Wide‐Area Strain Sensors based upon Graphene‐Polymer Composite Coatings Probed by Raman Spectroscopy

Functional graphene optical sensors are now viable due to the recent developments in hand‐held Raman spectroscopy and the chemical vapor deposition (CVD) of graphene films. Herein, the strain in graphene/poly (methyl methacrylate) sensor coatings is followed using Raman band shifts. The performance of an “ideal” mechanically‐exfoliated single crystal graphene flake is compared to a scalable CVD graphene film. The dry‐transferred mechanically exfoliated sample has no residual stresses, whereas the CVD sample is in compression following the solvent evaporation during its transfer. The behavior of the sensors under cyclic deformation shows an initial breakdown of the graphene‐polymer interface with the interface then stabilizing after several cycles. The Raman 2D band shift rates per unit strain of the exfoliated graphene are ≈35% higher than CVD graphene making the former more strain sensitive. However, for practical wide‐area applications, CVD graphene coatings are still viable candidates as a Raman system can be used to read the strain in any 5 μm diameter spot in the coating to an absolute accuracy of ≈0.01% strain and resolution of ≈27 microstrains (μs), which compares favorably to commercial photoelastic systems.     

A downlink beamforming assisted by locally positioned communication devices

Recently, multiple cell types with overlapping coverage have been deployed simultaneously to increase cellular network capacity. Cross‐tier interference is one of the key technical challenges in the use of this method. A simple and practical beamforming scheme assisted by locally positioned communication devices for the downlink of a multi‐cell wireless hierarchical cell structure system is proposed in this paper to maximize the capacity of the embedded small cell and simultaneously ensure minimal impact on the performance of existing macrocells. The locally positioned communication devices can be implemented with low complexity and at low cost and can continuously provide helpful and accurate information to base stations for the proper configuration of geographical cell coverage, allowing neighboring cells to cooperate effectively with each other. Simulation results verify that the proposed scheme can provide a significant gain over conventional systems not using the proposed algorithm. Copyright © 2013 John Wiley & Sons, Ltd.     

High Areal Capacitance of N‐Doped Graphene Synthesized by Arc Discharge

The lack of cost effective, industrial‐scale production methods hinders the widespread applications of graphene materials. In spite of its applicability in the mass production of graphene flakes, arc discharge has not received considerable attention because of its inability to control the synthesis and heteroatom doping. In this study, a facile approach is proposed for improving doping efficiency in N‐doped graphene synthesis through arc discharge by utilizing anodic carbon fillers. Compared to the N‐doped graphene (1–1.5% N) synthesized via the arc process according to previous literature, the resulting graphene flakes show a remarkably increased doping level (≈3.5% N) with noticeable graphitic N enrichment, which is rarely achieved by the conventional process, while simultaneously retaining high turbostratic crystallinity. The electrolyte ion storage of synthesized materials is examined in which synthesized N‐doped graphene material exhibits a remarkable area normalized capacitance of 63 µF cm^?2. The surprisingly high areal capacitance, which is superior to that of most carbon materials, is attributed to the synergistic effect of extrinsic pseudocapacitance, high crystallinity, and abundance of exposed graphene edges. These results highlight the great potentials of N‐doped graphene flakes produced by arc discharge in graphene‐based supercapacitors, along with well‐studied active exfoliated graphene and reduced graphene oxide.     

Open‐Ended Waveguide Antenna Using a Single Split‐Ring Resonator

This letter proposes an open‐ended waveguide antenna with a single split‐ring resonator. In contrast to the waveguide antennas incorporating multiple rings reported in a previous study, which exhibited narrow bandwidth, the proposed antenna uses only one ring to achieve broader bandwidth while keeping the aperture small. A single ring has a relatively low quality factor compared to multiple rings. The simulated and measured fractional bandwidth was 4.13% and 4.03%, respectively, which is much broader than the fractional bandwidth of about 1% demonstrated in a previous study. This simple technique can be used in many applications that require small apertures including near‐field probes and array elements.     

Higher education for the information age

The new generation of engineering professionals needs to know not only the scientific and engineering principles, but also have extensive knowledge about arts, literature, and social sciences. They need far-reaching vision for the future in order to understand grand challenges on the technical-level, the system-level, and the social aspects of topics that are of importance to the modern society. One solution is to emphasize fundamental courses such as mathematics and physics with new interpretation to correlate with real-world applications. It is important to include system-oriented topics in the curriculum so that students know how to apply the basic principles, The key focus should be placed on analysis and design skills, and effective communication is essential to address any large-scale problems     

Polarisation insensitive semiconductor optical amplifier withintegrated electroabsorption modulators

The authors demonstrate a 1.55 μm wavelength multiquantum well semiconductor optical amplifier, integrated with bulk layer electroabsorption modulators and passive waveguide beam expanders at the input and output ports. The device has a fibre to fibre gain of 9 dB, an extinction ratio of 15 dB per modulator, a spectral range >35 nm, and polarisation sensitivity <1 dB     

Enhancement of the photoelectric performance of dye-sensitized solar cells by using a CaCO3-coated TiO2 nanoparticle film as an electrode

Core-shell-type nanoparticles with TiO₂ cores and CaCO₃ shells were applied as the electrode of dye-sensitized solar cells. The performance of the cell was significantly improved (as high as 26.7%) compared to the case when un-coated TiO₂ particle film was used as electrode. The improved energy conversion efficiency has been ascribed to (i) enhanced dye adsorption due to the high isoelectric point of the overlayer, and (ii) the prevention of the back electron transfer by the insulating nature of the overlayer.     

Effect of surface modification of anode with surfactant on the performance of microbial fuel cell

Surface modification of anode using surfactant has great influence on the electrical performance of a microbial fuel cell (MFC). In this study, the effect of surface‐modified exfoliated graphite used for anode fabrication on a cube‐type MFC batch reactor was examined. The surface exfoliated graphite was modified with 5‐mM anionic surfactant, sodium dodecyl sulfate. Anaerobic sludge used as inoculum containing 70% (v/v) of artificial wastewater and 30% (v/v) of seed sludge in an anode chamber and air cathode was used in cathode side. Anode modification was explored as an approach to enhance the start‐up and improve the performance of the reactor. Scanning electron microscopy was used to evaluate the morphology and activity of electrochemically active bacteria. In the study, the start‐up time of MFC required to approach stable voltage was substantially reduced, and the maximum stable voltage was higher than the control. In addition, the activation resistance of the MFC was considerably reduced, and the maximum power density (1640 mW/m²) was 20% higher than control. However, when the surface of exfoliated graphite was modified with over 10‐mM anionic surfactant, some negative effects on start‐up time, activation resistance and maximum power density were observed. This modification also enhanced the bacterial attachment and biofilm formation on the modified anode surface. The result suggested that surface modification anode with surfactant is effective for electrical responses achieved in the MFC. Copyright © 2015 John Wiley & Sons, Ltd.     

FERMENTATION OF WORTS MADE FROM 100% RAW SORGHUM AND ENZYMES

Worts made from raw sorghum and enzymes were successfully fermented even though the level of FAN present (51 mg/l) is well below that essential for fermentation of wort made from malted barley. Changes in typical fermentation parameters such as specific gravity, pH uptake of free amino nitrogen (FAN) and ammonium ions mirrored the increase in yeast cell concentration. Yeast viability remained high throughout the fermentation. Under identical fermentation conditions, malted barley worts showed typical fermentation profiles. However, malted barley worts with specific gravity maintained by the addition of D-glucose, but in which the FAN was diluted to a level similar to that found in a wort made from sorghum and enzymes, fermented more slowly and failed to attenuate fully. Five consecutive fermentations, using yeast cropped from the preceding to pitch the current fermentation were conducted. The specific gravity profiles were essentially the same in all five fermentations. Final values of pH, yeast in suspension, yeast viability and FAN were also indistinguishable. The yeast crop taken from fermentations of worts made from raw sorghum and enzymes represented a 5-fold increase over the initial pitching rate. When compared to commercial beers, the beers derived from fermentation of worts made from raw sorghum and enzymes contained lower levels of ethyl acetate, and higher levels of both 2- and 3-methyl butanol. In the beers derived from sorghum, isobutanol was always less than 20% of the total higher alcohol concentration.