The iron(III) chloride‐catalyzed Friedel–Crafts arylation of 4‐aryl‐4‐methoxy‐2,5‐cyclohexadienones, which were easily prepared by the phenyliodine(III) diacetate (PIDA)‐mediated oxidation of 4‐arylphenols in methanol, proceeded site‐selectively to form meta‐terphenyl (2,4‐diarylphenol) derivatives in good yields. The subsequent PIDA‐mediated oxidation and iron(III) chloride‐catalyzed Friedel–Crafts arylation of the resulting products gave the corresponding 2,4,6‐triarylphenol derivatives. The present method provides useful highly substituted polyarylated compounds.
3-Pyridinecarboxylic acid (3-PC) adsorbed on low index face electrodes in NaF solution were investigated using in situ Fourier transform-infrared (FTIR) spectroscopy and differential capacity measurements. Two types of vertically adsorbed 3-PC were confirmed on the electrodes, while flat-lying adsorbed species were not observed at the potentials measured. At negative potentials, 3-PC molecules adsorb vertically on the electrode via the lone pair electrons of the pyridine ring nitrogen atom, and at positive potentials, 3-PC adsorbs vertically via the two oxygen atoms of the carboxyl group. 相似文献
The purpose of this study was to develop a system for communication between a human and a computer generated (CG) character
to make him or her more peaceful and cheerful. Nonverbal communication using such things as facial expression, a nod, or a
hand gesture is very important for reciprocal communication between humans. In this study, an image registered by infrared
rays which describes the thermal distribution of the face and neck has been used to develop a system for communication between
a human and a CG character. The CG character can synchronize its nod with a person’s nod by predicting his or her nod angle.
The measured feature parameter is input to a fuzzy algorithm system to obtain the nod angle of a person in front of an infrared
camera, and then a moving-average model is used to predict the nod angle of the person. The average error of the nod angle
obtained by the system has been estimated as about 5°. The CG character nods its head, not only when the human nods his or
her head, but also when the human shakes his or her head to the left or right. 相似文献
In obstruction of both lacrimal ducts at present the most frequently used method is conjunctivo(dacryo)cystorhinostomy using a Jones bypass cannula. The effectiveness of the procedure is 85-90%. The drainage cannulas can be straight or bent and are as a rule made from pyrex glass. The patients should be highly motivated and made familiar with possible complications, i.e. most frequently escape of the cannula. With regard to the necessary postoperative cooperation the operation is not recommended in young children. The authors performed in 1996-1997 a total of 8 conjunctivo(dacryo)cystorhinotomies. The lacrimal sac is opened into the nose under general anaesthesia by the endonasal route using endoscopes. In one instance the authors used a straight silicone cannula which fell out after three weeks. In the remaining patients they used a bent silicone cannula. Seven patients evaluate their condition after surgery as markedly improved and would be willing to have the operation again. One female patient (after escape of a straight cannula and later reinsertion of a bent cannula) would hesitate to have another operation. The authors evaluate their experience with this type of bypass operation as very satisfactory. 相似文献
We investigated changes in the glycosaminoglycans (GAGs) during progression of a human gingival carcinoma xenograft line, GK -1, in nude mice. The GAGs extracted from cancers 3, 5, 7, 10 and 15 weeks after transplantation consisted of hyaluronic acid (HA), chondroitin sulfate (CS) and heparan sulfate (HS) as major components, and dermatan sulfate (DS) as a trace component for all cancers. HPLC analysis revealed that the HA content per defatted tissue dry weight increased in the cancers 5 weeks after transplantation compared to those of 3 weeks (p < 0.05), while CS for cancers at 10 weeks decreased compared with 7 weeks (p < 0.05). However, HS showed no significant change. Both the CS and DS contained primarily 4-sulfated disaccharide units. Immunohistochemical staining with antibody 2-B-6 for the PGs having delta DI-4S produced by chondroitinase ABC digestion showed that CS is located in the tissue surrounding the cancer nests and mass. These results indicate that the location of accumulation of CS, which primarily contains 4-sulfated disaccharide units, plays an important role in cancer progression. 相似文献
In situ Fourier transform infrared spectroscopy (FTIR) spectra measurements were obtained for a Cu electrode/solution of lithium perchlorate in propylene carbonate (PC). The dependence of potential on the concentration of PC in the vicinity of the electrode was investigated. The bands due to free PC and PC solvated to lithium ions in the solution were distinguished by the single reflection attenuated total reflection (ATR) spectra. In the FTIR spectra, the reversible change in the concentration of free PC and solvated PC in the diffuse double layer was observed to be accompanied by a change in potential. As the potential decreased, the free PC concentration increased, while the concentration of the PC solvated to lithium ions decreased. Thus, it can be concluded that the equilibrium shifts from Li+(PC)4 to Li+(PC)3 + PC as the potential decreases. Furthermore, Li+(PC)3 orientates itself so that it is parallel to the electrode surface. 相似文献
Experimental exploration of highly spin-polarized states of liquid 3He by applying external magnetic field is limited by the availability of static magnetic field. In the “ferromagnetic” superfluid A1 phase of liquid 3He there is an alternate method for boosting spin-polarization by the process of spin pumping without requiring such high magnetic field. The spin pumping in the A1 phase takes advantage of a superleak (SL) acting simultaneously as a filter for both entropy and spin. The spin pump technique that uses the SL-spin filter and a mechanical actuator enables us to directly boost polarization of 3He. The amount of enhancement of spin polarization has been limited so far. We are now developing a new type of SL filter made of packed aluminum oxide powder (referred as PAP-SL), in order to achieve greater enhancement of spin polarization. Several kinds of the PAP-SL filter were constructed by pressing aluminum oxide powders into a cylinder holder. The packed structures were carefully characterized by a flow-rate-measurement, X-ray tomography, and mercury intrusion porosimetry. The preliminary result shows that the PAP-SL works as SL filter for the superfluid 3He. 相似文献