The temperature–composition phase diagram in the diluted region of the cationic surfactant cetyldimethylbenzylammonium salicylate/water
system was studied with a battery of techniques. The Krafft temperature (
T
k = 33 ± 1 °C) was measured by differential scanning calorimetry, polarizing microscopy, conductimetry, viscosimetry, and rheometry.
The critical vesicle concentration (cvc, ~0.002 wt%) and a vesicle–micellar transition (cvm, ~0.005 wt%) was detected at a
temperature of 35 °C. Below
T
k and concentrations ≤2 wt%, a transparent solution is formed (I). Above 2–8.5 wt%, a lamellar (L
1) phase forms. At higher concentrations and up to 12 wt%, a second lamellar phase (L
2) is detected. From 12.4 to 15.5 wt%, an emulsion phase (E) is formed. Rheological dynamic measurements for the I phase indicate
that the system exhibits a predominantly viscous behavior (
G′ <
G″) for concentrations lower than the overlap or entanglement concentration (
C
e, ~0.75 wt%). At higher concentrations, wormlike micelles form and the elastic behavior predominates (
G′ >
G″). The elastic (
G′) modulus collapses in a concentration–time master curve in the whole reduced frequencies range
ωτ
c examined, whereas the viscous modulus (
G″) collapses only at reduced frequencies lower than 0.1. Reduced stress plotted as a function of the reduced shear rate yields
a good superposition of the curves at the different concentrations up to the onset of the non-linear behavior.
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