Effect of polymerization conditions on o‐phenylenediamine and o‐phenetidine oxidative copolymers

A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution ¹H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry     

新型埽工--笼埽在黄河控导工程中的应用

介绍了新型埽工——笼埽的结构形式、施工方法，其优点为：(1)克服传统埽工施工工序复杂、速度慢、效率低的缺点；(2)笼埽可工厂化生产，减少现场作业工序和作业面后移；(3)充分利用大型施工机械进行大体积单个笼埽结合机械化施工，作埽速度快、强度高；(4)减少柳料用量，利于环境保护．结合在兰考蔡集控导工程水中进占工程中的应用，从施工准备、机械配合与人员安排及施工流程等方面对笼埽施工技术作进一步说明，并总结了施工注意事项．最后，进行了效益评价并提出了扩大技术应用范围和进行水槽实验的完善思路．     

参数强迫激励下非线性振子尖点型奇点的分叉

本文首先研究了不具有Z_2—对称性时的规范形理论和退化向量场的普适开折理论。然后利用这些理论研究了参数激励与强迫激励联合作用下非线性振动系统的尖点型奇点的余维2退化分叉。     

纺织机械零件CAPP技术的应用研究

要提高产品的竞争能力，必须在企业中加大CAPP的应用力度，笔者通过应用思普CAPP系统（SIPM/CAPP）编制纺织机械零件工艺文件的实践，证明了在企业中应用CAPP是提高产品的市场竞争能力，提高企业工艺快速反应能力的有力工具。     

新一代开放式自动抄表系统平台

本文提出了建立新一代的开放式自动抄表平台的思想,并着重介绍了构建平台的基本原则、技术要求和设计方式。     

Diffusion Behaviour of Fe-Cu Interface of Copper Brazed Double-wall Steel Tubes

By means of electron probe(EPMA),scanning electron microscope(SEM),and optical microscope(QM),the diffusion behaviour on the Fe-Cu interface of copper brazed double-wall steel tubes andthe microstructure of the diffusion layer have been investigated.There are three kinds of metallurgicalbonds between copper plating layer and steel substrate: (1)the Cu diffusing into steel substratealong grain boundary of ferrite;(2)the Cu diffusion into grain bulk of ferrite: (3)the Fe diffusing intoCu layer.The copper brazed double-wall steel tubes are formed by the combination of the diffusionsmentioned above and this is the reason for excellent mechanical and technological properties of thecopper brazed double-wall steel tubes.     

模块化蓝光光存储性能静态测试系统

蓝光光存储是信息存储领域发展的一个重要方向。测试系统是研究蓝光光存储材料的必备条件，为建立蓝光光存储研究平台，设计和搭建了一套模块化蓝光光存储性能静态测试系统。激光工作波长为406．7nm。系统采用调制解调技术降低系统噪声，提高测量粘度：采用光点移动模式降低对样品尺寸的要求；采用纳米平台提高记录点的反复定位性能。实验结果证明测试系统性能良好，可以满足蓝光光存储性能静态测试要求。     

A novel interference suppression scheme for global navigation satellite systems using antenna array

This paper considers interference suppression and multipath mitigation in Global Navigation Satellite Systems (GNSSs). In particular, a self-coherence anti-jamming scheme is introduced which relies on the unique structure of the coarse/acquisition (C/A) code of the satellite signals. Because of the repetition of the C/A-code within each navigation symbol, the satellite signals exhibit strong self-coherence between chip-rate samples separated by integer multiples of the spreading gain. The proposed scheme utilizes this inherent self-coherence property to excise interferers that have different temporal structures from that of the satellite signals. Using a multiantenna navigation receiver, the proposed approach obtains the optimal set of beamforming coefficients by maximizing the cross correlation between the output signal and a reference signal, which is generated from the received data. It is demonstrated that the proposed scheme can provide high gains toward all satellites in the field of view, while suppressing strong interferers. By imposing constraints on the beamformer, the proposed method is also capable of mitigating multipath that enters the receiver from or near the horizon. No knowledge of either the transmitted navigation symbols or the satellite positions is required.     

三峡工程泄洪坝段表孔溢流面拉模施工技术

三峡工程泄洪坝段表孔溢流面主要采用一期预留台阶、二期拉模一次成形的方法施工,体型复杂,拉模施工难度大,施工质量要求高,在生产性试验以及对试验结果进行分析的基础上,对混凝土性能、拉模设计、施工措施等方面进行了改进,形成了一套成熟的拉模施工技术。施工结果表明,施工质量达到了设计要求。     

一种控制盐层段井眼闭合率的钻井液密度新公式

针对钻井过程中钻遇的盐层段井眼蠕变缩径问题,利用弹塑性力学理论,蠕变本构方程采用Heard蠕变方程,在平面应变和均匀地应力假设下,推导出控制井眼收缩的钻井液密度新公式,该公式与前人推导的公式不同。通过理论分析,指出产生差异的根本原因在于蠕变应力差(极坐标下表示的径向应力与切向应力之差)公式的推导上,用有限元法计算结果对理论公式进行检验,证明是可行的。对文中的力学模型采用有限元法建模、求解,利用求解结果对各应力差公式进行验证,得出:根据文中公式计算结果与有限元法计算结果完全一致,而据前人公式计算结果偏离有限元计算值较大,从而间接证明了该钻井液密度新公式的推导更严密,更准确。