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71.
For development of polymer electrolyte fuel cell (PEFC) lifetime estimation method, a high accuracy PEFC electrode polarization model is required. An electrode polarization model which was previously proposed was verified. However, accuracy of the electrode polarization model was not enough to estimate PEFC performance under various conditions. A new high accuracy PEFC electrode polarization model has been developed based on electrochemical consideration and data observed at elevated pressures. In the cathode polarization model, effects of O2 diffusion and H2O plugging have to be considered to obtain high accuracy for long-term operation. In addition, PEFC performance degradation was analyzed by the electrode polarization model. Main factors of PEFC performance degradation are OCV drop, the cathodic activation polarization, voltage drops by O2 diffusion and H2O plugging. 相似文献
72.
73.
Avidin-containing polyelectrolyte microcapsules were prepared by a layer-by-layer deposition technique and uptake and release
of biotin-labelled fluorescein (b-FITC) was studied. The polyelectrolyte microcapsules were prepared by coating the surface
of calcium carbonate (CaCO3) microparticles containing avidin-poly(styrene sulfonate) (PSS) conjugate, followed by dissolution of CaCO3 core in an ethylenediaminetetraacetic acid solution. Release of avidin from the microcapsules was markedly suppressed due
to formation of a high molecular weight of avidin-PSS conjugate in the microcapsules. The uptake of b-FITC into the microcapsules
was highly enhanced through a strong binding of b-FITC to avidin, as compared to the uptake into avidin-free microcapsules.
Release of b-FITC from the microcapsules was accelerated upon addition of biotin, 2-iminobiotin, or lipoic acid in the solution
due to the competitive binding of the additives to the binding site of avidin. 相似文献
74.
Yoshihiro Itoh Fumiya Sahara Kaori Ozaki Ryo Akasaka Akira Teramoto 《Polymer Bulletin》2011,67(8):1455-1462
Emulsion polymerizations of several vinyl monomers, styrene, methyl methacrylate, butyl methacrylate, butyl acrylate, and
vinyl acetate, in water using alkali–hydrolysable cationic surfactants with a betaine ester group (1-alkoxycarbonylmethyl)trimethylammonium
chlorides, as emulsifiers were carried out and properties of the resulting latices and the polymers recovered by hydrolysis
and salting out were investigated. There were little influences of the surfactants and monomers used here on the polymerizations,
forming stable and monodisperse latices with a mean diameter of ca. 70 nm and giving a high molecular weight of polymers at
high yields. All polymers were precipitated and recovered by adding a small amount of sodium hydroxide into the latex solutions
contained little amount of ionic species. Solvent-cast films of the polymers were found to have surfaces as hydrophobic as
those for the corresponding pure polymers prepared by bulk polymerization. 相似文献
75.
Toshihiko Takaya Hidenori Kawamura Yoshihiro Minagawa Masahito Yamamoto Azuma Ohuchi 《Artificial Life and Robotics》2006,10(2):177-184
Blimp robots are attractive as indoor flying robots because they can float in the air, land safely with low energy, and stay
in motion for a long time compared with other flying robots. However, controlling blimp robots is difficult because they have
nonlinear characteristics, are influenced by air streams, and can easily be influenced by inertia. Therefore, a robust and
adaptive control system is needed for blimp robots. The applied research that has studied the features of indoor flying robots
in recent years has prospered. Operating an indoor blimp robot for a long time is difficult because the payload is small,
multiple batteries cannot be stacked, and the design of a thruster that gives freedom to the entire blimp robot is difficult.
Therefore, an autonomous charge that allows operation for a long time is needed. We have developed a method of landing with
orbital control of the charge point that gives autonomy to a blimp robot. The possibility of landing with orbital control
is shown.
This work was presented in part at the 10th International Symposium on Artificial Life and Robotics, Oita, Japan, February
4–6, 2005
An erratum to this article is available at . 相似文献
76.
77.
An exact analysis of the dynamic problem on the thermal displacements and stresses of cylindrical shells subjected to instantaneous heating is carried out. Equations of motion for cylindrical shells, including the thermal effects, are reduced and solved by using the Fourier and Laplace transformation methods, after obtaining the temperature distribution determined from the nonstationary equation of heat conduction for a shell under a prescribed temperature field. Numerical results are presented for the thermal displacement and stresses due to the time variation together with the quasistatic ones. 相似文献
78.
Summary The permeation characteristics of polymer blend membranes from poly(vinylidene fluoride) and poly-(ethylene glycol) to aqueous polymer solution were investigated under carefully controlled conditions. The permeation characteristics were influenced significantly by the blend ratio, the temperature and time of heat treatment, which changed the structure of the resulting membranes. 相似文献
79.
Summary Random-coiled conformation of poly(L-leucine), which has -branched side-chain, was theoretically analyzed by a conformational energy calculation based on intra-residue interactions. Calculated characteristic ratio 7.62 was obtained by using the transformation matrix statistically averaged over the entire side-chain conformational space of L-Leu residue. This value is smaller than those of poly(L-phenylalanine) (11.24) and poly(L-tyrosine) (12.33) which have -branched side-chain. 相似文献
80.