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2.
The structure and properties of high density polyethylene (HDPE) functionalized by ultraviolet irradiation at different light intensities in air were studied by electron analysis, FTIR spectroscopy, contact angle with water, differential scanning calorimetry and mechanical properties measurement. The results show that oxygen‐containing groups such as C?O, C—O and C(?O)O were introduced onto the molecular chain of HDPE following irradiation, and the rate and efficiency of HDPE functionalization increased with enhancement of irradiation intensity. After irradiation, the melting temperature, contact angle with water and notched impact strength of HDPE decreased, the degree of crystallinity increased, and their variation amplitude increased with irradiation intensity. Compared with HDPE, the yield strength of HDPE irradiated at lower light intensity (32 W m?2 and 45 W m?2) increases monotonically with irradiation time, and the yield strength of HDPE irradiated at higher light intensity (78 W m?2) increases up to 48 h and then decreased with further increase in irradiation time. The irradiated HDPE behaved as a compatibilizer in HDPE/polycarbonate (PC) blends, and the interface bonding between HDPE and PC was ameliorated. After adding 20 wt% HDPE irradiated at 78 W m?2 irradiation intensity for 24 h to HDPE/PC blends, the tensile yield strength and notched Izod impact strength of the blend were increased from 26.3 MPa and 51 J m?1 to 30.2 MPa and 158 J m?1, respectively. Copyright © 2003 Society of Chemical Industry 相似文献
3.
Studies on the deactivations and initiations of gas phase polymerizations of 1,3‐butadiene have been achieved by Monte Carlo simulation. Initiation and deactivation control the reaction before and after the peak of the polymerization rate, respectively. The influence of polymerization temperature has been studied. Monte Carlo modeling of polymerization kinetics and mechanism was confirmed by the agreement of experimental data and simulation results of polymerizations run with a temporary evacuation of monomer. The balance of catalysts and active chains is established by both initiation and chain transfer reactions with cocatalyst, which causes a ‘pseudo‐stability’ stage. © 2003 Society of Chemical Industry 相似文献
4.
Liang Y.C. Wenjiang Zeng Pick Hong Ong Zhaoxia Gao Jun Cai Balasubramanian N. 《Electron Device Letters, IEEE》2002,23(12):700-703
In this letter, a concise process technology is proposed for the first time to enable the fabrication of good quality three-dimensional (3-D) suspended radio frequency (RF) micro-inductors on bulk silicon, without utilizing the lithography process on sidewall and trench-bottom patterning. Samples were fabricated to demonstrate the applicability of the proposed process technology. 相似文献
5.
STEP-NC是由欧美提出的新的数控接口标准,目的是取代旧的数控标准ISO6983。本文首先分析了STEP-NC的两种应用标准:ISO14649(ARM)和STEPAP238(AIM),并且分析了Part21和Part28的应用领域及Part21文件格式和其中的信息产生方法。然後介绍了ST-Developer环境下ROSEC++颠库编程接口及其应用程序的早、晚编联方式,并且以此为基础设计了整个程序的编程流程,重点介绍了工艺规划设计。最后给出了在C++编程环境下利用ROSE库函数写入形成STEP AP238文件的方法。 相似文献
6.
A nuclear microprobe with high spatial resolution and high analytical sensitivity was applied to analyze trace elements,especially lead,in vehicle exhaust of Shanghai city.The result shows that the chemical composition and its corresponding x-ray relative intensity are different among different vehicle exhausts.There are many kinds of metal elements in particles of vehicle exhaust.most are harmful to people,such as Ti,Cr,Mn,Pb,etc.We found that the lead concentration was 6820μg/g and the bromine concentration was 5300μg/g in the exhaust from Santana using leaded gasoline(SULG).which is higher than any other kinds of vehicle exhausts.We have also detected the minimum lead in the particles of unleaded gasoline and its content varies from one to another.Its mean concentration was 450μg/g and the highest reached 6210μg/g.The unleaded gasoline‘s Pb existed in the whole particle while the leaded gasoline‘s enriched in the surface of the particle and was more harmful to the human beings. 相似文献
7.
Successful operation of the Synchronous Overlap and Add (SOLA) algorithm for Time Scale Modification (TSM) of speech is closely tied to the proper choice of parameters. This paper investigates the quality of time scale modified speech under different values of primary parameters. Based on Mean Opinion Score (MOS) tests and Bark Spectral Distortion (BSD) measure, the proper choices of synthesis shift (Ss) and the duration of the shift search interval (K max?) are given experimentally. The conclusions can be helpful for operating the SOLA algorithm for time scale modification of speech. 相似文献
8.
Jun Chen Berger T. 《IEEE transactions on information theory / Professional Technical Group on Information Theory》2008,54(8):3385-3398
We consider a distributed source coding system in which several observations must be encoded separately and communicated to the decoder by using limited transmission rate. We introduce a robust distributed coding scheme which flexibly trades off between system robustness and compression efficiency. The optimality of this coding scheme is proved for various special cases. 相似文献
9.
2007年国外有机硅进展 总被引:2,自引:0,他引:2
根据2007年公开发表的相关资料,综述了2007年国外有机硅行业的市场动向、行业动向及有机硅产品的研发进展. 相似文献
10.