东海盆地西南部地质特征与油气分布探讨

本文根据近3×10~4km地震和13口探井及其它地球物理、地质等方面资料,综合分析认为:东海盆地西南部与盆地其它部分在发育演化、构造运动、沉积环境等方面差异甚大。 盆地西南部(杭州湾—冲绳岛断裂以南地区)发育演化经历了断陷—坳陷—隆起—铺盖四个阶段。始新世末期的隆起在研究区演化史上有15～20Ma的沉积间断、剥蚀。这段历程,盆地其它部分未曾经历。其次是区内始新世末期抬升运动,致使始新统及以下老地层受剥蚀,仅始新统最大剥蚀量达1000m,这是盆地内绝无仅有的。第三是第三纪以海相沉积环境为主,特别在始新世,为海侵高潮,海城宽阔达8000km~2,这时盆地东北部正接受陆相沉积。研究区中部(北东向)可能存在超压泥岩及多套生油岩系,应为有利生油气区。研究区可能是盆地最有油气远景地区之一。     

用RAFA方法定量解析芳烃混合物的EEM

本文介绍了降秩因子分析(RAFA)方法,它是从一个多组分混合物中直接定量计算其中某一组分,而不必知道其它组分的物种及含量的一种定量分析的数学方法。它适用于双线性的数据。本实验首先将荧光分光光度计与外接计算机相连,以获得样品的激发-发射矩阵(EEM),再用RAFA方法对蒽、萘、菲、芘、芴、(艹屈)六种标样的一至五组分的混合物进行定量分析,获得满意的结果。     

A subunit interaction in chloroplast ATP synthase determined by genetic complementation between chloroplast and bacterial ATP synthase genes

F1F0-ATP synthases utilize protein conformational changes induced by a transmembrane proton gradient to synthesize ATP. The allosteric cooperativity of these multisubunit enzymes presumably requires numerous protein-protein interactions within the enzyme complex. To correlate known in vitro changes in subunit structure with in vivo allosteric interactions, we introduced the beta subunit of spinach chloroplast coupling factor 1 ATP into a bacterial F1 ATP synthase. A cloned atpB gene, encoding the complete chloroplast beta subunit, complemented a chromosomal deletion of the cognate uncD gene in Escherichia coli and was incorporated into a functional hybrid F1 ATP synthase. The cysteine residue at position 63 in chloroplast beta is known to be located at the interface between alpha and beta subunits and to be conformationally coupled, in vitro, to the nucleotide binding site > 40 A away. Enlarging the side chain of chloroplast coupling factor 1 beta residue 63 from Cys to Trp blocked ATP synthesis in vivo without significantly impairing ATPase activity or ADP binding in vitro. The in vivo coupling of nucleotide binding at catalytic sites to transmembrane proton movement may thus involve an interaction, via conformational changes, between the amino-terminal domains of the alpha and beta subunits.     

厚度控制技术在中厚板轧制生产中的应用

本文探讨了影响中厚板厚度波动的因素，结合安钢中板厂2800mm轧机按合同轧制一批交货重量不大于理论重量船板的生产实践，总结了实际生产中实现高精度厚度控制的有效方法。     

一种可切削玻璃陶瓷的压痕断裂特性

将断裂韧性测试的压痕方法与压痕弯曲方法相结合，独立地分离出了压痕残余应力因子ｘ，使其成为可测参量，并建立了压痕一压痕弯曲的断裂韧性测试方法．将这种方法应用于一种可切削玻璃陶瓷的测试，获得的Ｋ１ｃ值为Ｋ１ｃ＝２．０３ＭＰａ·ｍ１／２，与单边切口法（ＳＥＮＢ）获得的Ｋ１ｃ值有较好的一致性．测得的残余应力因子Ｘ＝０．０９３，符合Ａｎｓｔｉｓ经验公式的预测．     

空心微珠改性硬质聚氯乙烯复合材料的应用研究

经过改性的超细空心微珠可以作为填料加入到硬质聚氯乙烯（PVC－U）树脂中，同时改善PVC树脂的流变性、冲击性能和刚性等性能。研究结果表明，超细空心微珠加入到硬质PVC管材中，可以明显改善PVC硬管的加工流动性能，显著缩短塑化时间，降低最大扭矩。而超细空民微珠加入到硬质PVC板材时，可以提高PVC硬板的冲击性能，减小制品的收缩率，赋予PVC硬板优异的耐腐蚀性能，且产品的各项性能均符合PVC板材国家标准GB／T4454－96。     

Lipase‐catalyzed dynamic kinetic resolution of (R,S)‐fenoprofen thioester in isooctane

A lipase‐catalyzed enantioselective hydrolysis process under in situ racemization of the remaining (R)‐thioetser substrate with trioctylamine as the catalyst was developed for the production of (S)‐fenoprofen from (R,S)‐fenoprofen 2,2,2‐trifluoroethyl thioester in isooctane. Detailed investigations of trioctylamine concentration on the enzyme activation and the kinetic behavior of the thioester in racemization and enzymatic reactions were conducted, in which good agreement between the experimental data and theoretical results was observed. © 2002 Society of Chemical Industry     

Rheology in Processing of in Situ Composites of Polypropylene and Low Melting Poing Metals

The low melting point metallic tin powder or alloy of tin and lead was blended with polypropy-lene. A kind of in situ composite has been prepared. The variations of torque were studied when the composites were mixed in Haake torque rheogeniometer. By way of capillary extrusion, effects upon rheology of the in situ com-posites of the low melting point metals (LMPM) and coupling agent for their different variety and content, were investigated. From flow curves, the results indicate that in situ composites mixed with the LMPM are a kind of pseudoplastic fluid. If the LMPM were melted, the higher the content of the LMPM , the lower apparent viscosity of composites. Meanwhile, when the coupling agent is added into composites, the viscosity of composite will go up first and drop then. This shows that the LMPM have a promoter flow action on the polypropylene.