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41.
42.
The productivity of a peroxidase (DyP) originating from Geotrichum candidum Dec 1 was enhanced in the solid-state culture using Aspergillus oryzae RD005. When the humidity, water content, and temperature were adjusted to 60%, 50% and 27 degrees C, respectively, the productivity of DyP reached 5.3 g per kilogram wheat bran, which was used as the solid medium. The yield of 5.3 g per kg wheat bran corresponded to the yield of a 56 kg submerged culture. The productivity per gram carbon of the medium in the solid-state culture was 4.1-fold that in the submerged culture. 相似文献
43.
Ryuichi Sugimoto Hideyuki Kaneko Junji Saito Nobuo Kawahara Shingo Matsuo Tomoaki Matsugi 《Polymer Bulletin》2014,71(6):1421-1431
This paper introduces the new synthetic methodology of polyolefin-based block and graft copolymers with polar segments [e.g., polystyrene and poly(meth)acrylates]. Various brominated polyolefins were prepared by bromination of polyolefins with N-bromosuccinimide. The resulting brominated polyolefins were able to initiate the controlled radical polymerization of polar monomers, such as methyl methacrylate, ethyl acrylate, t-butyl acrylate, styrene and 2-(dimethylamino)ethyl acrylate, using a CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine catalyst system, leading to a variety of polyolefin-based copolymers with a different content of the corresponding polar segment. Because of the accessible synthesis of polyolefin macroinitiators, this synthetic methodology is expected to result in the preparation of a wide range of polyolefin-based block and graft copolymers. 相似文献
44.
Dual throat nozzle (DTN) is fast becoming a popular technique for thrust vectoring. The DTN is designed with two throats, an upstream minimum and a downstream minimum at the nozzle exit, with a cavity in between the upstream throat and exit. In the present study, a computational work has been carried out to analyze the performance of a dual throat nozzle at various mass flow rates of secondary flow and nozzle pressure ratios (NPR). Two-dimensional, steady, compressible Navier-Stokes equations were solved using a fully implicit finite volume scheme. The present computational results were validated with available experimental data. Based on the present results, the control effectiveness of thrust-vectoring is discussed in terms of the thrust coefficient and the coefficient of discharge. 相似文献
45.
46.
Takashi Tanaka Yosuke Matsuo Isao Kouno 《International journal of molecular sciences》2010,11(1):14-40
This review will discuss recent progress in the chemistry of secondary polyphenols produced during food processing. The production mechanism of the secondary polyphenols in black tea, whisky, cinnamon, and persimmon fruits will be introduced. In the process of black tea production, tea leaf catechins are enzymatically oxidized to yield a complex mixture of oxidation products, including theaflavins and thearubigins. Despite the importance of the beverage, most of the chemical constituents have not yet been confirmed due to the complexity of the mixture. However, the reaction mechanisms at the initial stages of catechin oxidation are explained by simple quinone–phenol coupling reactions. In vitro model experiments indicated the presence of interesting regio- and stereoselective reactions. Recent results on the reaction mechanisms will be introduced. During the aging of whisky in oak wood barrels, ellagitannins originating from oak wood are oxidized and react with ethanol to give characteristic secondary ellagitannins. The major part of the cinnamon procyanidins is polymerized by copolymerization with cinnamaldehyde. In addition, anthocyanidin structural units are generated in the polymer molecules by oxidation which accounts for the reddish coloration of the cinnamon extract. This reaction is related to the insolubilization of proanthocyanidins in persimmon fruits by condensation with acetaldehyde. In addition to oxidation, the reaction of polyphenols with aldehydes may be important in food processing. 相似文献
47.
T. Katsumi H. Kodama T. Matsuo H. Ogawa N. Tsuboi K. Hori 《Combustion, Explosion, and Shock Waves》2009,45(4):442-453
A new composition of hydroxylammonium nitrate based solution containing ammonium nitrate, methanol, and water was developed
for monopropellant in a reaction control system (RCS) as an alternative to conventional hydrazine. In comparison with hydrazine,
this solution has a 20% higher specific impulse, 1.4 times higher density, and lower freezing point and toxicity. The linear
burning rate of the solution is moderate at the operating pressures of RCS thrusters. It was found that the linear burning
rate had some characteristics whose mechanisms had not been understood. The combustion mechanism of this solution was investigated.
The burning behavior was observed using a medium speed camera, and a temperature profile for the combustion wave was measured
with a 2.5 μm diameter thermocouple. From these results, the instability of the liquid-gas interface may trigger a sudden
increase in the burning rate, and methanol was found to be effective in reducing the bubble growth rate in the solution. The
reactivity of several catalysts was evaluated in an open-cup test, and the S405 catalyst for hydrazine showed the best performance
among them. Thruster tests were conducted using the S405 catalyst with variation in the propellant mass flow rate, catalyst
bed configuration, and length-to-diameter ratio of the combustor. As a result, parameters were determined that ensured long
operating time. The model thruster operated stably for up to 100 sec with a specific impulse I
sp = 240 sec, which corresponds to a 90% efficiency.
__________
Translated from Fizika Goreniya i Vzryva, Vol. 45, No. 4, pp. 109–120, July–August, 2009.
An erratum to this article can be found at 相似文献
48.
Electrical and dielectric behaviors and their origins in the three-dimensional polyvinyl alcohol/MWCNT composites with low percolation threshold 总被引:1,自引:0,他引:1
The electrical conductivity and dielectric behavior of a three-dimensional composite of polyvinyl alcohol (PVA) and multiwalled nanotubes (MWCNTs) were measured and an extremely low percolation threshold was observed. Two established theories were used to investigate the behaviors of the composites near the percolation threshold, and then the results indicated that the intercluster polarization effect is more reasonable to explain the electrical property of our system in the frequency range of measurement. The high value of the dielectric constant of the composites was attributed to interfacial polarization within the bulk sample and DC conductance based on charge injection at electrode-sample interface. Thus an equivalent circuit was established by separating the behavior of the bulk sample from that of the electrode-sample interface. The introduction of the concept of Constant Phase Element into the equivalent circuit model gave a fit in good agreement with the experimental data and implied the influence of a fractal interface on the real capacitance. The interfacial polarization and the relaxation processes were fully studied. As a result, the activation energy associated with those relaxation processes in the composites was thought to be the energy needed for the charges accumulating and bounded on the interfaces between MWCNT and PVA. 相似文献
49.
Suehiro J. Yamasaki K. Matsuo H. Hara M. Gerhold J. 《Dielectrics and Electrical Insulation, IEEE Transactions on》1994,1(3):403-406
Information about breakdown time-lags under pulsed voltage stress is prerequisite to the insulation design of superconducting devices. Experiments have been carried out using a pulse generator which provides a step voltage with 200 ns rise time and a long decay time constant of more than 1 ms. The present experiments may bridge the information gap between time lag measurements in the ns range using extremely high field strengths, and existing data found with usual lightning impulse voltage. The test device is described in the paper, and some typical results are discussed in detail 相似文献
50.
Discovering emerging topics from WWW has been attracting attention of business professionals, especially marketing researchers. For this purpose, WWW can be a valuable source of information because it reflects the dynamics of human society. In this paper we aim at revealing the structure of WWW by using KeyGraph, a visualization method of hidden structure behind data, for understanding emerging topics. 相似文献