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991.
Hideyuki Nojima Takashi Shimoda Shinsuke Inagi Toshio Fuchigami 《Israel journal of chemistry》2024,64(1-2):e202300025
Various anodic substitution reactions such as fluorination, methoxylation, acetoxylation, and cyanation of heteroatom compounds containing a sulfur or nitrogen atom were comparatively studied using boron-doped diamond (BDD), Pt, and glassy carbon (GC) anodes. It was found that BDD anode is highly effective for these anodic substitution reactions similarly to Pt anode although both BDD and GC electrodes are carbon-based materials. 相似文献
992.
Dr. Haruka Hiraoka Dr. Zhaoma Shu Dr. Bao Tri Le Dr. Keiko Masuda Dr. Kosuke Nakamoto Lyu Fangjie Dr. Naoko Abe Dr. Fumitaka Hashiya Dr. Yasuaki Kimura Dr. Yoshihiro Shimizu Prof. Dr. Rakesh N. Veedu Prof. Dr. Hiroshi Abe 《Chembiochem : a European journal of chemical biology》2021,22(24):3437-3442
We have found that antisense oligonucleotides and siRNA molecules modified with repeat structures of disulfide units can be directly introduced into the cytoplasm and exhibit a suppressive effect on gene expression. In this study, we analyzed the mechanism of cellular uptake of these membrane-permeable oligonucleotides (MPONs). Time-course analysis by confocal microscopy showed that the uptake of MPONs from the plasma membrane to the cytoplasm reached 50 % of the total uptake in about 5 min. In addition, analysis of the plasma membrane proteins to which MPONs bind, identified several proteins, including voltage-dependent anion channel. Next, we analyzed the behavior of MPONs in the cell and found them to be abundant in the nucleus as early as 24 h after addition with the amount increasing further after 48 and 72 h. The amount of MPONs was 2.5-fold higher than that of unmodified oligonucleotides in the nucleus after 72 h. We also designed antisense oligonucleotides and evaluated the effect of MPONs on mRNA exon skipping using DMD model cells; MPONs caused exon skipping with 69 % efficiency after 72 h, which was three times higher than the rate of the control. In summary, the high capacity for intracytoplasmic and nuclear translocation of MPONs is expected to be useful for therapeutic strategies targeting exon skipping. 相似文献
993.
Yuki Kojima Koji Inazu Yoshiharu Hisamatsu Hiroshi Okochi Toshihide Baba Toshio Nagoya 《Polycyclic Aromatic Compounds》2013,33(5):321-333
Atmospheric polycyclic aromatic hydrocarbons (PAHs), nitro-PAHs and oxy-PAHs are emitted from primary sources. Some nitro-PAHs and oxy-PAHs can also arise from secondary formation in the atmosphere. To assess the relative importance of these sources, the polycyclic aromatic compound (PAC) concentrations were determined at a roadside (Roadside site) and on a rooftop (Urban Background site) in downtown Tokyo Japan. The concentrations of PAHs, 1-nitropyrene and oxy-PAHs at the Roadside site were higher than those at the Urban Background site, while 2-nitrofluoranthene levels were the same at both sites. However, the mean ratios of concentrations at the Urban Background site to the Roadside site were in the order 1,8-naphthalic anhydride>9,10-anthraquinone>PAHs or 1-nitropyrene or acenaphthenequinone or benzanthrone. This suggests that in addition to vehicle emissions, a considerable fraction of some of the oxy-PAHs studied originates from another source, which might be secondary formation by atmospheric PAH degradation, and this contribution varied among the oxy-PAHs. 相似文献
994.
Kana Takenaka Toshio Sugimoto Akihiro Makino Yoshihiko Hirotsu Akihisa Inoue 《Materials Letters》2009,63(21):1895-1897
With the aim of applying to a soft magnetic underlayer of the double-layered perpendicular magnetic recording media, an Fe74.9B17.5Si2.5Nb5.1 alloy thin film was fabricated on Si substrate by a pulsed laser deposition method. The Fe-based alloy thin film of 200 nm in thickness was confirmed as a glassy structure. The thermal properties of the thin film have similar features to those for the melt-spun glassy alloy ribbon. The glassy alloy thin film exhibits good soft magnetic properties, i.e., high Bs of 1.2 T and in-plane low Hc of 134 A/m. The Fe-B-Si-Nb glassy alloy thin film is expected to be suitable for the soft magnetic underlayer material in the double-layered perpendicular magnetic recording media. 相似文献
995.
A. Suemasu K. Nakahata K. Ro T. Kamiya C. M. Fortmann I. Shimizu 《Solar Energy Materials & Solar Cells》2001,66(1-4)
Polycrystalline silicon (poly-Si) films were deposited on glass by very high-frequency (100 MHz) plasma enhanced chemical vapor deposition from a gaseous mixture of SiF4 and H2 with small amounts of SiH4. (2 2 0) oriented films prepared at small SiF4/H2 ratios (<30/40 sccm) showed intrinsic transport properties of poly-Si. However, the room temperature dark conductivity (σd) of the (4 0 0) oriented film was very high for intrinsic poly-Si, 7.2×10−4S/cm. This conductivity exhibited a T−1/4 behavior, suggesting a high defect density at the grain boundaries. It was found that in situ hydrogen plasma treatment successfully produced (4 0 0) oriented poly-Si with a reasonably low σd of 4.5×10−7S/cm and a good photoconductivity of 1.3×10−4S/cm. 相似文献
996.
Yukimi Ichikawa Takashi Yoshida Toshio Hama Hiroshi Sakai Kouichi Harashima 《Solar Energy Materials & Solar Cells》2001,66(1-4)
We have developed a-Si-based solar cells with plastic film substrate and achieved a stabilized efficiency of 9% in a 40 cm×80 cm cell. The structure and fabrication process of flexible solar cells are presented. Then we discuss the merits and demerits of our process from the viewpoint of mass production, and clarify that the SCAF cell has a good adaptability to mass production. 相似文献
997.
Bo Liang Toshio Suzuki Koichi Hamamoto Toshiaki Yamaguchi Yoshinobu Fujishiro Masanobu Awano Brian J. Ingram 《Journal of power sources》2011,196(22):9124-9129
NiO-Fe2O3/gadolinium-doped CeO2 (GDC), NiO-Fe2O3/yttria-stabilized ZrO2 (YSZ) anode supported fuel cells were fabricated at co-sintering temperatures of anode-electrolyte from 1250 °C to 1400 °C. The volumetric shrinkage of the anode-electrolytes and the porosity of the anode tube were studied systematically at different temperatures. 1300 °C is the marginal temperature to obtain sufficient electrocatalytic activity of electrodes, and a higher temperature is needed to suppress gas leakage through the scandia-stabilized zirconia (ScSZ) electrolyte. At each co-sintering temperature from 1250 °C to 1400 °C, the porosity of NiO-Fe2O3/GDC anode tubes is nearly 10% higher than that of NiO-Fe2O3/YSZ anode tubes. SEM results exhibited the anode-supported electrolyte tends to be more dense as co-sintering temperature increasing to 1400 °C from 1250 °C. However, the high co-sintering temperature of 1400 °C will result in low porosity of anode which negatively affected the power density. 相似文献
998.
Ohkubo N. Suzuki M. Shinbo T. Yamanaka T. Shimizu A. Sasaki K. Nakagome Y. 《Solid-State Circuits, IEEE Journal of》1995,30(3):251-257
A 54×54-b multiplier using pass-transistor multiplexers has been fabricated by 0.25 μm CMOS technology. To enhance the speed performance, a new 4-2 compressor and a carry lookahead adder (CLA), both featuring pass-transistor multiplexers, have been developed. The new circuits have a speed advantage over conventional CMOS circuits because the number of critical-path gate stages is minimized due to the high logic functionality of pass-transistor multiplexers. The active size of the 54×54-b multiplier is 3.77×3.41 mm. The multiplication time is 4.4 ns at a 3.5-V power supply 相似文献
999.
Oxidation-Induced Microstructural Change of Si-Ti-C-O Fibers 总被引:2,自引:0,他引:2
Ken-ichi Kakimoto Toshio Shimoo Kiyohito Okamura 《Journal of the American Ceramic Society》1998,81(2):409-412
Two types of Si-Ti-C-O fibers STC(6HS) and STC(6H), with different C/Si molar ratios of 0.99 and 1.65, respectively, have been subjected to oxidation tests at high temperatures between 1000° and 1500°C. Both fibers showed different mass gain during the oxidation tests. In the unoxidized region, there was no change in the chemical composition. For STC(6HS), coarse ß-SiC grains were formed throughout the region, while the grain coarsening in STC(6H) was restricted to the vicinity of the film/fiber interface. In this paper, the influence of free carbon on the oxidation-induced microstructural change of Si-Ti-C-O fibers is discussed. 相似文献
1000.
Kenichi Higashiyama Toshiaki Yaguchi Kengo Akimoto Shigeaki Fujikawa Sakayu Shimizu 《Journal of the American Oil Chemists' Society》1998,75(11):1501-1505
The effect of mineral addition on arachidonic acid (AA) production by Mortierella alpina 1S-4 was evaluated. At first, the addition of minerals such as sodium, potassium, calcium, and magnesium was examined in flask cultures, and then the addition of phosphorus with the optimal amounts of the minerals was investigated in a 10-L jar-fermenter. As a result, 1.5% soy flour medium with the addition of 0.3% KH2PO4, 0.1% Na2SO4, 0.05% CaCl2·2H2O, and 0.05% MgCl2·6H2O was found to enhance the AA yield 1.7-fold over that without mineral addition. When 1% yeast extract with the above mineral mixture was used, the AA yield was enhanced 1.35-fold over that without minerals. We also verified that an increase in the polar lipid content occurred in the case of only KH2PO4 addition, and that the above-mentioned increase in the AA yield was due to the minerals themselves, not a pH buffer effect. 相似文献