Nanostructured Zn-Fe2O3 thin film modified by Fe-TiO2 for photoelectrochemical generation of hydrogen

Nanostructured semiconductor thin films of Zn-Fe₂O₃ modified with underlying layer of Fe-TiO₂ have been synthesized and studied as photoelectrode in photoelectrochemical (PEC) cell for generation of hydrogen through water splitting. The Zn-Fe₂O₃ thin film photoelectrodes were designed for best performance by tailoring thickness of the Fe-TiO₂ film. A maximum photocurrent density of 748 μA/cm² at 0.95 V/SCE and solar to hydrogen conversion efficiency of 0.47% was observed for 0.89 μm thick modified photoelectrode in 1 M NaOH as electrolyte and under 1.5 AM solar simulator. To analyse the PEC results the films were characterized for various physical and semiconducting properties using XRD, SEM, EDX and UV–Visible spectrophotometer. Zn-Fe₂O₃ thin films modified with Fe-TiO₂ exhibited improved visible light absorption. A noticeable change in surface morphology of the modified Zn-Fe₂O₃ film was observed as compared to the pristine Zn-Fe₂O₃ film. Flatband potential values calculated from Mott–Schottky curves also supported the PEC response.     

Intracavernous Injection of Platelet-Rich Plasma Therapy Enhances Erectile Function and Decreases the Mortality Rate in Streptozotocin-Induced Diabetic Rats

Erectile dysfunction (ED) is an agonizing complication of diabetes mellitus (DM) and it is challenging to treat ED in DM patients. Platelet-rich plasma (PRP) is a unique therapeutic strategy comprising intrinsic growth factors. An attempt was made to explore the potentiality of the PRP treatment in DM-induced ED rats in various groups (control, DM-non-ED, DM-ED, and DM-ED treated with PRP). Streptozotocin (STZ) was used to induce DM in rats. The blood glucose levels of the DM rats were maintained at >300 mg/dl. In the 18-week experiment, survival rate, body weight, intracavernous pressure (ICP) variations, and arterial blood pressure were analyzed. The tissue restoration results were validated by histological, immunofluorescence, and transmission electron microscopic analysis. PRP treatment of DM-ED rats significantly increased all parameters of erectile function compared to pre-treatment of PRP and DM-ED treated with vehicle. The histological results revealed that PRP treatment substantially enhanced the regeneration of myelinated nerves and decreased the atrophy of corporal smooth muscle. Notably, the PRP treatment immensely enhanced the survival rate in post-surgery DM-ED rats. These results indicated certain benefits of PRP treatment in delaying damage and preventing post-surgery complications in DM patients. Hence, PRP treatment is a novel multifactorial strategy for DM-ED patients.     

Simplified Impedance Model for Adhesively Bonded Piezo-Impedance Transducers

The electromechanical impedance technique employs surface-bonded lead zirconate titanate piezoelectric ceramic patches as impedance transducers for structural health monitoring and nondestructive evaluation. The patches are bonded to the monitored structures using finitely thick adhesive bond layer, which introduces shear lag effect, thus invariably influencing the electromechanical admittance signatures. This paper presents a new simplified impedance model to incorporate shear lag effect into electromechanical admittance formulations, both one-dimensional and two-dimensional. This provides a closed-form analytical solution of the inverse problem, i.e. to derive the true structural impedance from the measured conductance and susceptance signatures, thus an improvement over the existing models. The influence of various parameters (associated with the bond layer) on admittance signatures is investigated using the proposed model and the results compared with existing models. The results show that the new model, which is far simpler than the existing models, models the shear lag phenomenon reasonably well besides providing direct solution of a complex inverse problem.     

Study of bimetallic corrosion related to Cu interconnects using micropattern corrosion screening method and Tafel plots

On-chip microscopic corrosion, originating from contact of dissimilar metals, can cause serious reliability issues for integrated circuits and microelectromechanical devices. A new micropattern corrosion screening method combined with Tafel plots were employed to study Cu bimetallic corrosion in acid and base solutions relevant to the chemical–mechanical planarization process. The results demonstrated that Cu corrosion on Ru is much more severe compared to Cu corrosion on Ta substrates. Tafel plots confirm the nobility trend of Ru > Cu > Ta. The micropattern corrosion study shows the Cu bimetallic corrosion depends on specific chemicals and bimetallic contacts. Strong complexing ligands like NH₃ combined with energetically favorable Cu/Ru bimetallic contact promote faster Cu corrosion under alkaline conditions (9 ≤ pH ≤ 11.4). Micropattern corrosion screening was shown to be useful in identifying the metastable surface layer during Cu corrosion and determining the optimal benzotriazole concentration for Cu corrosion inhibition.     

Bio-butanol vs. bio-ethanol: A technical and economic assessment for corn and switchgrass fermented by yeast or Clostridium acetobutylicum

Fermentation-derived butanol is a possible alternative to ethanol as a fungible biomass-based liquid transportation fuel. We compare the fermentation-based production of n-butanol vs. ethanol from corn or switchgrass through the liquid fuel yield in terms of the lower heating value (LHV). Industrial scale data on fermentation to n-butanol (ABE fermentation) or ethanol (yeast) establishes a baseline at this time, and puts recent advances in fermentation to butanol in perspective. A dynamic simulation demonstrates the technical, economic and policy implications.The energy yield of n-butanol is about half that of ethanol from corn or switchgrass using current ABE technology. This is a serious disadvantage for n-butanol since feedstock costs are a significant portion of the fuel price. Low yield increases n-butanol's life-cycle greenhouse gas emission for the same amount of LHV compared to ethanol. A given fermenter volume can produce only about one quarter of the LHV as n-butanol per unit time compared to ethanol. This increases capital costs. The sometimes touted advantage of n-butanol being more compatible with existing pipelines is, according to our techno-economic simulations insufficient to alter the conclusion because of the capital costs to connect plants via pipeline.     

SIVA: A System for Coverage-Directed State Space Search

We introduce SImulation Verification with Augmentation (SIVA), a tool for coverage-directed state space search on digital hardware designs. SIVA tightly integrates simulation with symbolic techniques for efficient state space search. Specifically, the core algorithm uses a combination of ATPG and BDDs to generate directed input vectors, i.e., inputs which cover behavior not excited by simulation. We also present approaches to automatically generate lighthouses that guide the search towards hard-to-reach coverage goals. Experiments demonstrate that our approach is capable of achieving significantly greater coverage than either simulation or symbolic techniques in isolation.     

Photocatalytic degradation of dyes and organic contaminants in water using nanocrystalline anatase and rutile TiO2

Nanocrystalline TiO₂ was synthesized by controlled hydrolysis of titanium tetraisopropoxide. The anatase phase was converted to rutile phase by thermal treatment at 1023 K for 11 h. The catalysts were characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), Fourier-transform infrared absorption spectrophotometry (FT-IR) and N₂ adsorption (BET) at 77 K. This study compare the photocatalytic activity of the anatase and rutile phases of nanocrystalline TiO₂ for the degradation of acetophenone, nitrobenzene, methylene blue and malachite green present in aqueous solutions. The initial rate of degradation was calculated to compare the photocatalytic activity of anatase and rutile nanocrystalline TiO₂ for the degradation of different substances under ultraviolet light irradiation. The higher photocatalytic activity was obtained in anatase phase TiO₂ for the degradation of all substances as compared with rutile phase. It is concluded that the higher photocatalytic activity in anatase TiO₂ is due to parameters like band-gap, number of hydroxyl groups, surface area and porosity of the catalyst.     

Evaluation of satellite-altimetry-derived river stage variation for the braided Brahmaputra River

In this study, river stage variation derived from satellite altimetry was used to assess the water level, monthly discharge, and annual water yield at six virtual gauging stations at the braided reaches of the Brahmaputra River. The braided reaches of the river dynamically change their planform, thalweg line, and aggradation or degradation period. Stage records derived from the Envisat satellite of the European Space Agency and Topex/Poseidon of NASA/CNES were used for the period 2002–2010. Spatial interpolation and datum correction were applied on altimetry-derived river stage records before analysis. A correlation and error analysis between the in situ and satellite-altimetry-derived stages was carried out for these stations for both monsoon and non-monsoon seasons. Yearly optical satellite images were used for qualitative assessment of temporal variations in aggradation/degradation phases at the gauging stations. Using the pseudo-rating curve, discharges at two virtual gauging stations were estimated. The results show that the altimetry-estimated discharges are of good agreement with observed discharge for the monsoon months (June–September) as compared with the non-monsoon months (October–May). In order to assess the annual water yield variability, yearly variation in annual water yield from the altimetry data was also estimated and compared to that observed. The estimated annual water yields were 90% accurate. Similarly, the long-term averaged monthly discharge series estimated from satellite altimetry closely follows the temporal trend of that of the observed series.     

Contribution of organomodified clay on hybrid microstructures and properties of epoxidized natural rubber‐based nanocomposites

Influence of organic modifying agent of clay on dispersion, distribution, hybrid microstructure formation, and associated performance properties of epoxidized natural rubber‐based composites was evaluated. Binary and ternary composites of carbon black (CB) and two organomodified layered silicates (i.e., nanomer I30E and Cloisite 30B) were prepared and characterized based on small angle X‐ray scattering, transmission electron microscopy, hydrodynamic swelling, tensile measurement, and dynamic mechanical analyses. Greater extent of exfoliation and “nanounit” formation was noted in ternary composites containing nanomer I30E, which was reflected in higher interfacial roughness (d_s = 2.82) and lower radius of gyration (R_g = 205 Å). Morphological observations suggested higher nanomer I30E–CB interactions than that of Cloisite 30B–CB. The interplatelet distance in Cloisite 30B (d = 1.83 nm) stacks was lower than that of nanomer I30E (d = 2.26 nm). These two factors jointly contributed in higher breakdown of nanomer I30E stacks by CB than that of Cloisite 30B stacks. Greater exfoliation and nanounit formation in I30E–CB‐filled nanocomposite was also reflected in increased degree of crosslinking (n = 20 × 10^?5%), tensile modulus/strength, half height width of damping peak (20.3°C), and filler effectiveness (C = 0.33). POLYM. ENG. SCI., 2013. © 2012 Society of Plastics Engineers     

Effect of Solubles on Disintegration of Distiller's Spent Grain Compacts During Superheated Steam Drying

Drying of densified spent grain in superheated steam (SS) may cause breakage and disintegration of the product in the initial stage of SS drying. The present work investigated the effect of solubles (0, 10, 30, 50, and 70% solubles) on the percentage change in length, diameter, volume; hardness; and the asymptotic modulus (E_A) of the cylindrical compacts during SS drying. An increase in dimensions along with a decrease in hardness and E_A of the compact was observed immediately after exposing it to SS. We observed a 47% increase in length and 12% increase in diameter for compacts having 0% solubles during the first five seconds of SS drying; however, when the soluble content increased to 70%, the percentage increase in length and diameter became 12 and 2%, respectively. Also, with an increase in the amount of solubles in the compact, a considerable increase in the hardness and E_A of the compact was observed. The study also aimed to find suitable explanatory variables for predicting the hardness and E_A of the compact using a stepwise forward regression method.