顶空固相微萃取-气相色谱法测定苯胺类化合物

应用自制羟基-二苯并冠醚(OH-DB14C4/OH-TSO)为涂层的固相微萃取探头,采用气相色谱法测定苯胺(A)、间甲苯胺(MT)、N,N-二乙基苯胺(NNDEA)、N-乙基间甲苯胺(NEMT)和3,4-二甲基苯胺(3,4-DMA).并对固相微萃取的最佳条件进行了优化.顶空固相微萃取-气相色谱法的检测限(LOD)为0.17～0.98 ng·ml-1,相对标准偏差(RSD)为3.23%～6.20%,线性范围(LR)为0.11～29 μg·ml-1.对药厂废水的3,4-DMA进行了分析,其回收率为86%～90%.     

Impact fracture behavior of clay-reinforced polypropylene nanocomposites

The micromechanism of plastic deformation during impact loading of polypropylene-clay nanocomposites is examined and compared with the unreinforced polypropylene under identical conditions of processing to underscore the determining role of clay. The addition of clay to polypropylene increases the impact strength in the temperature range of 0 to +70 °C. Differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and transmission electron microscopy (TEM), wide-angle X-ray diffraction (WAXD) and scanning electron microscopy (SEM) techniques provided an understanding of the micromechanism of plastic deformation in terms of the response of the polymer matrix, nucleating capability of the reinforcement, crystal structure, percentage crystallinity, lamellae thickness, and particle-matrix interface. The enhancement of toughness on reinforcement of polypropylene with nanoclay is associated with change in the primary mechanism of plastic deformation from crazing and vein-type in neat polypropylene to microvoid-coalescence-fibrillation process in the nanocomposite.     

阻燃性有机硅高分子材料的研究进展

综述了国内外在阻燃性有机硅高分子材料的制备、性能及应用等方面的研究进展，介绍了有机硅高分子材料的燃烧历程、常用阻燃剂及其阻燃机理，并对阻燃性有机硅高分子材料的研究发展前景进行了展望。     

仿土质专用肥的开发和应用前景

本文介绍了基于某些名、优农产品在其生长过程中所需要的特定敏感元素,配制出“仿土质”专用肥。经施用证明,肥效显著,经济效益可观,具有推广应用的前景。     

New liquid membrane technology for simultaneous extraction and stripping of copper(II) from wastewater

In this paper, a new liquid membrane technique, hollow fiber renewal liquid membrane (HFRLM), is presented, which is based on the surface renewal theory, and integrates the advantages of fiber membrane extraction, liquid film permeation and other liquid membrane processes. The results from the system of CuSO₄+D2EHPA in kerosene+HCl show that the HFRLM process is very stable. The liquid membrane is renewed constantly during the process, the direct contact of organic droplets and aqueous phase provides large mass transfer area. These effects can significantly reduce the mass transfer resistance in the lumen side. Then the mixture of feed phase and organic phase flowing through the lumen side gives a higher mass transfer rate than that of stripping phase and organic phase, because the aqueous layer diffusion of feed phase is the rate-controlling step. The overall mass transfer coefficient increases with increasing flow rates and D2EHPA concentration in the organic phase, and with decreasing initial copper concentration in the feed phase. The overall mass transfer coefficient also increases with increasing pH in the feed phase, and reaches a maximum value at pH of 4.44, then decreases. Also, there is a favorable w/o volume ratio of 20:1 to 30:1 for this process. Compared with hollow fiber supported liquid membrane and hollow fiber membrane extraction processes, HFRLM process has a high mass transfer rate. Mathematical model for the HFRLM process based on the surface renewal theory is developed. The calculated results are in good agreement with experimental results under the conditions studied.     

2005年国外有机硅进展

根据2005年公开发表的相关资料,对1年来国外有机硅的市场状况作了分析,重点介绍了1年来国外几大有机硅公司的动向及产品开发情况。     

Synthesis and structure of the n = 4 member of the framework aluminium alkylenediphosphonate series Al2[O3PCnH2nPO3](H2O)2F2

We report here the solvothermal synthesis and crystal structure of the hybrid inorganic-organic framework material Al₂[O₃PC₄H₈PO₃](H₂O)₂F₂⋅2H₂O (monoclinic, 1P2₁/m, a = 4.961(2) ?, b = 11.930(5) ?, c = 10.727(5) ?, β = 93.972(6)^∘, Z = 2, R(F, F² > 2σ) = 0.094, R_w(F², all data) = 0.262), the third member of the Al₂[O₃PC_nH_2nPO₃](H₂O)₂F₂ framework series. The structure is formed from corrugated chains of corner-sharing AlO₄F₂ octahedra in which alternating AlO₄F₂ octahedra contain two fluorine atoms in a trans or a cis configuration. The diphosphonate groups link the chains together through Al-O-P-O-Al bridges and through the butyl groups to form a three-dimensional framework structure containing a one-dimensional channel system consisting of one type of channel only. The channels contain four extra-framework water molecules per unit cell. The formation of this member of the series shows that the form of the alkyl chain can successfully define the number of channel types and the channel length in this hybrid framework system.     

基于共轭梯度法的FIR数字滤波器优化设计

针对高阶FIR数字滤波器要中高阶矩阵逆计算困难,提出了一种共轭梯度法的FIR线性相位数字滤波器的优化设计方法.方法的主要思想是采用共轭梯度法计算余弦基函数的加权系数,从而获得FIR滤波器的单位脉冲响应,使得设计出的FIR滤波器的频率响应与理想滤波器的频率响应的全局误差在整个通带和阻带的范围内最小.仿真结果表明,与其它优化设计方法相比,提出的优化设计方法不仅具有更小的逼近误差,而且过渡带窄,阻带衰耗更大.上述方法不涉及逆矩阵计算,因而计算量小,在FIR数字滤波器优化设计中具有重要的应用价值.     

活化硅灰石粉新型填料的研制以及在PVC电缆料上的应用

本文介绍新型填料活化硅灰石粉的研制以及在ＰＶＣ电缆料上的应用，并建立了一种活化指数新概念来判断活化效果。经表面活化处理后的活性硅灰石粉吸水率降低、吸油率变小、粒径变细、活化指数〉９．０。由活性硅灰石粉在ＰＶＣ电缆料中的填充试验表明，在原配方基础上添加１０份活性硅灰石粉，电缆料性能良好，符合国家标准，成本降低。     

乳化环氧改性的丙烯酸系乳液室温固化体系

将乙二醇二缩水甘油醚分散在水中制成环氧化合物乳液,并以其为交联剂,用以对丙烯酸系单体/胺基单体乳液共聚物的改性,制成了双组分室温固化乳液涂料。研究了乳化剂种类和胺基单体用量对聚合稳定性的影响,结果表明,若采用p 壬基酚聚氧化乙烯醚硫酸钠为乳化剂,且胺基单体用量低于单体总量2 5%时,可以制得稳定的带胺基的共聚物乳液。将丙烯酸系共聚物乳液和环氧乳液复合并在室温下干燥成膜,通过对聚合物膜的DSC和力学性能测试均表明,双组分体系在成膜过程中发生了交朕反应,而未加环氧化合物的单组分聚合物乳液成膜时则不发生交联。