On-Site Fabrication of Crystalline Cerium Oxide Films and Patterns by Ink-Jet Deposition Method at Moderate Temperatures

Crystalline CeO₂ films and patterns have been successfully fabricated in a "single-step process" at moderate temperature. In this process, the combination of the ink-jet technique and depositing the precursor on a hot substrate (≤300°C) gave crystalline CeO₂ without further heat treatment. X-ray diffraction analysis revealed that the phase formed was crystallized ceria with nanosized (<10 nm) crystallites. The film thickness was several hundred nanometers and the pattern width was about 150 μm. Scanning electron microscopy analysis showed that the films and patterns were free of cracks and adhered to the substrate. This is the first report about the direct patterning of crystalline CeO₂ without postfiring or posttreatments like masking, etching, etc.     

Correlation of temperature rise and velocity along an inclined fire plume axis in crosswinds

Experiments with a single fire source were carried out in crosswinds in order to elucidate the correlation between temperature rise and velocity along an inclined fire plume axis. A circular propane burner with a diameter of 0.2 m was used as a model fire source. The temperature and velocity were measured along the inclined fire plume axis, and these were compared with fire plume data obtained in a calm condition. An empirical formula to represent the correlation of the temperature rise and velocity was developed. The values of empirical coefficients and exponents were derived from the experimental results of the circular burner. In order to verify the availability of the proposed empirical formula, the comparison was carried out with the data obtained from square and/or rectangular burners.     

采用无偏振片反射式LCD及超低功耗驱动技术制造移动显示器件

我们通过对材料和制备条件的精细化处理,生产出一种在低刷新频率下无闪烁和图像迟滞现象的反射式显示器。该显示器的功耗非常低,且可在宽温度范围内工作,是未来移动显示器件的潜力平台。     

Left ventricular regional systolic motion in patients with right ventricular pressure overload

The highly reactive and cytotoxic hydroxyl radical (OH) was found by electrochemical detection to be produced in reactions involving hydrogen peroxide (H2O2) and the nitric oxide (NO) donor diethylamine- NO complex. Using aromatic hydroxylation of salicylate as a specific indicator of OH, three salicylate hydroxylation products were identified; catechol, 2,3- and 2,5-dihydroxybenzoic acid. Four additional compounds were detected but not identified. The interactions of H2O2 and NO represent a biologically feasible reaction mechanism that can account for OH-induced damage in cellular environments where transition metal ions are unavailable for participation in the superoxide-mediated Fenton reaction. The ability of the NO/H2O2 complex to generate OH independently of iron or other transition metals provides a new focus for studies concerned with the origin of tissue-specific damage caused by oxygen-derived species.     

Antioxidant effects of chlorophyll and pheophytin on the autoxidation of oils in the dark. II. The mechanism of antioxidative action of chlorophyll

To understand the mechanism of the antioxidant effect of chlorophyll on the autoxidation of oils in the dark, antioxidant activities of several derivatives of chlorophyll were compared. Antioxidant activities were observed in chlorophyll derivatives such as protopor-phyrin methyl ester and its magnesium chelated compound. Porphyrin seems to be an essential chemical structure for the antioxidant activity of chlorophyll. Chlorophyll did not decompose the hydroperoxides, but reduced free radicals such as 1,1-diphenyl-2-picrylhydrazyl. Electron spin resonance spectrum of the π-cation radical was recorded during the oxidation of chlorophyll in methyl linoleate solution. These observations suggest that chlorophyll may act as a hydrogen donor to break the chain reaction.     

Thermal behaviour and particle size evaluation of primary clusters in a water-based magnetic fluid

This paper reports the experimental research on thermal behaviour and particle size evaluation of primary clusters of ferromagnetic nano-particles in a water-based magnetic fluid. The magnetic fluids are suspensions of ultra fine particles coated with a molecular layer of dispersant in a liquid carrier such as water or kerosene. The particles are coated with single- or double-layer of surfactant to achieve stable dispersion. Numerous experimental studies have indicated the existence of the primary cluster of ferromagnetic nano-particles in a water-based magnetic fluid. The purpose of this research is to evaluate the particle size of the primary clusters by applying the Einstein's equation for Brownian motion assuming that the primary cluster has a spherical-shape. The thermal behaviour of ferromagnetic nano-particles in magnetic fluids is investigated through the micro visualization using the optical darkfield microscope system and particle tracking velocimetry data processing system. Real-time visualization of the Brownian motion of primary clusters in a water-based magnetic fluid was carried out. The experimental results clarified that the primary cluster size depends upon the concentration of the ferromagnetic nano-particle in the magnetic fluid.     

Generalized stress intensity factors of V-shaped notch in a round bar under torsion, tension, and bending

In this study, generalized stress intensity factors K_I,λ1, K_II,λ2, and K_III,λ4 are calculated for a V-shaped notched round bar under tension, bending, and torsion using the singular integral equation of the body force method. The body force method is used to formulate the problem as a system of singular integral equations, where the unknown functions are the densities of body forces distributed in an infinite body. In order to analyze the problem accurately, the unknown functions are expressed as piecewise smooth functions using three types of fundamental densities and power series, where the fundamental densities are chosen to represent the symmetric stress singularity and the skew-symmetric stress singularity. Generalized stress intensity factors at the notch tip are systematically calculated for various shapes of V-shaped notches. Normalized stress intensity factors are given by using limiting solutions; they are almost determined by notch depth alone, and almost independent of other geometrical parameters. The accuracy of Benthem-Koiter’s formula proposed for a circumferential crack is also examined through the comparison with the present analysis.     

Formation of a Network Structure in the Gaseous Reduction of Magnetite Doped with Alumina

Reduction of un-doped magnetite is developed topochemically with the formation of a dense iron shell. However, the reduction of alumina-doped magnetite to wüstite proceeds with the formation of a network-like structure which consists of criss-crossed horizontal and vertical plates of wüstite. Reduction of magnetite includes the conversion of Fe³⁺ to Fe²⁺ and the movement of iron cations from the tetrahedral sites on the {400} and {220} planes of magnetite to the octahedral sites on the {200} planes of wüstite. Alumina has a negligibly small solubility in wüstite. In the reduction of magnetite doped with Al₂O₃, rejected Al³⁺ cations from wüstite diffuse to the magnetite–hercynite solid solution. Enrichment of the Fe₃O₄–FeAl₂O₄ solution with alumina in the vicinity of the reduction interface restricts the growth of {220} planes of wüstite and nucleation of {220} planes adjusted to the existing planes, preventing the merging of wüstite plates during the reduction process. Reduction of magnetite from the magnetite–hercynite solid solution practically stops when the Al³⁺ content at the interface approaches the solubility limit. Wüstite in the separated plates is reduced further to iron.     

Advances in nature-guided materials processing

The center of excellence (COE) titled ‘The Creation of Nature-Guided Materials Processing’ has been established in Nagoya University as the 21st Century COE Program supported by Ministry of Education, Culture, Sports, Science and Technology. In the Nature COE, various activities on the education and research are being performed through learning the laws of nature, namely, methods of attaining ‘appearance of the maximum function under the minimum substance and energy consumption’, which the nature and living organisms have acquired through their evolution in long period. Together with such educational programs for PhD students as research incentive, oversea training, and external evaluation programs, an ‘Open-Cluster Program’ was originated for promoting researches proposed by research groups consisting of young researchers in and out of the university and also for fostering them.

The researches are being advanced on materials used for living bodies, mimicking structures which nature or living bodies are forming, and producing materials by mimicking processes to form the structures observed in the nature or the living bodies. In this COE, these researches are conducted by four groups to extend the processes observed in the natural world to a new type of processing, that is, thoroughly examined and rationalized by plunging a scalpel of engineering and to establish a new academic field of materials science and engineering.     

Direct modulation characteristics of GaInAsP/InP d.h. lasers with various stripe widths measured by sharp-pulse method

The direct modulation characteristics of GaInAsP/InP d.h. lasers emitting at 1.3 ?m with various stripe widths were measured by the proposed sharp-pulse method. As a result, a flat modulation frequency response up to 1.9 GHz was observed in a laser diode with 5 ?m stripe width.