基于智能软开关优化配置的配电网柔性互联策略

目前的储能建模研究大都关注其电磁仿真模型,难以用于大规模储能接入对系统稳定性的影响研究。该文提出了集中式储能电站的机电暂态建模方法,在电力系统分析综合程序PSASP的用户自定义（UD）模块中搭建了考虑限幅和附加功率控制的储能机电暂态仿真模型。在此基础上,提出了储能电站的自适应附加功率控制方法,并搭建了相应控制模块。不同工况下的仿真结果证明,所提模型能够准确模拟储能对电力系统的暂态支撑,所提自适应附加功率控制方案进一步提升了储能电站对系统的暂态支撑能力。     

基于激光诱导击穿光谱的煤样典型特性研究北大核心CSCD

为了准确检测煤样的各种元素含量、灰分和发热量等工业指标,提出利用激光诱导击穿光谱技术进行煤样的光谱强度信息采集。激光诱导击穿光谱技术作为一种新型的元素分析技术,通过高能脉冲激光聚集在样品表面,分析等离子体释放出的元素谱线信息,得出样品元素含量和组成。而光谱信息采样的延迟时间是光谱检测中一个非常重要的参数,为了研究延迟时间对煤样激光诱导击穿光谱信号强弱的影响,提出了通过连续背景强度变化和相对标准偏差计算来判定测量煤样的最佳延迟时间。本研究选取山东济南众标科技有限公司的三种标准煤样作为研究对象,实验测试使用Nd∶YAG脉冲激光器,波长为1064nm。对于煤质的检测,采用AvaSpec Dual型光纤光谱仪,光谱探测波长范围为两通道195~467nm和615~973nm。延迟时间为247~252μs对三种标准煤样ZBM100、ZBM101、ZBM104的光谱信息进行特征分析,通过光谱信号强度和连续背景强度随延迟时间变化的关系,判断出247~252μs范围内的最佳延迟时间。随着延迟时间的增加,连续背景强度快速衰减,在250μs时,连续背景强度和光谱信号强度分别衰减到延迟时间为247μs时的30和50。其次通过在不同延迟时间下相对标准偏差的计算,判断出标准煤样样本中Al、Si、Fe三种元素最佳延迟时间为247μs、248μs、249μs所对应的标准偏差达到最小值,得到因选用标准煤样对象不同其相对标准偏差对应元素的最佳延迟时间也会有所差异。研究结果表明,三种标准煤样ZBM100、ZBM101、ZBM104的光谱强度在247~252μs的最佳采样延迟时间为250μs。此实验研究结果,为激光诱导击穿光谱技术探测和分析煤质检测的最佳延迟时间提供了依据。     

不同土壤湿度和雨强下径流曲线模型的改进

前期土壤湿度条件和降雨强度是影响径流曲线（SCS-CN）模型径流量预测精度的重要因素。分析不同流域下二者对SCS-CN模型性能的影响,对提高模型预测精度至关重要。基于5个半干旱半湿润和湿润流域的降雨径流资料,利用偏相关分析和K-均值聚类改进SCS-CN模型。结果表明：在重新划分前期土壤湿度条件区间后,模型预测能力大幅度提升,有效降低模型平均偏差,纳什效率系数平均提高42.8%。基于最大10 min雨强对SCS-CN模型改进后,纳什效率系数得到一定提高,且半干旱半湿润流域的提升幅度略大于湿润流域。改进的模型在研究流域都取得较好的效果,平均偏差均低于7 mm;除呈村流域非汛期外纳什效率系数均达到0.93,平均提升89%;均方根误差平均降低29.2 mm。     

基于XGBOOST-PSO提高受端电网电压暂态稳定的发电机无功优化方法

考虑发电机稳态输出无功对其支撑暂态电压恢复稳定能力的影响,基于机器学习研究优化发电机稳态输出无功提高电压对故障扰动保持暂态稳定能力的预防控制方法。该方法采用加权多二元表暂态稳定裕度指标量化母线暂态电压对不同预想故障扰动的综合稳定裕度,并基于指标排序确定稳定裕度薄弱母线。同时基于发电机无功调节对预想故障下各薄弱母线电压暂态稳定裕度综合作用灵敏度排序,选择作用灵敏发电机。在利用XGBoost建立根据系统稳态特征向量预测薄弱母线暂态电压稳定的分类模型基础上,以系统对预想故障扰动保持暂态电压稳定为约束、以减小发电机稳态无功调节对网损产生影响为目标,基于潮流计算寻优灵敏发电机稳态输出无功,以提高薄弱母线的暂态电压稳定性。最后采用雅湖直流接入江西电网的PSASP计算模型验证了所提方法的有效性。     

Nanocellulose-Carboxymethylcellulose Electrolyte for Stable,High-Rate Zinc-Ion Batteries

Aqueous Zn ion batteries (ZIBs) are one of the most promising battery chemistries for grid-scale renewable energy storage. However, their application is limited by issues such as Zn dendrite formation and undesirable side reactions that can occur in the presence of excess free water molecules and ions. In this study, a nanocellulose-carboxymethylcellulose (CMC) hydrogel electrolyte is demonstrated that features stable cycling performance and high Zn²⁺ conductivity (26 mS cm⁻¹), which is attributed to the material's strong mechanical strength (≈70 MPa) and water-bonding ability. With this electrolyte, the Zn-metal anode shows exceptional cycling stability at an ultra-high rate, with the ability to sustain a current density as high as 80 mA cm⁻² for more than 3500 cycles and a cumulative capacity of 17.6 Ah cm⁻² (40 mA cm⁻²). Additionally, side reactions, such as hydrogen evolution and surface passivation, are substantially reduced due to the strong water-bonding capacity of the CMC. Full Zn||MnO₂ batteries fabricated with this electrolyte demonstrate excellent high-rate performance and long-term cycling stability (>500 cycles at 8C). These results suggest the cellulose-CMC electrolyte as a promising low-cost, easy-to-fabricate, and sustainable aqueous-based electrolyte for ZIBs with excellent electrochemical performance that can help pave the way toward grid-scale energy storage for renewable energy sources.     

Polyether-b-Amide Based Solid Electrolytes with Well-Adhered Interface and Fast Kinetics for Ultralow Temperature Solid-State Lithium Metal Batteries

Solid-state lithium metal batteries (SSLMBs) are highly desirable for energy storage because of the urgent need for higher energy density and safer batteries. However, it remains a critical challenge for stable cycling of SSLMBs at low temperature. Here, a highly viscoelastic polyether-b-amide (PEO-b-PA) based composite solid-state electrolyte is proposed through a one-pot melt processing without solvent to address this key process. By adjusting the molar ratio of PEO-b-PA to lithium bis(trifluoromethanesulphonyl)imide (ethylene oxide:Li = 6:1) and adding 20 wt.% succinonitrile, fast Li⁺ transport channel is conducted within the homogeneous polymer electrolyte, which enables its application at ultra-low temperature (−20 to 25 °C). The composite solid-state electrolyte utilizes dynamic hydrogen-bonding domains and ion-conducting domains to achieve a low interfacial charge transfer resistance (<600 Ω) at −20 °C and high ionic conductivity (25 °C, 3.7 × 10⁻⁴ S cm⁻¹). As a result, the LiFePO₄|Li battery based on composite electrolyte exhibits outstanding electrochemical performance with 81.5% capacity retention after 1200 cycles at −20 °C and high discharge specific capacities of 141.1 mAh g⁻¹ with high loading (16.1 mg cm⁻²) at 25 °C. Moreover, the solid-state SNCM811|Li cell achieves excellent safety performance under nail penetration test, showing great promise for practical application.     

Fine-Tuning Alkyl Chains on Quinoxaline Nonfullerene Acceptors Enables High-Efficiency Ternary Organic Solar Cells with Optimizing Molecular Stacking and Reducing Energy Loss

Material design of guest acceptor is always a big challenge for improving the efficiency of ternary organic solar cells (OSCs). Here, a pair of isomeric nonfullerene acceptors based on quinoxaline core, Qx–p-C₇H₈O and Qx–m-C₇H₈O, is designed and synthesized. By moving the alkoxy chain attached on side phenyl from meta-position to para-position, both π–π stacking distance and crystallinity are enhanced simultaneously. They obtain the uplifted lowest unoccupied molecular orbital level. Compared to Qx–m-C₇H₈O, Qx–p-C₇H₈O exhibits wider absorption spectrum and higher extinction coefficient. Using D18-Cl:N3 as host materials, the addition of guest acceptor Qx–p-C₇H₈O significantly improves the power conversion efficiency (PCE) from 17.61% to 18.49% because of higher open-circuit voltage (0.875 V) and short-circuit current density (27.85 mA cm⁻²). This can be attributed to the faster exciton dissociation, more balanced carrier mobility, fine fiber morphology, and lower energy loss in the ternary devices. However, Qx–m-C₇H₈O-based ternary device achieves relatively low PCE of 17.17% because this device shows extremely low electron mobility. The results indicate that molecular stacking, film morphology, etc., can be effectively modulated by fine-tuning the side chains of guest materials, which may be an effective design rule for further improving the PCE of OSCs.     

基于黎曼流形的多视角谱聚类算法

现有的多视角谱聚类算法大多只线性结合了各视角的基拉普拉斯矩阵,未考虑不同视角数据的差异性对最优拉普拉斯矩阵的影响,存在聚类性能受限的问题。提出一种基于黎曼几何均值与高阶拉普拉斯矩阵的谱聚类算法(RMMSC),挖掘多视角数据中的高阶连接信息与流形信息,提高最优拉普拉斯矩阵对各视角的信息利用率。按一定的权重线性结合数据单一视角的各阶拉普拉斯矩阵,得到每个视角的基拉普拉斯矩阵,通过低阶与高阶连接信息的结合使用,充分体现多视角数据集的全局结构。在此基础上,计算各视角基拉普拉斯矩阵的黎曼几何均值,将其作为最优拉普拉斯矩阵输入谱聚类算法,得到聚类结果。相比于传统矩阵算数均值的计算,基于黎曼流形的黎曼几何均值能够更好地恢复互补层数据的流形信息。实验结果表明,RMMSC在多组标准数据集上聚类效果优于ONMSC、MLAN、AMGL等算法。其中,在Flower17数据集上,精确度较基准算法ONMSC提高了2.14%,纯度提高了1.7%,且收敛性较好。     

Tailoring of Photoluminescence Properties in All-Vacuum Deposited Perovskite via Ruddlesden–Popper Faults

Ruddlesden–Popper (RP) faults are well known in oxide perovskites, and are also observed in promising metal halide perovskites. However, the effect of RP faults on optical properties of perovskite has not been systematically investigated. In this study, it is found that RP faults are common planar faults in all-vacuum deposited CsPbBr₃-based perovskite polycrystal thin films, and the density of RP planar faults can be greatly increased by non-stoichiometric composition (Cs-rich) as well as reduced dimensionality (quasi-2D) strategies. The photoluminescence (PL) measurement reveals monotonically increasing peak intensities with higher densities of RP planar faults from Cs-rich, quasi-2D to Cs-rich & quasi-2D samples. The corresponding atomic-scale differential phase contrast maps indicate strongly confined charges within the RP planar fault network, which explains well the relationship between PL enhancement and the density of RP planar faults, and offers an alternative pathway for tailoring the optoelectronic properties of perovskite.