重稀土2-噻吩甲酸配合物的合成及Tb3+的发光

合成了4种稀土与2-噻吩甲酸(L)配合物。通过元素分析、稀土配合滴定及摩尔电导确定其化学组成为REL3.2H2O(RE=Gd,Tb,Dy,Er),并对配合物进行了红外光谱、荧光激发和发射光谱测定。红外光谱测定表明,配体通过羧基以螯合双齿的方式与稀土离子(Ⅲ)配位成键。荧光光谱数据表明,铽配合物具有良好的荧光性能。     

交联剂和助交联剂对ABS/PP/CaCO3反应性共混的影响

为提高ABS/PP/CaCO3复合材料相容性,采用转矩流变仪观察了ABS/PP/CaCO3三元复合物反应性共混后的扭矩,考察了不同的助交联剂蓖麻油(CO)、异氰脲酸三烯丙酯(TAIC)、松香酯(JS-1)、二甲基丙烯酸乙二醇酯(GD)以及交联剂过氧化二异丙苯(DCP)的用量对共混物的影响.研究结果表明,在交联剂DCP为0.2%(wt)时,助交联剂GD比CO、TAIC、JS-1对ABS/PP/CaCO3体系有更好反应共混效果;反应共混超过2.5 min后,随DCP量增加,复合材料将发生严重的降解.用毛细管流变仪研究了复合材料的流变特性,结果显示用DCP/GD交联体系反应共混的ABS/PP/CaCO3复合材料的剪切黏度,随温度、剪切速率的增加而下降,比较同一剪切速率下的非牛顿指数,说明其流动性能优于纯ABS.力学性能测试数据说明,用DCP/GD交联的ABS/PP/CaCO3复合材料比未交联的有较高的弯曲强度和模量.电镜观察揭示了用DCP/GD动态交联的ABS/PP/CaCO3复合材料有更好的界面相容.     

基于非线性干扰观测器的高超声速飞行器滑模反演控制

针对高超声速飞行器非线性、强耦合和参数不确定弹性体模型,提出了一种基于非线性干扰观测器的滑模反演控制方法.将飞行器曲线拟合模型分解为速度子系统和高度相关子系统并表示为严格反馈形式,分别采用滑模和反演方法设计实际控制量与虚拟控制量.采用1阶低通滤波器获取虚拟控制量的导数,解决了传统反演控制方法"微分项膨胀"问题.基于改进滑模微分器设计了一种新型非线性干扰观测器,以此对模型不确定项进行估计和补偿.仿真结果表明,该控制器对模型不确定性和气动弹性影响具有鲁棒性,且实现了对速度和高度参考输入的稳定跟踪.     

粉磨细度对水泥与外加剂相容性的影响

在化验室小磨上磨制的不同比表面积的水泥中,掺入不同掺量的萘系高效减水剂和氨基系高效减水剂,测定各试样的水泥净浆流动度,研究粉磨细度对水泥与外加剂相容性的影响。结果表明:当水泥比表面积小于400m2/kg,随比表面积增加,初始流动度及30min、60min经时流动度逐渐降低,水泥与高效减水剂适应性变差,但变化不是十分显著,可以通过增大高效减水剂掺量进行改善;当比表面积大于400m2/kg,随比表面积增加,初始流动度及30min、60min经时流动度均十分明显降低,水泥与高效减水剂适应性很差。因此,提出不宜通过过分粉磨来生产高等级水泥。     

交联助剂对过氧化物硫化天然胶乳性能的影响

选用不同的过氧化物硫化体系制得硫化天然胶,在此基础上探讨了不同种类及用量的交联助剂和热处理温度对硫化效果的影响.结果表明:选用BPO过氧化物硫化天然胶时,添加3份DVB交联助剂的硫化天然胶,基本达到了硫黄硫化的基本力学性能;选用过氧化二叔丁基-硫酸亚铁络合物的氧化还原体系,添加3份的SJ-1交联助剂,在80℃以上时,可使硫化天然胶性能进一步提高,拉伸强度相比BPO过氧化物硫化的天然胶增加了近一倍.平衡溶胀试验的结果表明,氧化还原体系制得的硫化胶有最小的平衡溶胀增量和最大的凝胶含量.     

HPF加固梁受弯性能影响参数试验

为研究原梁纵向配筋率和混凝土强度等原梁参数对其高性能复合砂浆钢筋网(HPF)加固梁受弯受弯承载力和变形能力影响,设计了7根HPF加固梁足尺受弯试验.试验结果表明高性能复合砂浆钢筋网加固RC足尺梁是一种有效的加固方法,能够显著地提高RC足尺梁的抗弯承载力、截面刚度以及抗裂性能;原梁参数对其加固梁的受弯性能改善效应影响显著.     

下一代电信网关键协议的安全性研究

下一代电信网中信令控制协议的安全性是影响网络安全的重要因素之一。文章从协议自身的安全问题、协议实现的安全问题2个方面,较全面地分析了此类协议的安全性研究方法,介绍了安全性测试方法,最后给了国内相关标准的进展情况。     

Intermittent Clutter Removal Approach for Wind Profiler Data Based on Fractional Fourier Transform

Through the analysis of the target characteristics and according to the intermittent clutter bursting and short duration characteristics, a new method for the clutter recognition based on the fractional Fourier transform (FRFT) is proposed. This method is predicated on the fact that the FRFT perfectly localizes a chirp signal as an impulse when the angle parameter of the transform matches the chirp rate of the chirp signal. The method involves detecting the presence of the intermittent clutter and correctly estimating its orientation in the time-frequency plane, removing the intermittent clutter in the fractional domain, and completing wind estimation by the power spectrum. By testing the artificial WPR-like signal and data measured from the field, we verify that the FRFT-based method is very effective.     

Intermittent Clutter Removal Approac for wind Profiler Data Based on Fractional Fourier Transform

Through the analysis of the target characteristics and according to the intermittent clutter bursting and short duration characteristics, a new method for the clutter recognition based on the fractional Fourier transform (FRFT) is proposed. This method is predicated on the fact that the FRFT perfectly localizes a chirp signal as an impulse when the angle parameter of the transform matches the chirp rate of the chirp signal. The method involves detecting the presence of the intermittent clutter and correctly estimating its orientation in the time-frequency plane, removing the intermittent clutter in the fractional domain, and completing wind estimation by the power spectrum. By testing the artificial WPR-like signal and data measured from the field, we verify that the FRFT-based method is very effective.     

Novel Channel Estimation Method Based on Decision-Directed in OFDM

Based on the analysis of decision-directed (DD) channel estimation by using training symbols,a novel DD channel estimation method is proposed for orthogonal frequency division multiplexing (OFDM) system.The proposed algorithm takes the impact of decision error into account,and calculates the impact to next symbol duration channel state information.Analysis shows that the error propagation can be effectively restrained and the channel variation is tracked well.Simulation results demonstrate that both the signal error rate (SER) and the normalized mean square error (NMSE) performance of the proposed method are better than the traditional DD (DD+ IS) and the maximum likelihood estimate (DD+ MLE) method.