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991.
Qianyu Yang Chen Gao Xuemei Zhang Xingyu Zhao Yiqing Fu Chihui Tsou Chunyan Zeng Li Yuan Zejun Pu Yiqing Xia Yuping Sheng Yu Fang 《应用聚合物科学杂志》2021,138(13):50308
Shape memory hydrogels (SMHs) can fix the hydrogels in a provisional shape and restore the initial shape under external stimulation. Herein, a dual-responsive shape memory hydrogel with dual-responsive swelling and self-healing properties is presented in this work. The SMHs were fabricated by one-step emulsion copolymerization of acrylic acid (AAc), acrylamide (AAm) and stearyl methacrylate (SMA). Sodium alginate (SA) was introduced as an interpenetrating polymer in the network. With ionic cross-linking between -COO− and Fe3+ or saline-reinforced hydrophobic association, the hydrogels can be fixed in a provisional shape, which can be restored by immersing the hydrogels in vitamin C solution or pure water, respectively. When the as-prepared hydrogels were immersed in FeCl3 solutions, additional ionic cross-linking between Fe3+ and -COO− could be formed, thus constructing the dual physically cross-linked (DPC) network, which endows the hydrogels with excellent fracture stress (2.6 MPa) and toughness (5.47 MJ/m3). Besides, the reversible physical cross-linkings endowed the hydrogel with outstanding self-healing capability. Furthermore, the pH and saline responsive swelling properties of the SMHs are additional fantastic properties. Therefore, we believe that this simple strategy provides a great opportunity for the preparation of SMHs with multiple intellectual performances. 相似文献
992.
Haodong Duan Xiaolei Xu Kangwei Leng Sheng Zhang Yuxi Han Jun Gao Qing Yu Zhongwei Wang 《应用聚合物科学杂志》2021,138(31):50792
The compound (4-fluorophenyl)(phenyl) phosphine oxide (4-FPO) was designed, synthesized, and used in the modification of epoxy resin (EP). The 4-FPO-modified EP was prepared by curing the reaction mixture of diglycidyl ether of bisphenol A (DGEBA) and 4-FPO in the presence of 4,4′-diaminodiphenylsulfone (DDS). Compared with the unmodified EP, the limiting oxygen index value of the EP/4-FPO-0.6 (4-FPO-modified EP with 0.6 wt% of phosphorus) increased to 31.6%, and the sample achieved UL-94 V-0 rating. The peak of the heat release rate, average of the heat release rate, and total heat release of EP/4-FPO-0.6 were reduced by 39, 24, and 19%, respectively. Mechanism study showed that the quenching effect in the gas and barrier effect in the condensed phase were responsible for the enhanced flame-retardant properties of the 4-FPO-modified EP. The results showed that hydrophobicity and dielectric properties of the modified EP were clearly improved. 相似文献
993.
It is still a challenge for simultaneously achieving high heat resistance, high strength and outstanding electrochemical performance for separators in power lithium-ion battery (PLB). Herein, new high performance electrospun separators are developed through building unique structure based on polyimide (PI) and poly (m-phenylene isophthalamide) (PMIA). Orthogonal tests (44) show that the magnitude order of electrospinning factors on the morphology of membrane is concentration>injection rate>receiving distance>voltage. With the optimum factors, the electrospun membrane (PI/PMIA) was prepared, which was further pressed at 100°C for 10 min to get treated membrane (H-PI/PMIA). Interestingly, the comprehensive performance of PI/PMIA is not a simple combination of those of PI and PMIA; instead, PI/PMIA has much better thermal and mechanical properties than both PI and PMIA, proving that PI/PMIA has a synergistic effect. PI/PMIA and H-PI/PMIA not only have good ionic conductivity and electrochemical stability, but also have superiorly high properties including dimensional stability (thermal shrinkage temperature>300°C), tensile strengths (24.1 MPa for PI/PMIA, 34.3 MPa for H-PI/PMIA) and capacity retentions (97.9%, 99.2%) compared with electrospun membranes for PLBs reported in the literature so far (SCI database). The mechanism behind these attractive performances is discussed from condensed structure of membranes. 相似文献
994.
In this study, laser surface treatment was applied to alter the surface texturing and chemical compositions of fused deposition modeling (FDM)-printed PEEK/CF samples to improve the deficiency of inert surface of PEEK as adherend substrate. The influence of IR-laser parameters including treatment gaps, single pulse energy and pulse widths on surface properties and shear bond strength were discussed. The results indicated that surface roughness was enhanced with decreasing treatment gap or increasing pulse energy, which reached the highest value of Ra = 32.44 μm at 0.4*0.4 mm2 treatment gap and 300 mJ single pulse energy. By adjusting laser pulse width, surface wettability changed from hydrophobicity to hydrophilicity. After micro-second laser ablation, the texturing structure was changed and acted as mechanical interlocking effect, and therefore make the shear bond strengths improve from 3.28 to 6.42 MPa compared with the untreated groups. On the other hand, functional groups on substrate surface were activated after nano-second laser ablation, which contributes to an enhancement of shear bond strength through chemical interaction between adhesives and substrates. Therefore, our work highlights an efficient method of laser surface treatment on the adhesion property of FDM-printed substrates. 相似文献
995.
The dodecyl sulfate intercalated CaMgAl-hydrotalcites (layered double hydroxides [LDHs]) were successfully prepared by co-precipitation method, and characterized by X-ray diffraction analysis, infrared spectroscopy (Fourier transform infrared spectra [FT-IR]), thermogravimetry (TG-DTA), scanning electron microscope, and Brunner−Emmet−Teller (BET). The prepared LDHs were added to the intumescent flame retardant (IFR) polypropylene (PP) nanocomposites, and the limiting oxygen index method (LOI), vertical combustion method (UL-94), cone calorimetry (CCT), and other test methods were used to study its thermal stability and combustion performance. The results showed that when the flame retardant was composed of 23 wt% IFR and 2 wt% O-SDS-LDHs, the LOI value of the material was increased to 31.5%, reaching the V-0 level, and the flame retardant performance was significantly improved. The results also showed that there was a significant synergistic effect between IFR and O-SDS-LDHs, which could improve the thermal stability and graphitization degree of PP nanocomposites. In addition, the peak heat release rate, total heat release, and total smoke production of the PP/IFR/O-SDS-LDHs system were 177 kW/m2, 101 MJ/m2, and 15.4 m2, respectively, which were 82.2%, 51.0%, and 23.0% lower than those of pure PP, respectively. These improvements could be attributed to the presence of dense and continuous char layer formed by the synergistic effect. 相似文献
996.
Yan Song Kaifeng Chen Jingjing Wang Yuan Liu Jingzhi Yang Dawei Zhang Tao Qi Guo Liang Li 《应用聚合物科学杂志》2021,138(41):51214
It is highly desirable to develop self-healing anticorrosion coatings with enhanced antibacterial function to prevent the scratched area to be fouled or corroded in harsh environments. Herein, we report antibacterial self-healing anticorrosion coatings via the simple incorporation of the easily synthesized single polymer microcapsule system. Well-defined polymer microcapsules containing isophorone diisocyanate (IPDI) as a healing agent and 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one (DCOIT) as antibacterial molecules were synthesized by one-pot polymerization. The diameter and core fraction were around 30 μm and 90%, respectively. The active DCOIT content in the core material could be precisely controlled by adjusting the DCOIT/IPDI feeding ratio. The DCOIT/IPDI microcapsules-embedded protective coating exhibits an adaptive self-healing anticorrosion property, as shown by electrochemical test under the condition of the salt-water immersion. Furthermore, the self-healing coating showed efficient antibacterial function against Escherichia coli and Pseudomonas aeruginosa, which is due to the released active biocide molecules on the damaged surfaces. In contrast to other systems, this single capsule system without any catalyst is perspective for extending the service time of the antibacterial self-healing materials in harsh environment. 相似文献
997.
Di Bao Fei Xu Yexiang Cui Sicheng Yuan Xiguang Zhang Yanji Zhu Yueyang Gao Huaiyuan Wang 《应用聚合物科学杂志》2021,138(41):51218
High loadings of fillers are usually needed to achieve high-thermal conductivity (TC) of polymer-based composites, which inevitably sacrifices processability and meanwhile causes high-cost. Therefore, it is of great significance to achieve high-TC composites under low-filler loading. Here, a novel p-phenylenediamine (PPD) modified expanded graphite (EG-PPD)/epoxy (EP) composite with high TC and low-filler content was successfully prepared via pre-dispersion and vacuum assisted mixing strategy. With the improved interfacial compatibility between EG and EP by PPD, the prepared EG-PPD/EP composite exhibited excellent thermal management performance, resulting in the TC of which reached 4.00 W·m−1·K−1 with only 10 wt% (5.59 vol%) of EG-PPD, which is approximately 19 times higher than that of pure EP. Meantime, the interface thermal resistance of EG-PPD/EP composite between EG-PPD and EP is reduced by 33% compared with EG/EP composite. This composite with excellent TC property is expected to be used in thermal management field. 相似文献
998.
Dynamic vulcanized thermoplastic polyurethane (TPU)/methyl vinyl silicone rubber (MVQ) thermoplastic vulcanizates (TPVs) were prepared in torque rheometer. The influence of the type and amount of peroxide crosslinking agent on the mechanical properties, thermal stability, micromorphology and melt flowability was systematically investigated. The results showed that the mechanical properties of the TPVs vulcanized by 2,5-dimethyl-2,5-di (tert-butyl peroxy) hexane (DBPH) first increased and then decreased with increasing the peroxide amount, while for dicumyl peroxide (DCP) vulcanizing system the mechanical properties slowly increased. Besides, the comprehensive mechanical properties vulcanized by DBPH were better than those of DCP group. The results of the thermogravimetric analysis showed that the TPVs vulcanized by DBPH had better heat stability, corresponding to the excellent thermo-oxidative aging performance and the 38% increase in tensile strength after aging. In addition, the MVQ rubber particles showed better dispersing performance for DBPH vulcanizing system. The melt flow rate of the TPVs showed a linear relationship with increasing DBPH dosage and became worse after the amount of crosslinking agent exceeded 1.5 phr. By comprehensive comparison, the TPVs have better performance when use peroxide DBPH as the crosslinking agent and the dosage is 1.5 phr. 相似文献
999.
In this work, to improve its dispersion and flame retardancy, graphene oxide (GO) was functionalized by silane coupling agent KH550 and 1-butyl-3-methylimidazole hexafluorophosphate (PF6-ILs), and characteristics of the PF6-ILs@GO was obtained by transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). Then, the synergistic flame retardant of GO or PF6-ILs@GO and melamine pyrophosphate (MPP) were applied for epoxy resin (EP) materials. Specifically, the limiting oxygen index (LOI) value of EP with 0.1 wt% PF6-ILs@GO was increased to 29.2% from 27.5% of EP/MPP composites, and the UL-94 test reached the V-0 rating. The CCT results showed that the total heat release (THR) and total smoke release (TSP) of EP/MPP/PF6-ILs@GO composites were significantly 24.4% and 53.4% lower than that of EP/MPP composites. Besides, the thermal behavior investigated by TGA indicated that the char-forming effect of GO and PF6-ILs@GO was great, the residual char of EP/MPP/PF6-ILs@GO composites was as high as 19.5% at 700°C, and its thermal stability was higher than that of EP/MPP composites. On the other hand, the tensile strength of EP/MPP/GO and EP/MPP/PF6-ILs@GO composites were increased by 15.6% and 28.3% compared with EP/MPP composites. According to SEM analysis, the EP/MPP/GO composites formed a good protective char layer, which can effectively improve flame retardancy of EP. This research represents a new method of flame retardant modified GO to improve the flame retardancy and mechanical properties of polymers. 相似文献
1000.
为适应在线暂态稳定分析与控制,提出了一种电力系统参数空间中的暂态稳定边界构建及快速更新方法.对于给定的关键故障和既定故障前后的网络拓扑结构,首先,基于横向可扩展的宽度学习系统,构建了极限切除时间与电力系统参数之间的映射关系.为提高实际故障切除时间阈值附近的预测准确率,通过构建二次比例因子对临界误差进行修正.然后,结合预设故障切除时间阈值确定相应暂态稳定边界,并评估当前系统的稳定裕度.最后,在保证暂态稳定评估准确性的基础上,基于增量学习方法提出了无须重新训练全部网络的在线快速更新策略.通过对IEEE 39节点测试系统和中国南方电网实例系统仿真分析发现,所构建模型能够对系统暂态稳定性进行准确评估,并具有良好的泛化性能.同时,快速更新策略可在保证预测准确率的情况下,大幅减少模型更新时间,为在线暂态稳定评估提供了支撑. 相似文献