical compounds may have significant influence on the overall flavor and taste of the “Onisiówka”. These substances belong to four chemical classes, in which the greatest number is represented by esters (13), aldehydes (6), alcohols (3), and one terpene compound. According to the sensory evaluation, the Onisiówka is characterized by sweet, honey, fruity, flowery, bitter, and spirituous flavor and taste.     

Effect of temperature and initial dibutyl sulfide concentration in chloroform on its oxidation rate by ozone

A scheme of dibutyl sulfide (DBS) oxidation with ozone and generation of transitional products was determined in this study. The main identified intermediate product was dibutyl sulfoxide (DBSO), and the main end product of DBS oxidation was dibutyl sulfone (DBSO2). It was determined that for three temperatures: 0, 10 and 20 degrees C there was certain initial DBS concentration for which half-times observed in experimental conditions were equal and independent from temperature. Generation of phosgene and water as by-products was confirmed for the reaction of DBS with ozone in chloroform. Results of the described study allowed to present generalized mechanism of sulfide oxidation with ozone.     

Zn(1-x)MnxTe diluted magnetic semiconductor nanowires grown by molecular beam epitaxy

It is shown that the growth of II-VI diluted magnetic semiconductor nanowires is possible by the catalytically enhanced molecular beam epitaxy (MBE). Zn(1-x)MnxTe NWs with manganese content up to x=0.60 were produced by this method. X-ray diffraction, Raman spectroscopy, and temperature dependent photoluminescence measurements confirm the incorporation of Mn(2+) ions in the cation substitutional sites of the ZnTe matrix of the NWs.