一种基于模型修正的结构损伤识别方法

基于模型修正技术提出一种结构损伤识别方法。首先通过建立带约束边界非线性最小二乘目标函数，极小化结构实测模态与分析模态之间误差，将损伤识别问题转化为优化问题。其次采用信赖域方法求解该优化问题使优化过程具有更强的鲁棒性和可靠性。然后提出一种目标函数向量扩充方法并进行了参数优化研究。最后通过一栓接框架损伤试验研究，验证了该识别方法应用于结构损伤识别的可行性和有效性。     

<Emphasis Type="Italic">In situ</Emphasis> synthesis of graphene oxide/gold nanorods theranostic hybrids for efficient tumor computed tomography imaging and photothermal therapy

Graphene oxide/gold nanorod (GO/GNR) nanohybrids were synthesized with a GO- and gold-seed-mediated in situ growth method at room temperature by mixing polystyrene sulfonate (PSS) functionalized GO, secondary growth solution, and gold seeds. Compared with ex situ preparation methods of GO/GNRs or graphene (G)/GNRs, the in situ synthesis of GO/GNRs addressed the issue of the aggregation of the GNRs before their attachment onto the GO. The method is straightforward and environment-friendly. The GO/GNRs showed a remarkable photothermal effect in vitro. The temperature of the GO/GNR nanohybrids increased from 25 to 49.9 °C at a concentration of 50 μg/mL after irradiation with an 808-nm laser (0.4 W/cm²) for 6 min. Additionally, the GO/GNRs exhibited good optical and morphological stability and photothermal properties after six cycles of laser irradiation. Upon injection of the GO/GNRs into xenograft tumors, excellent computed tomography (CT) imaging properties and photothermal effect were obtained. The preclinical CT agent iohexol was combined with the GO/GNRs and further enhanced CT imaging. Therefore, the GO/GNR nanohybrids have great potential for precise CT-image-guided tumor photothermal treatment.

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Integrated liquid crystal optical switch based on double teeth-shaped structure at telecom wavelengths

The characteristics of a double teeth-shaped plasmonic optical switch are analyzed. Based on the metal–insulator–metal waveguide consisting of double rectangular teeth, a nanoscale liquid crystal optical switch is proposed and numerically simulated by using the finite difference time domain method with a perfectly matched layer absorbing boundary condition. It is found that the double teeth-shaped structure filled with liquid crystal can realize the function of a switch. The modulation depth of the double teeth-shaped structure is larger than 50?dB.     

直接法合成三烷氧基硅烷的研究进展

综述了直接法合成三烷氧基硅烷反应机理、所用原料、溶剂、催化剂以及分离纯化工艺.并对其发展前景进行了展望.     

Toward a molecular design of porous carbon materials

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Synergizing Phase and Cavity in CoMoOxSy Yolk–Shell Anodes to Co‐Enhance Capacity and Rate Capability in Sodium Storage

Sodium‐ion batteries (SIBs) have been recognized as the promising alternatives to lithium‐ion batteries for large‐scale applications owing to their abundant sodium resource. Currently, one significant challenge for SIBs is to explore feasible anodes with high specific capacity and reversible pulverization‐free Na⁺ insertion/extraction. Herein, a facile co‐engineering on polymorph phases and cavity structures is developed based on CoMo‐glycerate by scalable solvothermal sulfidation. The optimized strategy enables the construction of CoMoO_xS_y with synergized partially sulfidized amorphous phase and yolk–shell confined cavity. When developed as anodes for SIBs, such CoMoO_xS_y electrodes deliver a high reversible capacity of 479.4 mA h g^?1 at 200 mA g^?1 after 100 cycles and a high rate capacity of 435.2 mA h g^?1 even at 2000 mA g^?1, demonstrating superior capacity and rate capability. These are attributed to the unique dual merits of the anodes, that is, the elastic bountiful reaction pathways favored by the sulfidation‐induced amorphous phase and the sodiation/desodiation accommodatable space benefits from the yolk–shell cavity. Such yolk–shell nano‐battery materials are merited with co‐tunable phases and structures, facile scalable fabrication, and excellent capacity and rate capability in sodium storage. This provides an opportunity to develop advanced practical electrochemical sodium storage in the future.     

Effect of selective laser melting on microstructure and properties of AZ91D alloy

Selective laser melting technology is used to manufacture porous and solid AZ91D alloys. The effects of laser power and hatch spacing on the density, blowholes, microstructure and mechanical properties of AZ91D alloy are studied. The laser power and hatch spacing play a significant role in the density and blowholes of AZ91D specimens. The grains size of specimens increases from 1 μm–2 μm to 8 μm–10 μm from the bottom to the top in single molten pool. Compared with grain size of die‐casting alloy (30 μm), that of selective laser melted gets refinement. There is no significant change in microstructure in the bottom, middle and top of specimens. The micro‐hardness of AZ91D alloy, reaching up to 115.3 HV 0.1, is superior to that of die‐casting alloy (56 HV 0.1). The compression properties of porous and solid specimens reach the degree of die‐casting solid magnesium alloy. AZ91D alloy shows the potential in the application of medical biodegradable materials.     

纳米流体强化相变蓄冷的数值模拟

采用Fluen软件对封闭腔内Cu-H2O纳米流体强化相变蓄冷进行了数值模拟,重点分析Cu纳米粒子添加量和Gr数对蓄冷性能的影响,并解释其换热机理.研究结果表明:Gr数对其结冰时间影响不大,但纳米流体的质量分数是影响纳米流结冰时间的一个主要因素.对于一给定的Gr数,随着纳米粒子质量分数的增加,结冰时间减少,这是由于纳米流体相比基液具有较高的导热系数.另一方面,由于纳米流体融解潜热降低,则纳米流体结冰时,每单位质量的纳米流体需要的能量较少,所以纳米流体具有较高的热释放率,在相变储能应用中具有巨大优势.     

Crystallographically-oriented nanoassembly by ZnS tricrystals and subsequent three-dimensional epitaxy

Chemistry gives us the ability to manipulate atoms and molecules into nanometer and micrometer scale building blocks, while the science of crystallography is concerned with the spatial arrangement of atoms, ions, and molecules and thus the morphology and structures of materials. Complex three-dimensional ZnS nanostructures have been fabricated via step-by-step crystallographically-controlled chemical processes. Tricrystals of ZnS whiskers were prepared via a controlled thermal evaporation process, and then the tricrystals were thermally treated in an atmosphere formed by evaporating B-N-O precursors into N₂/NH₃ to afford BN-coated arrays of nanobranches. The ZnS nanobranches grew epitaxially on the ternary facets and extended in three [0001] directions forming ordered nanostructures. Meanwhile, the protecting insulating sheath of BN formed on the ZnS nanostructures confined the growth of the nanospines and enhanced their stability. The method may be extended to fabricate other semiconductor nanomaterials with novel structures.      

Self‐Assembly of Hyperbranched Polymers and Its Biomedical Applications

Hyperbranched polymers (HBPs) are highly branched macromolecules with a three‐dimensional dendritic architecture. Due to their unique topological structure and interesting physical/chemical properties, HBPs have attracted wide attention from both academia and industry. In this paper, the recent developments in HBP self‐assembly and their biomedical applications have been comprehensively reviewed. Many delicate supramolecular structures from zero‐dimension (0D) to three‐dimension (3D), such as micelles, fibers, tubes, vesicles, membranes, large compound vesicles and physical gels, have been prepared through the solution or interfacial self‐assembly of amphiphilic HBPs. In addition, these supramolecular structures have shown promising applications in the biomedical areas including drug delivery, protein purification/detection/delivery, gene transfection, antibacterial/antifouling materials and cytomimetic chemistry. Such developments promote the interdiscipline researches among surpramolecular chemistry, biomedical chemistry, nano­technology and functional materials.