Transformation of sputtered calcium copper titanate thin film into nanorods by sequential annealing

Rapid synthesis of long calcium copper titanate (CCTO) nanorods was carried out by sequential annealing. CCTO thin films have been deposited on p-Si substrate by RF sputtering technique and afterwards, the samples were thermally treated using a preheated furnace by varying the annealing temperature from 850 °C to 1100 °C. CCTO nanorods of 12 µm lengths and 400–600 nm diameters were synthesized at 1100 °C. Based on the FESEM observations, a plausible growth mechanism has been proposed to explain the formation of nanorods. The (220) XRD peak of the CCTO film became prominent for the annealing temperature of 950 °C. The presence of nanoscale crystals in amorphous matrix has been observed by HRTEM studies. The elemental mapping of CCTO nanorod has shown a spatial variation of elements throughout the nanorod. The oxide and interface charge density was found to be increased with the rise in annealing temperature.     

Control of dynamic overvoltages due to load rejection by static shunt compensation

A digital computer method used to evaluate the performance of a static shunt compensator as a device for controlling dynamic overvoltages caused by load rejection is presented. A typical system of a generating station connected to a load centre through an EHV transmission line with a static compensator at the load end is considered, and the envelopes of dynamic overvoltages following load rejection are evaluated. Detailed mathematical models incorporating the dynamics of a synchronous machine, transmission network and static shunt compensator are employed in the analysis. The static shunt compensator is shown to be an effective tool for controlling dynamic overvoltages. The application of this analysis for choosing an economic voltage rating of the surge arrestor is highlighted.     

Digit pipelined arithmetic on fine-grain array processors

In this paper, we present a novel scheme for performing fixed-point arithmetic efficiently on fine-grain, massively parallel, programmable architectures including both custom and FPGA-based systems. We achieve anO(n) speedup, wheren is the operand precision, over the bit-serial methods of existing fine-grain systems such as the DAP, the MPP and the CM2, within the constraints of regular, near neighbor communication and only a small amount of on-chip memory. This is possible by means of digit pipelined algorithms which avoid broadcast and which operate in a fully systolic manner by pipelining at the digit level. A base 4, signed-digit, fully redundant number system and on-line techniques are used to limit carry propagation and minimize communication costs. p ]Although our algorithms are digit-serial, we are able to match the performance of the bit-parallel methods, while retaining low communication complexity. Reconfigurable hardware systems built using field programmable gate arrays (FPGA's) can share in the speed benefits of these algorithms. By using the organization of logic blocks suggested in this paper, problems of placement and routing that exist in such systems can be avoided. Since the algorithms are amenable to pipelining, very high throughput can be obtained.     

Biobased polymeric flocculants for industrial effluent treatment

Water is a scare commodity now. Recycling of municipal wastewater, industrial and mineral processing effluents require treatment with the inorganic or organic flocculants. Inorganic flocculants are used in large quantities, leave large amount of sludge and are very much affected by pH changes. Other polymeric flocculants are used in a very minute quantity, form large cohesive floc and are inert to pH changes. Both natural and synthetic polymers are used as flocculants. Natural polymers are biodegradable and are effective at very large dosages but are very shear stable. The synthetic polymers are highly effective flocculants at very small dosages and have high tailorability, but have poor shear stability. In the authors laboratory, a new class of flocculants has been developed by grafting polyacrylamide branches onto polysaccharide such as guargum, hydroxypropyl guargum, starch, amylopectin and sodium alginate. These grafted polysaccharides exhibit synergistic flocculation characteristics, shear stability and controlled biodegradability. Out of all the grafted polysaccharides, amylopectin grafted polysaccharides out performs most of the commercially available flocculants. The polacrylamide branches grafted on high molecular weight branched amylopectin have larger approachability to contaminants in the industrial effluents [1, 2].     

Probabilistic neural-network-based protection of power transformer

An optimal probabilistic neural network (PNN) as a core classifier for fault detection and status indication of a power transformer has been presented. In this scheme, various operating conditions of a transformer are distinguished using signatures of the differential currents. The proposed differential protection scheme is implemented through two different structures of PNN, that is, one having one output and the other having five outputs. The developed algorithm is found to be stable against external fault, magnetising inrush, sympathetic inrush and over-excitation conditions for which relay operation is not required. For the test data of fault, it is found to operate successfully. The performance of proposed PNN and classical artificial neural network (ANN) has been compared. For evaluation of the developed algorithm, relaying signals for various operating conditions of a transformer are obtained by modelling the transformer in PSCAD/EMTDC. The algorithms are implemented using MATLAB. The results show the capability of PNN in terms of classification accuracy and speed in comparison to classical ANNs.     

Hydrodynamically and chemically induced in situ kaolin particle release from porous media an experimental study

Contaminant transport in the subsurface is decidedly influenced by the presence of colloids that are clay type particles, like kaolinite. To understand the contaminant associated colloid transport, one needs to know how release of these colloidal particles in in situ condition is affected by change in geochemical condition. In this work an attempt has been made to experimentally study the effect of different parameters like flowrate, void fraction, ionic strength, and pH on release of kaolin particle from the porous bed of kaolin–sand mixture. It was observed that there exists a critical velocity at 0.017 cm/s for the release of kaolin, and plugging of these released particles was significant in the bed. This plugging was explained by size exclusion and agglomeration of particles. It was also observed that with increase of pH and decrease of ionic strength kaolin release increases.     

Novel fire resistant matrixes for composites from cyclic poly(butylene terephthalate) oligomers

The objective of the work is to exploit the processing advantages of c-PBT oligomers, essentially required in industrial practice to produce new, robust, multifunctional hybrid copolymers of c-PBT oligomers in a single reaction-molding step, which will be suitable for the use in continuous fiber composites with excellent flame retardant properties. In this article a series of copolyesters were synthesized by using in situ polymerization of cyclic poly(butylene terepthalate) oligomers (c-PBT) and hydroxyl terminated bisphenols and hydroxylated siloxanes in the presence of a tin catalyst at a moderate temperature. The in situ copolymerization was conducted with various c-PBT/tetrabromobisphenol A (TBBPA), bisphenol A diglycidyl ether (BPADGE) and Carbinol PDMS feed ratios respectively. The copolyesters were characterized by GPC, NMR, and DSC techniques. Pyrolysis-combustion flow calorimeter (PCFC) and pyrolysis gas chromatography/mass spectrometry (PyGC/MS) studies were performed to characterize the fire retardant properties of the copolymers during combustion. POLYM. ENG. SCI., 47:1536–1543, 2007. © 2007 Society of Plastics Engineers     

Microprocessor based recognition of dot-matrix characters using a fibre-optic scanner

This paper presents a new, but simple device to recognize computer-printed dot-matrix character patterns. The device uses a fibre-optic scanner for feature extraction and is controlled by an 8-bit 8085 microprocessor. Details of design, fabrication and recognition techniques are presented. The device was used to recognize all the keyboard characters/symbol patterns of an IBM Personal Computer.     

Optimization of the PCR for detection of Staphylococcus aureus nuc gene in bovine milk

Staphylococcus aureus is an economically important and a major mastitis-causing pathogen that also poses food safety and antimicrobial resistance threats. Substances in mastitic milk inhibit the Taq DNA polymerase reaction (Taq PCR) making it of limited use for detecting S. aureus mastitis. In the study reported here, a set of oligonucleotide primers of 21 and 24 bases was used in Taq-PCR to amplify DNA from S. aureus (isolates from bovine mastitis). A specific amplicon of 270 bp was generated as predicted. Replacing Taq DNA polymerase with Thermus thermophilus (Tth) DNA polymerase alone (Tth-PCR) raised the sensitivity of S. aureus detection in milk from experimentally infected cows from 65 to 80%. Combining the use of Tth DNA polymerase and the purification of crude DNA extract using Chelex-100 before PCR raised the sensitivity to 100%. In a random survey involving 100 milk samples from cattle not infected with S. aureus, the test was 100% specific. With milk samples from clinical cases of bovine mastitis, 100% sensitivity and specificity were also observed. It is concluded that Tth-PCR on milk samples with the purification of crude DNA extracts using Chelex-100 is as sensitive as but faster than conventional milk bacteriological culture techniques and is highly specific. The modified PCR correlates with elevated somatic cell counts, detects evidence of chronic and resolving infection based on S. aureus-specific DNA and circumvents the endogenous inhibitory effects of milk.