纳秒激光加工PCD表面织构的摩擦磨损行为研究

采用最大功率100 W,脉冲宽度120 ns,重复频率50 MHz的纳秒激光在聚晶金刚石(PCD)复合片表面加工了名义深度分别为50 mm、150 mm的等边三角形截面槽型织构.采用光学干涉显微镜、光学金相显微镜、扫描电子显微镜、X射线光电子仪等分析表征表面形貌组织;采用球盘式摩擦磨损仪研究了织构对PCD样片的摩擦行为...     

涂层结构对Ti-Al-N涂层氧化行为的影响

采用多弧离子镀技术及TiA合金靶,在SKH51高速钢基体上沉积了Ti1-xAlxN单层构型涂层和TN/Ti1_xAlxN复合多层构型涂层,分析其高温氧化行为.用扫描电镜、X射线衍射、电子探针等手段表征了涂层氧化后的组织结构和元素分布.试验发现,基体Fe元素扩散到涂层表面意味着SKH51涂层试样剧烈氧化阶段的开始.当涂层的构型相同时,涂层的抗氧化性能随着涂层中铝含量增加而单调增加.但对于TiN/Ti0.33Al0.67N复合多层构型涂层,其抗氧化性则比Ti0.33Al0.67N单层构型涂层差,高于铝含量基本相同的Ti0.67A0.33N单层构型涂层.空气中800℃恒温退火,TiN/Ti0.33 Al0.67N涂层出现严重氧化的时间是43h,Ti0.33Al0.67N、Ti0.67Al0.33N涂层分别为53 h和11h.因此,Ti-Al-N涂层的抗氧化性不仅同涂层中铝含量有关,涂层构型也起着重要用.     

Al2O3-SiO2/AZ91D镁基复合材料的制备及其性能研究

采用硅酸铝纤维和镁合金制备出结构紧密的A1:O,-SiO:/AZ91D镁基复合材料.介绍了复合材料的制备工艺,适宜的挤压铸造工艺为:基体温度650℃、模具温度550℃、浇注温度760℃和压力30～50 MPa.XRD、SEM、EDS和光学金相显微镜OM等分析结果表明:复合材料主要由Mg、β-Mg.,Al12、MgO、AlPO4、3Al2O3·2SiO2和Mg2 Si等结晶相组成;镁与硅酸铝纤维反应生成MgO和汉字状Mg2Si等产物;基体镁与硅酸铝纤维的界面形成比较紧密的结合层.与镁合金相比,复合材料的硬度和油摩擦性能有较大提高.     

Micro-yield behaviors of Al2O3-SiO2（sf）/Al-Si metal matrix composites

Effects of the volume fraction and the size of crystallized alumina silicate short fibers as well as heat treatment processes on micro-yield strength（MYS） of Al2O3-SiO2（sf）/Al-Si metal matrix composite（MMC） that was fabricated by squeezing cast, were investigated by using continuous loading method on an Instron 5569 tester with a special extensometer with an accuracy of 10^-7. The results show that MYS of MMC decreases with the increase of volume fraction and length of the alumina silicate short fibers in the metal matrix composite, respectively. MYS of quenched Al2O3-SiO2（sf）/Al -Si MMC is the lowest, MYS of the MMC through peak-aging treatment is higher than that through other heat treatment methods. And before the peak-aging, MYS of MMC aging treated gradually increases with the increase of the aging time. Aging treatment after solution treatment is a preferred way that enhances micro and macro-yield strength of Al2O3-SiO2（sf）/Al-Si MMC.     

预处理对金刚石薄膜质量及结合力的影响

目的改善硬质合金表面金刚石薄膜的结合力。方法采用热丝CVD法在硬质合金基体上制备金刚石薄膜,研究对比喷砂+一步法、喷砂+两步法、Al Cr N过渡层和传统两步法这四种预处理对金刚石薄膜质量及其结合性能的影响。对预处理后硬质合金基体表面的形貌和粗糙度进行分析,并通过扫描电子显微镜、X射线衍射、拉曼光谱及洛氏硬度计表征金刚石薄膜的形貌、结构及性能。结果喷砂有利于在基体表面获得均匀分布的凹坑,提高金刚石的形核密度及均匀性,尤其改善了金刚石颗粒的团聚现象。Al Cr N过渡层虽然表面粗糙度不高,但有大量的凸起颗粒,提供了极佳的形核点,也在一定程度上优于传统两步法的表面金刚石形核密度。在金刚石薄膜沉积参数不变的前提下,传统两步法预处理获得的涂层结合力为HF4级,喷砂结合一步法和两步法获得的结合力分别达到了HF3级和HF1级,但Al Cr N过渡层的结合力表现较差。结论 Al Cr N过渡层能阻挡Co的扩散,提高了金刚石的纯度,但金刚石膜的内应力较大,结合力差。喷砂和刻蚀复合预处理不仅能提高金刚石的结晶质量和纯度,金刚石薄膜的结合力也得到改善。     

A356铝合金的强韧化工艺研究

研究了A356铝合金的组织结构特点及强韧化工艺控制,通过采取细化组织、硅相变质、微合金化处理及优化热处理工艺等措施和手段提高车轮用A356铝合金的强韧化效果.     

微弧氧化法制备磁性薄膜的研究

采用微弧氧化法以FeSO4溶液在钛金属表面制备超顺磁性薄膜．用IR、XRD和SEM等表征了磁性薄膜的组成和形貌，结果表明磁性薄膜主要由Fe3O4和（Fe2O3）x·2H2O晶体组成．推断了磁性薄膜的形成机理．     

连铸结晶器内钢液流场的数值模拟

采用商业软件,针对连铸机结晶器的结构和工艺参数,进行了流动过程的三维数值模拟,分析了浸入式水口的浸入深度、水口侧孔倾角和拉速对结晶器内钢液流动的影响.结果表明,合适的浸入深度、水口侧孔倾角和拉速有利于夹杂物的上浮,减小液面波动.     

织构对锆合金拉伸和爆破性能的影响

研究了两种组织形貌相似的核燃料包壳管材M5和N36锆合金的拉伸性能和爆破性能．利用X射线衍射仪分析了它们的织构．试验结果表明，两种材料表现出明显的各向异性．同时分析了织构因素对Schmiidt因子的影响，结合研究管材的力学性能各向异性，建立了拉伸、爆破屈服强度同织构的定性关系．     

Synthesis of tetragonal BaTiO3 film on Ti substrate by micro-arc oxidation

BaTiO3 films on Ti substrate were fabricated by alternative current（AC） and direct current（DC） micro arc oxidation （MAO）. Microstructures of films were investigated by means of SEM, XRD and TEM. The results show that the amorphous phase and primitive cubic phase are the main phases in the films prepared by AC MAO. Even after being annealed at 1 200 ℃ for 8 h, only a few tetragonal phases can be observed in films prepared by AC MAO. However, tetragonal BaTiO3 phase can be produced by DC MAO directly. In the films prepared by DC MAO, a mixture of cubic phase and tetragonal phase is formed. After sparking spacious distribution, sparking duration and temperature gradient near sparking sites were taken into account, and a mechanism of synthesis of tetragonal BaTiO3 phase by DC MAO was proposed.