Unsteady effects and heat-transfer when starting up power plant

The results of experimental study of unsteady effects on local heat transfer coefficients caused by abruptly increasing of the gas flow temperature in the inlet section of a cylindrical channel are presented.     

Ultrasonic treatment restores the photoelectric parameters of silicon solar cells degraded under the action of <Superscript>60</Superscript>Co gamma radiation

The photoelectric parameters of silicon solar cells degraded under the action of ⁶⁰Co gamma-radiation can be partly restored using an ultrasonic treatment (UST). The growth of the maximum output power of solar cells after the UST is related to a redistribution of the radiation defects and an increase in the homogeneity of a semiconductor crystal structure.     

Neural-Net Analysis of the Plasticity of ÉP-450 Ferrite–Martensite Steel with Different Alloying Element Concentrations

The results of a computational experiment with a neural-net model simulating the effect of the chemical composition on the plastic properties of ÉP-450 steel are presented. It is shown that computer-aided development of reactor steel with prescribed properties is, in principle, possible.     

Low-temperature pyroelectric properties of Li<Subscript>2</Subscript>SO<Subscript>4</Subscript>

The pyroelectric properties of lithium sulfate have been studied theoretically on the hypothesis of a pseudosymmetry of the structure of its polar phase. Analytical expressions are proposed for the temperature dependences of its pyroelectric polarization and pyroelectric coefficient at low temperatures and near the polymorphic transformation. The pyroelectric and piezoelectric coefficients of a polar crystal are shown to be in direct proportion.     

Mechanism of the skeletal isomerisation of linear butenes over ferrierite: analysis of side reactions

An investigation of the effect of reaction conditions on product distribution in the skeletal isomerisation reaction of linear butenes has been carried out. The main reaction routes over ferrierite have been identified. Beside the main product isobutene, major by-product formation occurs. The unwanted reactions include dimerisation of butene to form octenes, hydrogen transfer yielding small amounts of saturated C₃ and C₄ hydrocarbons and disproportionation producing propene and pentenes. The most abundant by-products were pentene and propene, though these were not formed in equimolar amounts as could be expected. Oligomerisation experiments of propene over ferrierite produced large amounts of butene and pentene, revealing the presence of adsorbed nonene. The cracking of this surface species to hexene and propene is the most likely reaction route for the excess propene formation. This additional path to propene formation operates mainly at temperatures above 623 K.