Preparation and electrochemical properties of nanosized tin dioxide electrode material by sol-gel process

1　INTRODUCTIONTinoxideisawideenergy gapsemiconductorandhasfoundmanytechnologicalapplicationssuchascatalystsforoxidationoforganics,solid stategassen sorsandopticalelectronicdevices[1,2 ] .Recently ,sev eraltin oxide basedcompoundswerereportedtobegoodcandidatesasanodesforlithiumionbatteriesin steadofcarbonaceouselectrodes[36 ] ,theelectro chemicalreactionoccurringinthesecompoundsisnottheintercalationoflithiumintoahoststructure .Forbulksamplesofamorphousandcrystallinetinoxide ,adecomposition…     

Synthesis and electrochemical properties of polyradical cathode material for lithium second batteries

A stable polyradical, poly (2 ,2,6,6-tetramethylpiperidinyloxy methacrylate)(PTMA) , was synthesized, and its structure was determined by infrared, ultraviolet-visible, and ESR spectroscopy. Cyclic voltammograms of the PTMA polyradical electrodes were obtained by using a three-electrode cell at a scan rate of 5 mV/s within a potential range of 3. 2-4. 0 V. The results show that the shape of oxidation peak is very similar to that of reduction peak, and oxidation peak current is equal to the corresponding reduction peak current, which suggest that PTMA possesses an excellent reversibility. The difference of the anodic peak potential (Ea,p = 3. 66 V, vs Li/Li+) and ca-thodic peak potential(Ec,p = 3. 58 V, vs Li/Li+ ) is estimated at 80 mV, which is extremely less than that of the other organic positive materials in lithium second batteries such as organosulfide compounds, leading to a capability for high current capability in the charging and discharging process of the battery. The maximum discharge specif     

Soft chemical synthesis and electrochemical properties of tin oxide-based materials as anodes for lithium ion batteries

1　INTRODUCTIONWiththedevelopmentoflithiumionbatteries ,thereisanincreasingdemandforelectrodematerialspossessinghighcapacity .Muchresearchwasunder takentosearchfornewanodematerialsin placeofcarbon (theoreticalmaximumcapacityof 372mA·h·g- 1)toimproveenergydensityforrechargeablelithi umionbatteries[110 ] .Notably ,tinoxide basedmate rials ,aspossiblecandidatesforthenextgenerationanodematerialsforLi ionbatteriesduetotheirhighlithiumstoragecapacityandlow potentialoflithiumionintercalation ,…     

Influence of polyethylene glycol on pore structure and electric double-layer capacitance of carbon xerogel

Mesoporous polyethylene glycol-resorcinol and formaldehyde(PEG-RF) carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable polyethylene glycol with organic monomers, resorcinol and formaldehyde and then subjected to pyrolization at 1 000℃. The influences of mass ratio of PEG to the theoretical yield of RF xerogel, m(PEG)/m(RF) and the relative molecular mass of PEG on the pore structure and electric double layer capacitance(EDLC) performance of PEG-RF carbon xerogels were investigated. The results show that PEG under different conditions leads to the difference of phase separation structure of the polymer blend and thus the change of pore structure of PEG-RF carbon xerogels. Specific surface area and capacity of PEG-RF carbon xerogels in 300/60 H2SO4 solution can reach 755 m^2/g and 150 F/g, respectively. Their surface can be fully utilized to form electric double layer. However, the pore structure differences of PEG-RF carbon xerogels result in their different EDLC performances. The distributed capacitance effect increases with decreasing the pore size of PEG-RF carbon xerogels.     

草酸铜掺杂DMcT/PAn的氧化还原反应机理

通过循环伏安、Raman光谱和红外光谱研究了铜离子与DMcT/PAn复合材料之间的氧化还原反应机理,结果表明Cu（Ⅱ）盐能改善DMcT/PAn复合材料的均匀性,增加其导电性,充分发挥PAn的催化作用,提高活性物质的利用率;减少DMcT及其配合物在电解液中的溶解,稳定DMcT的氧化还原过程;使复合材料中溶剂尽可能多的除去,相对地增加了复合材料的比容量.     

基于电压时间换相面积预测的换相失败抑制方法

提前触发控制是降低高压直流输电系统换相失败发生概率的一种重要方法,精准的提前触发是该方法抑制换相失败的关键.根据换相电压时间面积理论,提出了一种基于换相电压时间面积预测的换相失败抑制方法.该方法不仅计及了故障后直流电流的变化,还通过换相面积的测量间接计及了故障后换相角以及等效换相电抗的变化.同时,该方法具有较清晰的物理...     

PTMA/LiMn2O4复合正极材料及电化学性能

介绍了用于锂离子电池的一种有机-无机复合正极材料PTMA/LiMn2O4的制备方法,报导了PTMA/LiMn2O4复合材料的循环伏安特性、交流阻抗、循环性能以及高倍率充放电特性。试验结果表明：PTMA/LiMn2O4复合正极材料具有比较优良的循环稳定性和大电流充放电性能,是一种性能优良的锂离子电池正极材料。     

新型锂盐双乙二酸硼酸锂的制备与性能

文章综述了近年来锂离子电池豹新型锂盐一双乙二酸硼酸锂（LiBOB）研究的成果。介绍了双乙二酸硼酸锂的合成方法、组成与结构、化学和电化学性能及其与结构的关系。并重点综述了LiBOB电解液的导电性研究,对负极材料、正极材料的稳定性研究,与其他锂盐在锂离子电池中混合使用的性能研究等。总结了LiBOB的优缺点,指出了其进一步的研究方向。     

基于典型波形特征与改进DBSCAN的电压暂降同源识别方法

针对电网内单次短路故障可能触发多条母线上的电能质量监测装置记录电压暂降波形,造成电压暂降录波数据冗余、电网电压暂降水平过估计的问题,提出一种基于典型波形特征与改进基于密度的有噪空间聚类(DBSCAN)的电压暂降同源识别方法。首先,提出综合倾斜因子、波形相似度和持续时间三维特征,综合刻画电压暂降同源性;同时,研究电压暂降经多级变压器的传播特性,推导出13种变压器相电压等效传递矩阵,并提出基于Bhattacharyya距离的波形相似度计算方法。其次,利用共享近邻点(SNN)改进DBSCAN,对由三维特征构成的矩阵进行同源聚类,提出基于电网节点总数和监测点总数的聚类参数计算方法,实现电压暂降同源识别。应用实测数据和IEEE 30节点系统仿真数据进行验证,结果证明了所提方法的正确性和有效性。     

基于DSP的全数字直流模糊位置伺服控制系统

本文提出一种基于数字信号处理器（DSP）的全数字直流模糊位置伺服控制系统、该系统充分利用了DSP周边接口丰富、运算速度快的特点,使所设计的系统硬件简单,并实现了采用模糊控制策略对系统进行控制。实验结果表明,系统结构紧凑,具有良好的动态和静态特性。