Self-assembly of a silica-surfactant nanocomposite in a porous alumina membrane

A mesoporous membrane composed of nanochannels with a uniform diameter has a potential use for precise size-exclusive separation of molecules. Here, we report a novel method to form a hybrid membrane composed of silica-surfactant nanocomposite and a porous alumina membrane, by which size-selective transport of molecules across the membrane becomes possible. The nanocomposite formed inside each columnar alumina pore was an assembly of surfactant-templated silica-nanochannels with a channel diameter of 3.4 nm; the channel direction being predominantly oriented along the wall of the columnar alumina pore. Molecules could be transported across the membrane including the silica-surfactant nanocomposite with a capability of nanometre-order size-exclusive separation. Our proposed membrane system has a potential use not only for separation science, but also catalysis and chip technologies.     

The influence of a fibre structure on optical loss in a graded-index fibre

For designing a fibre structure, the influence of structural parameters on optical loss is investigated experimentally for a graded-index fibre. The fibre with large cladding/outer-layer index difference and small cladding thickness is found to have large excess loss near excitation points, such as a launching point and a splicing point.     

Liquid holdup and heat transfer coefficient between bed and wall in liquid solid and gas-liquid-solid fluidized beds

In fluidized beds of 0.052 and 0.12 m i.d. air, water and aqueous solutions of carboxymethyl cellulose (viscosity = 9.0 X 10^-4- 52 X 10^-2 Pa s), and glass beads were used as gas, liquid and solid phase, respectively. The diameters of the glass beads were 4.2 X 10^-4 6.6 X 10^-4 1.2 X l0^-3, and 2.2 X 10^-3 m.The liquid holdup in the gas-liquid-solid fluidized bed was well correlated by modifying the Garside and Al-Dibouni's equation with the gas phase Froude number.The wall heat transfer coefficient of the gas-liquid-solid fluidized beds in the range of stable fluidization state runs correlated as a function of modified Nusselt number, modified Reynolds number and gas phase Froude number.     

Temperature distribution in Li2O pellets under neutron irradiation

The center temperature of Li₂O pellets under neutron irradiation was measured using an encapsuled pin. The surface temperatures of the pellets and the pellet/cladding heat transfer coefficients were estimated on the basis of the well-known conductivity integral.     

High-frequency broad-band signal generation using a semiconductor laser with a chaotic optical injection

Chaotic signals with a flat power spectrum over 20 GHz have been generated using two commercially available semiconductor lasers coupled in a unidirectional master-slave scheme. The master laser has an external optical feedback that induces optical chaos in the laser output. A part of the chaotic light output from the master laser is injected into the slave laser. We experimentally demonstrated the generation of broad-band signals up to 22 GHz using lasers whose relaxation oscillation frequency in the free-running state is only around 6.4 GHz. We also show that the experimental results can be well reproduced by numerical simulations using two coupled rate equations. The numerical investigation shows that the high-frequency broad-band signal generation is owing to two key effects: high-frequency oscillations as a result of beating between the master and slave laser lights, and spectrum flattening due to the injection of the chaotic signal. The flatness, stability, and tunability of the power spectra demonstrated in our experiments suggests that the proposed system can be potentially useful for generation of high-frequency broad-band random signals.     

Optimization method of P+ ω PSS parameters for stability and robustness enhancement in a multimachine power system

Recent steady increase of electric power demand causes power sources to be large and far from cities. Wide area power interchanges lead to larger and more complex power systems. This makes the network susceptible to poor damping power swing oscillations of relatively low frequencies which influence the whole system. This paper describes a newly developed generator's double input signal PSS (P+ ω input PSS) design method. Several power system conditions (power flow and/or power patterns) are considered to satisfy a well‐stabilized power system for each system condition. Major features of this method are: (1) Weighting factor for eigenvalue sensitivity of the oscillation mode is considered when the parameters of the PSS are updated during the optimization process. (2) The new method provides good results for the generator's local and interarea oscillation modes under peak and off‐peak power flow conditions. © 2000 Scripta Technica, Electr Eng Jpn, 131(1): 19–31, 2000     

Electron injection in "electron-only" devices based on a symmetric metal/silole/metal structure

We report on electron injection from two different metal electrodes into three silole derivatives, namely 2,5-di-(3-biphenyl)-1,1-dimethyl-3,4-diphenylsilacyclopentadiene (PPSPP), 1,2-bis(1-methyl-2,3,4,5,-tetraphenylsilacyclopentadienyl) ethane (2PSP) and 2,5-bis-(2', 2'-bipyridin-6-yl)-1, 1-dimethyl-3,4-diphenylsilacyclopentadiene (PyPySPyPy), previously employed as emissive and electron transport materials in molecular organic light-emitting diodes (MOLEDs). Silole films were sandwiched between symmetric Mg:Ag or bilayer CsF-Al electrodes. The steady-state current density-voltage characteristics were measured as a function of the silole layer thickness for the two cathodes. The trap-free space-charge-limited current based on time-of-flight measurements compared with the injected electron current for PyPySPyPy indicated that Mg:Ag contacts limit the injected current, while CsF-Al contacts behave as quasi-ohmic contacts. Similar findings were obtained for 2PSP and PPSPP allowing steady-state derived electron mobility parameters to be extracted. Based on space-charge-limited conduction analysis of the measured current-voltage characteristics, PyPySPyPy is found to be a superior electron transporting silole with approximately an order of magnitude higher electron mobility (2.0/spl times/10/sup -4/ cm/sup 2//Vs) compared with those of 2PSP (2.4/spl times/10/sup -5/ cm/sup 2//Vs) and PPSPP (5.2/spl times/10/sup -5/ cm/sup 2//Vs), which is significantly higher than that of the prototype electron transport material tris (8-hydroxyquinolinolato) aluminum (III) (Alq/sub 3/) (6.5/spl times/10/sup -7/ cm/sup 2//Vs) at 0.6 MV/cm.     

Pollution control of actual flue gas using pulsed power at a thermal power plant

There are several important environmental problems in the world. One of them is acid rain caused by combustion flue gases from thermal power plants, factories, and automobiles. Different kinds of gas discharges, such as surface discharge, dc and ac corona discharge, silent discharge, and electron beam controlled discharge, have been studied for the removal of NO_x and SO₂ from flue gases. The recent development of repetitive pulsed power generators gives the pulsed steamer corona discharges a chance of success in the removal of NO_x and SO₂. In this paper, the experimental results of NO_x and SO₂ removal by a repetitive pulse power generator are described. The actual flue gas at a thermal power plant was used. It is shown that about 90% of the NO was removed at a flow rate of 0.8 liters/min and a repetition rate of 7 pps. © 2001 Scripta Technica, Electr Eng Jpn, 134(4): 28–35, 2001     

Experimental analysis of temperature dependence in 1.3-μmAlGaInAs-InP strained MQW lasers

We have analyzed experimentally the temperature and pressure dependences of the lasing characteristics of 1.3-μm AlGaInAs-InP strained multiple-quantum-well lasers, by focusing on the ratio of the nonradiative recombination current to the total current. The temperature dependence of the radiative current was studied by observing the spontaneous emission through a window in the substrate. It was found to increase linearly with temperature, exactly as expected for an ideal quantum well over the entire temperature range from 100 to 360 K. Further, it was shown that pure radiative recombination dominated the total current below a breakpoint temperature T_b of 220 K. Above this temperature, the onset of loss processes including Auger recombination caused a superlinear increase in the threshold current. Analysis of the linear and nonlinear components allowed us to determine the ratio of the nonradiative to radiative currents at threshold. We find that, relative to similar GaInAsP/InP lasers, there is a decrease in the nonradiative component of the current, resulting in a higher characteristic temperature T₀ in the AlGaInAs-InP lasers. At 300 K, the radiative recombination current is more than 70% of the total threshold current. This result is consistent with the observation that the threshold current increases by about 8% in 12-kbar hydrostatic pressure, while in GaInAsP lasers, a decrease of 10% or more is always observed over this pressure range     

Preparation of Laminin-apatite-polymer Composites Using Metastable Calcium Phosphate Solutions

1Introduction Themostimportantrequirementofapercutaneous deviceisthepreventionofbacterialinfectionthroughtheinterfacebetweenthematerialandtheskin.Therefore,a percutaneousdevicehastoadherefirmlytoskintissueandpreventepidermaldowngrowth.Previously,Aokietalp…