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991.
Chun Lin Ma Qing Feng Wang Rufen Zhang Jikun Li 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(2):229-235
Six triorganotin(IV) complexes of the type {(R3Sn)2[C3S3(COO)2]}n (R = C6H5 1; n-Bu 2; PhCH2 4; p-F-PhCH2 5; o-F-PhCH2 6) and {(R3Sn)2[C3S3(COO)2]}n·[EtOH] (R = Me 3) have been synthesized by the reaction of bis(carboxymethyl)trithiocarbonate with triorganotin(IV) chloride
in the presence of sodium ethoxide. All complexes were characterized by elemental analysis IR, 1H, 13C and 119Sn NMR spectroscopy. Except for 4–6, all complexes were also characterized by X-ray crystallography. The X-ray date revealed
that complexes 1–3 show two-dimensional network polymeric structure in which the geometries of tin atoms are trigonal bipyramid
with the axial positions occupied by carboxylic oxygen atoms. 相似文献
992.
Cubic boron nitride (c-BN) crystals were synthesized in conditions of high temperature and high pressure (HTHP) when different kinds of bonded water were respectively added into the system of h-BN–Mg. All bonded water used in this work could reduce the temperature of growing c-BN compared to that in the system of h-BN–Mg. The c-BN color could change from black to yellow when certain amounts of bonded water, such as NiSO4·6H2O and CuSO4·5H2O, Mg(OH)2, were added. However, c-BN color remained black no matter how much bonded water, such as NiCl2·6H2O, CuCl2·2H2O, and SnCl2·2H2O, was added. The bonded water can be classified into Chlorine-containing bonded water (Cl-BW) and Chlorine-free bonded water (ClF-BW) according to their different characters and effects on the synthesized c-BN color. 相似文献
993.
Hydrothermal Synthesis of Magnesium Aluminate Platelets 总被引:1,自引:0,他引:1
Zhi-Zhan Chen Er-Wei Shi Hua-Wei Zhang Yong Zhang Xiang-Biao Li Xue-Chao Liu Bing Xiao 《Journal of the American Ceramic Society》2006,89(12):3635-3637
Magnesium aluminate (MgAl2 O4 ) platelets were first synthesized by hydrothermal treatment of γ-AlO(OH) in a magnesium nitrate aqueous solution at 400°C. The platelets are 100–200 nm in width and 25 nm in thickness. The influence of temperature, the anions of the magnesium salt, the amount of magnesium salt, and precursor pH on the formation of such structure was investigated. The experimental results indicated that the anions of the magnesium salt and precursor pH could have a significant influence on the growth of MgAl2 O4 . MgAl2 O4 formation followed the in situ transformation mechanism, which was the reason why the MgAl2 O4 crystallites had a platelet morphology. 相似文献
994.
In this work the synergistic effects of microwave (MW) irradiation induced oxidation processes and CoFe2O4 were studied for the degradation of brilliant green (BG) from aqueous solutions. Under the optimum condition, the ratio of solid to liquid was 1:167 (0.3 g CoFe2O4 mixed with 50 mL of 20 mg L−1 BG solution), MW power 600 W, and the time of the irradiation 2 min. And the decolorization rate could reach up to 100%. Further investigation showed that BG was degraded by MW-induced oxidation combined with CoFe2O4 surface adsorption. The CoFe2O4 could increase the efficiencies of MW degradation and be used repeatedly. The experimental results indicated that the method of MW degradation BG in the presence of CoFe2O4 could reduce reaction time and increase product yield. 相似文献
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张学军 《精细石油化工进展》2003,4(11):10-11
柴油抗蜡分散剂PDN -3 0 2 3应用试验表明 ,抗蜡分散剂能有效改变蜡结晶的形状及尺寸 ,抑制蜡结晶的生长 ,有助于蜡晶体在柴油中分布得更均匀。 相似文献
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