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51.
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A method for producing electrocatalysts containing silver supported on different carbons was developed. The catalysts were investigated in air (oxygen) diffusion electrodes in alkaline electrolyte (7 M KOH). Depending on the carbon support used, up to a threefold improvement in electrode performance was achieved compared with the activity of the uncatalysed carbon in this media. At ambient temperature and atmospheric pressure, a current density of 150 mA/cm–2 was obtained at electrode potential 1.2 V vs zinc (0.75 vs HE). A correlation between electro catalytic activity and wetted surface area of the electrocatalysts was found. 相似文献
53.
Deposits from silicon monoxide prepared by pulsed laser ablation were allowed to react with acrylic and vinyl monomers—styrene, methyl methacrylate and 1,2 ethylene glycol dimethacrylate. It was revealed by means of FTIR, electron paramagnetic resonance (EPR), and NMR spectroscopies that silyl ?Si· reacts with monomer molecules and initiates the consecutive polymerization. Crosslinking is proved by the occurrence of bending δ(? CH2) absorption peak at about 750 cm?1 in FTIR spectra. Because of very low concentration of the propagating radical for styrene we used a radical scavenger N‐phenyl‐t‐butylnitrone for trapping. The measured EPR parameters were compared with the calculated ones. In case of styrene, NMR analysis manifested the presence of Si? C bonds in SiCxOy (x + y = 2) units, which can be taken as direct evidence of the reaction between silyl centers and monomer molecules. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4488–4492, 2006 相似文献
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55.
Robert C. Pullar Yong Zhang Lifeng Chen Shoufeng Yang Julian R.G. Evans Peter Kr. Petrov Andrei N. Salak Dmitry A. Kiselev Andrei L. Kholkin Victor M. Ferreira Neil McN. Alford 《Journal of the European Ceramic Society》2007,27(16):4437-4443
Applying combinatorial methods to materials science offers the opportunity to accelerate the discovery of more efficient dielectric ceramics. High-throughput methods have the potential to investigate the effects of a wide range of dopants on the dielectric properties, and to optimise existing systems, encouraging the short innovation cycles that the communications technology industry requires. The London University Search Instrument (LUSI) is a fully automated, high-throughput combinatorial robot that has the potential capability to produce large numbers of sintered bulk ceramic samples with varying composition in 1 day, as combinatorial libraries on alumina substrates. Ba1−xSrxTiO3 (BST) libraries were produced by LUSI as a proof-of-principle, with x = 0–1 in steps of 0.1, and fired to 1350 and 1400 °C for 1 h. Part I of this paper described the manufacture and physical characterisation of BST libraries, showing a regular change in composition with x across the libraries. In this second part, the dielectric properties of BST libraries produced by LUSI are assessed at frequencies between 100 Hz and 1 MHz, and at temperatures between 150 and 500 K. Local piezoelectric properties were also characterised by scanning probe microscope (SPM). All measurements showed evidence of a clear functional gradient varying with x across the library, with measured r corresponding to expected values for BST. 相似文献
56.
Polyamide‐6 (PA6)/polybutadiene (PB) block copolymers were synthesized with macroactivators (MAs) based on hydroxyl‐terminated polybutadiene functionalized with diisocyanates and having three N‐acyllactam chain‐growing centers per molecule. Two different diisocyanates, hexamethylene diisocyanate and isophorone diisocyanate, were applied as precursors for the MAs. The sodium salt of ε‐caprolactam was chosen as an initiator. The influence of the MA type and concentration on the anionic ring‐opening polymerization of ε‐caprolactam at 180°C was studied. A large percentage of the gel fraction in the copolymers was estimated, indicating crosslinked macromolecules. The structure and phase behavior of the copolymers were investigated with differential scanning calorimetry, wide‐angle X‐ray scattering, thermogravimetric analysis, and dynamic mechanical thermal analysis. In the copolymers, only the PA6 chains crystallized, and the crystallinity depended on the PB content. Different glass‐transition temperatures for the PB blocks and PA6 blocks were observed, indicating microphase separation in the copolymers. The mechanical properties of the copolymers were studied by notched impact testing and hardness measurements. The impact strength increased linearly with the soft component concentration up to 10 wt % and reached values six times higher than those of the PA6 homopolymer. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 711–717, 2003 相似文献
57.
V. G. Komlev N. A. Bazunov V. V. Bazunova N. A. Petrov G. A. Chesnokova 《Refractories and Industrial Ceramics》1979,20(5-6):360-363
Conclusions The authors have investigated the strength properties of chamotte concretes based on phosphate binders over a wide range.They have shown the dependence of the compressive strength of the concretes on the type of phosphate binder used, the heat treatment temperature of the concrete, and its test temperature. Maximal compressive strength is exhibited by concretes roasted at 1450°C.They have established a relation between the physicochemical transitions taking place in a phosphate binder during heating and the strength characteristics of the concrete.Simultaneous introduction of phosphate binder and clay to the extent of 10–20% into chamotte concretes increases their strength at 20°C and during heating.Translated from Ogneupory, No. 6, pp. 32–36, June, 1979. 相似文献
58.
S. A. Petrov O. Yu. Sinel'shchikova L. F. Grigor'eva I. B. Patrina N. O. Ovchinnikov V. V. Gusarov 《Glass Physics and Chemistry》2005,31(6):803-807
The ramsdellite-type phases crystallizing in the Li2O-Fe2O3-TiO2 system in the course of synthesis in gaseous media at different oxygen partial pressures are studied. Solid solutions based on the ramsdellite structure with the composition Li2Ti3?xFe x O7 ? δ (0 ≤ x ≤ 0.7) are prepared in an oxidizing medium (PO2 = 1 atm) for the first time. Analysis of the results obtained by electron paramagnetic resonance and Mossbauer spectroscopy revealed that, in these solid solutions, all iron ions are in the oxidation state Fe+3. 相似文献
59.
The influence of pitch composition and surface properties of petroleum coke on the interaction of pitch and coke in the composite is studied. The adsorption results and EPR data indicate that recombination of paramagnetic centers and interaction of oxygen functional groups occur during the preparation of the composite. As a result of interaction between petroleum coke and pitch, polar compounds are concentrated in the adsorption layer. The baking criterion is used for the characterization of the baking ability of the pitches obtained as a result of different oxidation treatments of commercial coal tar pitch. It is determined that physico-chemical properties of the obtained pitches influence the value of the “baking criterion”. The kind of thermo-oxidation treatment of the parent pitch should be chosen hence achieving the maximum value of the baking criterion. For this purpose, the maximal part of the pitch has to take part in the adsorption layer. 相似文献
60.
D. M. Gokhfeld D. A. Balaev K. A. Shaikhutdinov S. I. Popkov M. I. Petrov 《The Physics of Metals and Metallography》2006,101(1):S27-S28
The current-voltage characteristic (CVC) of a break junction made from polycrystalline Bi1.8Pb0.3Sr1.9Ca2Cu3Ox is investigated. The experimental CVC has a hysteretic feature that reflects part of the curve with a negative differential resistance. The CVC is discussed within the framework of the Kümmel-Gunsenheimer-Nicolsky theory that takes into account multiple Andreev reflections in superconductor/normalmetal/superconductor junctions. 相似文献