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31.
Tuncay Tun? ?brahim Uslu ?enol Durmu?o?lu Selda Keskin Arda Aytimur Ahmet Akdemir 《Journal of Inorganic and Organometallic Polymers and Materials》2012,22(1):105-111
In this study, boron doped and undoped poly (vinyl) alcohol/bismuth–gadolina acetate (PVA/Bi–Gd) nanofibers were prepared
using electrospinning technique then calcinated at 800 °C for 2 h. The originality of this study is the addition of boron
to metal acetates. The effects of boron doping were investigated in terms of solution properties, morphological changes and
thermal characteristics. The characteristics of the fibers were investigated with FT-IR, XRD, SEM and BET. The addition of
boron did not only increase the thermal stability of the fibers, but also their diameters, which yielded stronger fibers.
XRD analyses showed that boron doping increased the peak intensities and indicated that the boron doping enhanced the crystallite
size. Moreover, no shifts were noticed in diffraction angles for boron doped and undoped samples. Therefore, boron doping
did not significantly alter the lattice spacing. The SEM micrograph of the fibers showed that the addition of boron resulted
in the formation of cross-linked bright-surfaced fibers. The average fiber diameter for boron doped and undoped fiber mats
were 204 and 123 nm, respectively. Also, grain diameters of boron doped and undoped nanocrystalline sintered powders were
measured as 140 and 118 nm, respectively. The BET results showed that boron undoped and doped Bi2O3–La2O3 nanocrystalline powder ceramic structures sintered at 800 °C have surface areas of 59.72 and 39.80 m2/g, respectively. 相似文献
32.
Organizations are in the process of moving to a network-based operating structure. Telecommuting is just a corollary of this push. While new information technologies allow for a highly mobile work force that can work from remote locations across the world, this begs the question how does supporting this new telecommuting workforce differ from supporting employees in a regular office. The purpose of this study is to describe how telecommuting and a telecommuter differ from in situ working and the desk-bound worker and how this difference dictates different approaches to providing various services such as IT support services for telecommuters. Our goal is to provide a framework to assist IT managers in addressing issues of how to support telecommuting employees to maximize their potential benefits. 相似文献
33.
Alireza Abbasi Mohammad Ashraful Islam Paul E. Ege Hugo I. de Lasa 《American Institute of Chemical Engineers》2013,59(5):1635-1647
This study contributes with a computational fluid dynamic simulation based on the numerical solution of continuity and momentum balance equations in a three‐dimensional (3‐D) framework. The proposed down flow gas–solid suspension model includes a unit configuration and CD drag coefficients recommended for these units. Computational particle fluid dynamics (CPFD) calculations using suitable boundary conditions and a Barracuda (version: 14.5.2) software allow predicting local solid densification and asymmetric “wavy flows.” In addition, this model forecasts for the conditions of this study higher particle velocity than gas velocity, once the flow reaches 1 m from the gas injector. These findings are accompanied with observations about the intrinsic rotational character of the flow. CPFD numerical 3‐D calculations show that both gas and particle velocities involve the following: (a) an axial velocity component, (b) a radial velocity component (about 5% of axial velocity component), and (c) an angular velocity component. The calculated velocity components and the rotational flow pattern are established for a wide range of solid flux/gas flux ratios. © 2012 American Institute of Chemical Engineers AIChE J, 59: 1635–1647, 2013 相似文献
34.
Ozdemir Erdem Tevfik Kartal Ugur Dikici Tuncay Erol Mustafa Yurddaskal Metin 《Journal of Materials Science: Materials in Electronics》2021,32(23):27398-27408
Journal of Materials Science: Materials in Electronics - In this study, zinc oxide (ZnO) nanowires (NWs) were successfully produced on Zn plates through electrochemical anodization in potassium... 相似文献
35.
Dr. Dirk Kessler Dr. Moriz Mayer Dr. Stephan K. Zahn Dr. Markus Zeeb Dr. Simon Wöhrle Dr. Andreas Bergner Jens Bruchhaus Tuncay Ciftci Dr. Georg Dahmann Maike Dettling Sandra Döbel Dr. Julian E. Fuchs Dr. Leonhard Geist Wolfgang Hela Dr. Christiane Kofink Roland Kousek Franziska Moser Teresa Puchner Dr. Klaus Rumpel Maximilian Scharnweber Patrick Werni Bernhard Wolkerstorfer Dr. Dennis Breitsprecher Dr. Philipp Baaske Dr. Mark Pearson Dr. Darryl B. McConnell Dr. Jark Böttcher 《ChemMedChem》2021,16(9):1420-1424
Aberrant WNT pathway activation, leading to nuclear accumulation of β-catenin, is a key oncogenic driver event. Mutations in the tumor suppressor gene APC lead to impaired proteasomal degradation of β-catenin and subsequent nuclear translocation. Restoring cellular degradation of β-catenin represents a potential therapeutic strategy. Here, we report the fragment-based discovery of a small molecule binder to β-catenin, including the structural elucidation of the binding mode by X-ray crystallography. The difficulty in drugging β-catenin was confirmed as the primary screening campaigns identified only few and very weak hits. Iterative virtual and NMR screening techniques were required to discover a compound with sufficient potency to be able to obtain an X-ray co-crystal structure. The binding site is located between armadillo repeats two and three, adjacent to the BCL9 and TCF4 binding sites. Genetic studies show that it is unlikely to be useful for the development of protein–protein interaction inhibitors but structural information and established assays provide a solid basis for a prospective optimization towards β-catenin proteolysis targeting chimeras (PROTACs) as alternative modality. 相似文献
36.
A conceptual framework, the Interaction Management Network (IMN), that captures the essential structure of any interface from task-oriented specification to object-oriented implementation is presented. IMN is essentially a task-oriented specification scheme based on a semantic network. For each element, as well as for the complete network, there is a direct representation suitable for object-oriented implementation. By capturing task relationships in the interface specification and explicitly representing constraints, designers can create interfaces that meet the often elusive user requirements. The application of IMN to creating an interface system for laying out floors is described 相似文献
37.
This study was retrospectively designed to examine if the Wiktor stent, a balloon-expandable tantalum coil stent, provides a more favorable procedural and long-term clinical and angiographic outcome than does conventional coronary balloon angioplasty (POBA). From April 1995 to April 1996, we implanted 56 Wiktor stents in 46 lesions (LAD: 23, RCA: 16, CX: 7) in 42 patients (average age 53 +/- 10 years). Coronary lesions from the stent group were matched with similar lesions of another 42 POBA patients whose characteristics were identical to the Wiktor group. Revascularization indications in the Wiktor and POBA groups, respectively, were recent myocardial infarction (RMI) (45%, 40%), unstable (31%, 39%) and stable (24%, 21%) angina pectoris. 7% of the stents and 17% of the POBA balloons were less than 3 mm in diameter (p > 0.05). Procedural success was significantly greater in the Wiktor group than in the POBA group (100% vs. 92%, p < 0.05). Neither major cardiac event (death, CABG, acute myocardial infarction) nor (sub)acute occlusion was encountered in the Wiktor group during the hospitalization period and 1 month follow-up. There was 1 urgent CABG and 4 subacute occlusions in the POBA group. Control angiography at 8 months was performed in patients of both groups, of whom some were symptomatic at long-term follow-up or completely event free for 8 months. Angiographic restenosis (> 50% diameter stenosis) occurred in 25% of the Wiktor patients and in 43% of those in the POBA group (p < 0.05). For an 18 month clinical follow-up, 91% of the patients in the Wiktor group were asymptomatic and without ischemia in radionuclide imaging (RI), whereas 79% of the POBA patients were angina-free and 74% were without ischemia in the RI study. In conclusion, Wiktor stent implantation, with no major cardiac event or subacute occlusion, provides a more favorable procedural and long-term clinical and angiographic outcome than does conventional POBA. 相似文献
38.
A. Tuncay
zylmaz N. Colak M.K. Sangün M. Erbil B. Yazc 《Progress in Organic Coatings》2005,54(4):353-359
The copolymer films PANI-co-POA and poly(aniline-co-o-anisidine) were carried out on copper (Cu) electrode, by applying two different scan rates (20 and 50 mV s−1) and using two different thicknesses at high scan rate. Synthesizes were achieved under cyclic voltammetric conditions from 0.075 M aniline and 0.075 M o-anisidine containing sodium oxalate solutions. The synthesized copolymer films were strongly adherent and homogeneous in both cases. AC impedance spectroscopy (EIS), anodic polarization plots and open circuit potential–time curves were used to evaluate the corrosion performance of copolymer coated and uncoated electrodes in 3.5% NaCl. It was shown that the copolymer film coated at low scan rate exhibited a better property initially when compared with the copolymer film produced at high scan rate. However, it could not resist the attack of corrosion products, in longer time and meanwhile its barrier property significantly diminished. It was found that the thin copolymer film produced at high scan rate by its catalysing effect led to the formation of highly protective copper oxides on the surface whereby providing a better protection for long exposure times. It also emerged that the corrosion resistances of thin copolymer film produced at high scan rate and copolymer film synthesized at low scan rate were almost same and relatively higher for much longer periods when compared with the one observed for bare copper electrode. 相似文献
39.
Hasan Öktem Tuncay Erzurumlu Mustafa Çöl 《The International Journal of Advanced Manufacturing Technology》2006,28(7-8):694-700
The objective of this paper is to develop a Taguchi optimization method for low surface roughness in terms of process parameters
when milling the mold surfaces of 7075-T6 aluminum material. Considering the process parameters of feed, cutting speed, axial-radial
depth of cut, and machining tolerance, a series of milling experiments were performed to measure the roughness data. A regression
analysis was applied to determine the fitness of data used in the Taguchi optimization method using milling experiments based
on a full factorial design. Taguchi orthogonal arrays, signal-to-noise (S/N) ratio, and analysis of variance (ANOVA) are used
to find the optimal levels and the effect of the process parameters on surface roughness. A confirmation experiment with the
optimal levels of process parameters was carried out in order to demonstrate the effectiveness of the Taguchi method. It can
be concluded that Taguchi method is very suitable in solving the surface quality problem of mold surfaces. 相似文献
40.
Ayhan Demirbas Tuncay Simsek 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2013,35(14):1321-1328
In this work, the utilization of aniline (C6H7N) formaldehyde (HCHO) resins as a binding agent of coke briquetting was investigated. Aniline (AN) formaldehyde (F) resins are a family of thermoplastics synthesized by condensing AN and F in an acid solution exhibiting high dielectric strength. The tensile strength sharply increases as the ratio of F to AN from 0.5 to 1.6, and it reaches the highest values between 1.6 and 2.2 F/AN ratio; it then slightly decreases. The highest tensile strength of F-AN resin-coke briquette (23.66 MN/m2) was obtained from the run with 1.5 of F/AN ratio by using (NH4)2S2O8 catalyst at 310 K briquetting temperature. The tensile strength of F-AN resin-coke briquette slightly decreased with increasing the catalyst percent to 0.10%, and then it sharply decreased to zero with increasing the catalyst percent to 0.2%. In general, the tensile strength of F-AN resin-coke briquette increased as increased the briquetting temperature in these tests contras with NaOH catalytic runs. The effect of pH on the tensile strength is irregular. As the pH of the mixture increases from 9.0 to 9.2, the tensile strength shows a sharp increase, and the curve reaches a plateau value between pH 9.3 and 9.9; then the tensile strength shows a slight increase after pH = 9.9. 相似文献