Synthesis and Sintering of Cerium(II) Monosulfide

Cerium monosulfide (CeS) powder was synthesized by the reduction of Ce₂S₃ powder with metallic Ce, which was obtained from ceria (CeO₂) powder using carbon disulfide (CS₂) gas. To obtain the maximum amount of CeS from a mixture of Ce₂S₃ and Ce, an excess amount of metallic Ce, a stoichiometric composition, was necessary in the synthesis at 1273 K for 10.8 ks. The preliminary sintering experiments also were performed using a synthetic CeS powder containing a small amount of Ce, Ce₂O₂S, and β-Ce₂S₃ as impurities. It was found that the oxygen content in the sintered compact decreases gradually as the sintering temperature increases, because of the removal of the impurities due to the evaporation of the volatile CeO. Single-phase CeS was formed by sintering at 2173 K. To evaluate the activation energy for densification of single-phase CeS, a CeS powder was prepared by milling an initial sintered compact and was used as an ingredient for hot-press experiments. Densification data during hot-press sintering were analyzed using a kinetic equation, showing that boundary diffusion is a rate-limiting process. The results suggest that this boundary diffusion model can explain well the densification data, with an apparent activation energy of 479 kJ·mol^-1.     

Dielectric relaxation phenomenon of rare earth Nd3+ modified bismuth layer ferroelectric ceramics fabricated by plasma active sintering method

Abstract

The crystalline structure, dielectric relaxation and ferroelectric properties of the solid solution, Nd _x Bi_4-x Ti₃O₁₂ (NBIT) compound were measured. The Curie temperature of the NBIT ceramics was determined to be 490°C from dielectric measurements. The dielectric constant of the NBIT ceramics shows a small anisotropic property. Polarization switching was observed using a Sawyer-Tower circuit at 50 Hz. Remnant polarizations and coercive fields could not be confirmed since the hysteresis loops were not saturated. The large dielectric relaxation is observed in the frequency range between 100 kHz and 1 MHz.     

IT2000: A critical appraisal of Singapore's state-wide strategic planning process for information technology

In April 1992, the Singapore Government announced its information technology (IT) vision and plan for the next 15 years to turn Singapore into ‘an intelligent island’, providing a strategic regional switching centre for expertise, goods, services and information. At the heart of this plan is a national information infrastructure that would capitalize on information as a key factor of production and an important ingredient for enhancing the quality of life of its people. Code named ‘IT2000’, the plan was developed by 60 senior managers at the National Computer Board in 1991 with participation and inputs from about 200 business and industry leaders, domain experts and academics. This paper describes the background of Singapore's drive into the information age, the IT2000 planning process, the roles of various participants and the main recommendations of the plan. An evaluation of IT2000 is made in terms of its objectives, its unanticipated results and its impacts on industry participants. Implications and lessons are drawn for strategic IT planning at the national or sectoral level.     

A pictorial index mechanism for model-based matching

We are currently developing unified query processing strategies for image databases. To perform this task, model-based representations of images by content are being used, as well as a hierarchical generalization of a relatively new object-recognition technique called data-driven indexed hypotheses. As the name implies, it is index-based, from which its efficiency derives. Earlier approaches to data-driven model-based object recognition techniques were not capable of handling complex image data containing overlapping, partially visible, and touching objects due to the limitations of the features used for building models. Recently, a few data-driven techniques capable of handling complex image data have been proposed. In these techniques, as in traditional databases, iconic index structures are employed to store the image and shape representation in such a way that searching for a given shape or image feature can be conducted efficiently. Some of these techniques handle the insertion and deletion of shapes and/or image representations very efficiently and with very little influence on the overall system performance. However, the main disadvantage of all previous data-driven implementations is that they are main memory based. In the present paper, we describe a secondary memory implementation of data-driven indexed hypotheses along with some performance studies we have conducted.     

搞定双核处理器“变”单核的问题

不久前笔者购买了一台电脑,采用Intel Pentium E2180双核处理器,在现场验机时,看到开机自检信息和系统属性中均显示出正确的处理器型号,于是就打包拿回了家。不料再开机使用时才发现,任务管理器中只有一颗核心的占用率信息（正常应该是两颗）,而且在CPU-Z和Everest检测软件中均显示处理器型号为Intel Pentium E2180,但核心却只有一个（图1、图2）。难道双核处理器也有假货吗？     

Driving a Wedge Between Evidence and Beliefs: How Online Ideological News Exposure Promotes Political Misperceptions

This article has 2 goals: to provide additional evidence that exposure to ideological online news media contributes to political misperceptions, and to test 3 forms this media‐effect might take. Analyses are based on representative survey data collected during the 2012 U.S. presidential election (N = 1,004). Panel data offer persuasive evidence that biased news site use promotes inaccurate beliefs, while cross‐sectional data provide insight into the nature of these effects. There is no evidence that exposure to ideological media reduces awareness of politically unfavorable evidence, though in some circumstances biased media do promote misunderstandings of it. The strongest and most consistent influence of ideological media exposure is to encourage inaccurate beliefs regardless of what consumers know of the evidence.     

Problematic Instant Messaging Use

This study is an empirical investigation of problematic instant messaging (IM) use among university students in Singapore. It adapts Caplan's (2005) theoretical framework of problematic Internet use (PIU) to the context of problematic IM use by linking pre-existing human dispositions to cognitive-behavioral symptoms and negative outcomes of improper IM use. Four new factors—oral communication apprehension, polychronicity, perceived inconvenience of using offline communication means, and trait procrastination—were tested as predictors of problematic IM use. The results provided strong support for Caplan's theoretical framework of PIU and indicated that oral communication apprehension and perceived inconvenience of using offline means were significant predictors of problematic IM use, whereas polychronicity and trait procrastination were not. The implications of these findings are discussed.     

Collapse of micrometer-sized cavitation bubbles near a rigid boundary

The interaction of cavitation bubbles with a rigid boundary and its dependence on the distance between bubble and boundary is investigated experimentally. Individual cavitation bubbles, with a maximum radius of 150?μm, are generated by using pulsed high-intensity focused ultrasound. Observations are made with high-speed photography with framing rates of up to 200?million frames per second and exposure time of 5?ns, and the spatial resolution is in the order of a few micrometers. The significant parameter of this study is the non-dimensional stand-off parameter, γ, defined as the distance between the ultrasound focus and the rigid boundary scaled by the maximum bubble radius. Both the velocity of the liquid jet developed during bubble collapse and the maximum pressure of the shock wave emitted during bubble rebound show a minimum for γ?≈?1 and a constant value for γ?>?3. The maximum jet velocity is slightly smaller than the corresponding values obtained in the case of millimeter-sized bubbles and ranges from 80?m/s (at γ?≈?1) to 130?m/s (for γ?>?3). No jet formation was observed for γ?>?3. The shock wave pressure, measured at a distance of 5?mm from the emission center, ranges from 0.2?MPa (at γ?≈?1) to 0.65?MPa (for γ?>?3). These values are an order of magnitude smaller than those obtained in the case of millimeter-sized bubbles. The shock wave duration is almost independent of γ at a value of about 75?ns. For large γ values (γ?>?3), a large percentage of the bubble energy (up to 60?%) is transformed into the mechanical energy of the shock wave emitted during bubble rebound but, for γ?≈?1, the conversion efficiency decreases to 30?%. Independent of the relative distance between bubble and rigid boundary, the shock pressure decays proportionally to r ^?1 with increasing distance r from the emission center. The results are discussed with respect to cavitation damage and collateral effects in pulsed high-intensity focused ultrasound surgery.     

Usefulness of Permanent Power Fuse in Control Centers with Molded Case Circuit Breakers

The increase in electric power consumption in industry has led to the development of modern distribution systems such as control centers having high kVA ratings and high prospective fault current. In such a situation, the improvement of the system usefulness such as reliability and cost effectiveness is the essential requirement. An index is presented to evaluate the system usefulness using the cost effectiveness for fault protection in a system of given bank kVA. The index is estimated on four different system structures of control centers, including one which utilizes Permanent Power Fuses (PPF). It is presented that the PPF combined with molded case circuit breaker in main circuit effectively improves the cost effectiveness in control centers with high fault current. Operating principles of the PPF and the control center utilizing the PPF are briefly outlined.