In situ FTIR study of 2-chloropyridine adsorbed on Au(111) and Au(110) electrodes

2-chloropyridine (2Clpy) adsorbed on Au(111) and Au(110) electrodes in 0.1 M KClO₄ containing 2 mM 2Clpy has been investigated using in-situ infrared spectroscopy and differential capacity measurements. For both the electrodes, an in-plane ring vibration due to N-bonded 2Clpy was observed, which was accompanied by a loss in the in-plane ring vibrations due to dissolved 2Clpy. However, the integrated band intensity ratios between the adsorbed 2Clpy and the loss of dissolved 2Clpy for both electrodes are quite different in all potentials measured. The relative band intensity of the N-bonded 2Clpy for Au(110) is much stronger than that for the Au(111). This indicates that for the Au(111) the adsorbed 2Clpy is mainly flat type or the tilt angle of the N-bonded 2Clpy is large. It can be explained by the configuration of adsorbed 2Clpy on the electrode surface. For Au(111) terrace, N-bonded configuration is obstructed by the presence of Cl atom. There is no obstruction for the Au(110) step if the N-bonded 2Clpy is adsorbed on the overtop layer.     

A New Challenge for Applying Time Series Metrics Data to Software Quality Estimation

In typical software development, a software reliability growth model (SRGM) is applied in each testing activity to determine the time to finish the testing. However, there are some cases in which the SRGM does not work correctly. That is, the SRGM sometimes mistakes quality for poor quality products. In order to tackle this problem, we focussed on the trend of time series data of software defects among successive testing phases and tried to estimate software quality using the trend. First, we investigate the characteristics of the time series data on the detected faults by observing the change of the number of detected faults. Using the rank correlation coefficient, the data are classified into four kinds of trends. Next, with the intention of estimating software quality, we investigate the relationship between the trends of the time series data and software quality. Here, software quality is defined by the number of faults detected during six months after shipment. Finally, we find a relationship between the trends and metrics data collected in the software design phase. Using logistic regression, we statistically show that two review metrics in the design and coding phase can determine the trend. Sousuke Amasakireceived the B.E. degree in Information and Computer Sciences from Okayama Prefectural University, Japan, in 2000 and the M.E. degree in Information and Computer Sciences from Graduate School of Information Science and Technology, Osaka University, Japan, in 2003. He has been in Ph.D. course of Graduate School of Information Science and Technology at Osaka University. His interests include the software process and the software quality assurance technique. He is a student member of IEEE and ACM. Takashi Yoshitomireceived the B.E. degree in Information and Computer Sciences from Osaka University, Japan, in 2002. He has been working for Hitachi Software Engineering Co., Ltd. Osamu Mizunoreceived the B.E., M.E., and Ph.D. degrees in Information and Computer Sciences from Osaka University, Japan, in 1996, 1998, and 2001, respectively. He is an Assistant Professor of the Graduate School of Information Science and Technology at Osaka University. His research interests include the improvement technique of the software process and the software risk management technique. He is a member of IEEE. Yasunari Takagireceived the B.E. degree in Information and Computer Science, from Nagoya Institute of Technology, Japan, in 1985. He has been working for OMRON Corporation. He has been also in Ph.D. course of Graduate School of Information Science and Technology at Osaka University since 2002. Tohru Kikunoreceived the B.E., M.Sc., and Ph.D. degrees in Electrical Engineering from Osaka University, Japan, in 1970, 1972, and 1975, respectively. He joined Hiroshima University from 1975 to 1987. Since 1990, he has been a Professor of the Department of Information and Computer Sciences at Osaka University. His research interests include the analysis and design of fault-tolerant systems, the quantitative evaluation of software development processes, and the design of procedures for testing communication protocols. He is a member of IEEE and ACM.     

An Empirical Approach to Characterizing Risky Software Projects Based on Logistic Regression Analysis

During software development, projects often experience risky situations. If projects fail to detect such risks, they may exhibit confused behavior. In this paper, we propose a new scheme for characterization of the level of confusion exhibited by projects based on an empirical questionnaire. First, we designed a questionnaire from five project viewpoints, requirements, estimates, planning, team organization, and project management activities. Each of these viewpoints was assessed using questions in which experience and knowledge of software risks are determined. Secondly, we classify projects into “confused” and “not confused,” using the resulting metrics data. We thirdly analyzed the relationship between responses to the questionnaire and the degree of confusion of the projects using logistic regression analysis and constructing a model to characterize confused projects. The experimental result used actual project data shows that 28 projects out of 32 were characterized correctly. As a result, we concluded that the characterization of confused projects was successful. Furthermore, we applied the constructed model to data from other projects in order to detect risky projects. The result of the application of this concept showed that 7 out of 8 projects were classified correctly. Therefore, we concluded that the proposed scheme is also applicable to the detection of risky projects.     

Successful treatment of bilateral deep femoral aneurysms and multiple iliac aneurysms associated with severe aortic valve disease: report of a case

We report herein the case of a patient in whom aneurysms of the bilateral deep femoral arteries (DFA) and multiple iliac aneurysms associated with severe aortic valve disease were successfully treated by a two-staged operation. The patient was a 74-year-old man who had dense calcification of the ascending aorta and aortic arch. Prior to aortic valve replacement (AVR), the aneurysms of the DFA and internal iliac arteries were resected. The terminal end of the abdominal aorta and bilateral common iliac arteries were then reconstructed with a Y graft to be used as a possible alternative arterial input route in place of the ascending aorta for extracorporeal circulation during the AVR. The inferior mesenteric artery (IMA) was well developed, and the external iliac arteries and their branches were preserved at aneurysmectomy. Postoperatively, there was no ischemia of the pelvic organs or the hip muscles. The AVR was subsequently performed 5 weeks after the first operation, and the patient was discharged after an uneventful postoperative course.     

Dependence of Output Power on Cavity Length in a Gyrotron Backward Wave Oscillator

A relativistic electron beam (500 keV, 200 A, 10 ns) generated magnetically tunable microwave radiation in a frequency range of 9-13 GHz when it is injected into an X-band rectangular waveguide immersed in a uniform axial magnetic field (4-10 kG). The mechanism of the microwave radiation was identified as the gyrotron backward wave interaction. The output power of the radiated microwave increased exponentially with the increase of the cavity length.     

Development of novel rare earth doped fluoride and oxide scintillators for two-dimensional imaging

Two topics were focused.The first one was about the gamma-ray scintillator,Pr3+:Lu3Al5O12(LuAG) .The second one was about neutron scintillator,Ce3+:6LiCaAlF6 and Eu2+:6LiCaAlF6(6LiCAF) .Those scintillators have been developed very recently for modern imaging appli-cations in the medical and homeland security fields.In both cases,the rare earth ions are playing the crucial role as emission centers.Pr3+ in LuAG provided fast 5d→4f transition providing noticeably shorter decay time than that of Ce3+.Among several candidate hosts,LuAG showed the best performance.Bulk crystal growth,basic scintillation properties,two-dimensional gamma-ray imaging and positron emission mammography(PEM) application were demonstrated.Due to the international situation,the homeland security was compromized by illicit traffic of explosives,drugs,nuclear materials,etc.and the ways to its improvement became an important R&D topic.For this purpose the Ce and Eu doped LiCAF ap-peared competitive candidates.Especially,when substitution of 3He neutron detectors was considered,the discrimination ability of gamma-ray from alpha-ray was important.Bulk crystal growth,basic scintillation properties and two-dimensional neutron imaging were demonstrated.     

Gaussian solar flux model

The Gaussian Solar Flux model (GSFM) predicts instantaneous hourly and integrated daily direct and diffuse solar flux upon sloped as well as horizontal surfaces for clear and cloudy days. Comparison with Davis SEMRTS data from the first six months of 1981 indicates a mean relative error of +/−3.5% and a correlation coefficient of 0.999 for instantaneous global flux during clear days.The GSFM improves upon previous monolayer models with cloud transmittance functions generalized for different surface albedos and a fast Gaussian quadrature based estimate for water vapor pathlengths. Advantages over multilayer models are its speed and lack of need for soundings. Input may be made entirely from standard surface meteorological measurements.     

Status of design and procurement activities in JT-60SA

The JT-60SA experiment is one of the three projects to be undertaken in Japan as part of the Broader Approach Agreement, conducted jointly by Europe and Japan, and complementing the construction of ITER in Europe. It is a fully superconducting tokamak capable of confining break-even equivalent deuterium plasmas with equilibria covering high plasma shaping with a low aspect ratio at a maximum plasma current of I_p = 5.5 MA. In late 2007 the BA Parties, prompted by cost concerns, asked the JT-60SA Team to carry out a re-baselining effort with the purpose to fit in the original budget while aiming to retain the machine mission, performance, and experimental flexibility. Subsequently the Integrated Project Team has undertaken a machine re-optimization followed by engineering design activities aimed to reduce costs while maintaining the machine radius and plasma current. This effort led the Parties to the approval of the new design in late 2008 and hence final design and procurement activities have commenced. The paper will describe the process leading to the re-baselining, the resulting final design and technical solutions and the present status of procurement activities.     

High transconductance selfaligned WSi gate AlInAs/GaInAs HIGFETs grown by MOCVD

HIGFETs were fabricated using an AlInAs/GaInAs heterostructure grown by MOCVD. The 1 mu m-gate HIGFET showed a maximum transconductance of 740 mS/mm at room temperature, which is the highest transconductance obtained for HIGFETs. The reduction of the AlInAs layer thickness to 30 nm and the low source resistance are the primary reasons for this enhancement.<>