Rice-like CuO nanostructures for sensitive electrochemical sensing of hydrazine

In this work, a low temperature aqueous chemical growth methodology was used for the fabrication of CuO nanostructures. The as-synthesised nanostructures were then elaborately characterised by number of analytical techniques such as scanning electron microscopy (SEM) and X-ray powder diffraction (XRD). The obtained nanostructures were observed to possess interlaced rice-shaped structural features with the length and width of individual rice determined to be in the range of 200–300 nm and 50–100 nm respectively. The unique nanostructures when utilised as electrode material exhibited excellent electro-catalytic potential towards oxidation of hydrazine in alkaline media. The excellent conductive of CuO added by the high surface area of obtained nanorice-like structures enabled development of highly sensitive (3087 µA mM⁻¹ cm⁻²), selective and stable electrochemical sensor for hydrazine. In addition, the successfully application of the developed sensor in spiked tap, bottled and industrial water samples for the detection of hydrazine suggested its feasibility for practical environmental application.

     

A construction and improvement heuristic for a liquefied natural gas inventory routing problem

We present a large scale ship routing and inventory management problem for a producer and distributor of liquefied natural gas (LNG). The problem contains multiple products, inventory and berth capacity at the loading port and a heterogeneous fleet of ships. The goal is to create an annual delivery program to fulfill the producer’s long-term contracts at minimum cost, while maximizing the revenue from selling LNG in the spot market. To solve this problem we have developed a construction and improvement heuristic (CIH).The CIH is a multi-start local search heuristic that constructs a set of solutions using a greedy insertion procedure. The solutions are then improved using either a first-descent neighborhood search, branch-and-bound on a mathematical formulation, or both. Tests on real-life instances show that the CIH provides good solutions in a short amount of time.     

Planar-Based Visual Inertial Navigation: Observability Analysis and Motion Estimation

In this paper, we address the problem of ego-motion estimation by fusing visual and inertial information. The hardware consists of an inertial measurement unit (IMU) and a monocular camera. The camera provides visual observations in the form of features on a horizontal plane. Exploiting the geometric constraint of features on the plane into visual and inertial data, we propose a novel closed form measurement model for this system. Our first contribution in this paper is an observability analysis of the proposed planar-based visual inertial navigation system (VINS). In particular, we prove that the system has only three unobservable states corresponding to global translations parallel to the plane, and rotation around the gravity vector. Hence, compared to general VINS, an advantage of using features on the horizontal plane is that the vertical translation along the normal of the plane becomes observable. As the second contribution, we present a state-space formulation for the pose estimation in the analyzed system and solve it via a modified unscented Kalman filter (UKF). Finally, the findings of the theoretical analysis and 6-DoF motion estimation are validated by simulations as well as using experimental data.     

Pseudospectral method for assessing stability robustness for linear time-periodic delayed dynamical systems

The article presents a pseudospectral approach to assess the stability robustness of linear time-periodic delay systems, where periodic functions potentially present discontinuities and the delays may also periodically vary in time. The considered systems are subject to linear real-valued time-periodic uncertainties affecting the coefficient matrices, and the presented method is able to fully exploit structure and potential interdependencies among the uncertainties. The assessment of robustness relies on the computation of the pseudospectral radius of the monodromy operator, namely, the largest Floquet multiplier that the system can attain within a given range of perturbations. Instrumental to the adopted novel approach, a solver for the computation of Floquet multipliers is introduced, which results into the solution of a generalized eigenvalue problem which is linear w.r.t. (samples of) the original system matrices. We provide numerical simulations for popular applications modeled by time-periodic delay systems, such as the inverted pendulum subject to an act-and-wait controller, a single-degree-of-freedom milling model and a turning operation with spindle speed variation.