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71.
Ultra-Stable and Sensitive Ultraviolet Photodetectors Based on Monocrystalline Perovskite Thin Films
Xu Li Chang Liu Feng Ding Zheyi Lu Peng Gao Ziwei Huang Weiqi Dang Liqiang Zhang Xiaohui Lin Shuimei Ding Bailing Li Ying Huangfu Xiaohua Shen Bo Li Xuming Zou Yuan Liu Lei Liao Yiliu Wang Xidong Duan 《Advanced functional materials》2023,33(15):2213360
The detection of ultraviolet (UV) radiation with effective performance and robust stability is essential to practical applications. Metal halide single-crystal perovskites (ABX3) are promising next-generation materials for UV detection. The device performance of all-inorganic CsPbCl3 photodetectors (PDs) is still limited by inner imperfection of crystals grown in solution. Here wafer-scale single-crystal CsPbCl3 thin films are successfully grown by vapor-phase epitaxy method, and the as-constructed PDs under UV light illumination exhibit an ultralow dark current of 7.18 pA, ultrahigh ON/OFF ratio of ≈5.22 × 105, competitive responsivity of 32.8 A W−1, external quantum efficiency of 10867% and specific detectivity of 4.22 × 1012 Jones. More importantly, they feature superb long-term stability toward moisture and oxygen within twenty-one months, good temperature tolerances at low and high temperatures. The ability of the photodetector arrays for excellent UV light imaging is further demonstrated. 相似文献
72.
73.
A Supermolecular Photosensitizer with Excellent Anticancer Performance in Photodynamic Therapy 下载免费PDF全文
Ruizheng Liang Rui Tian Lina Ma Lele Zhang Yanli Hu Jian Wang Min Wei Dan Yan David G. Evans Xue Duan 《Advanced functional materials》2014,24(21):3144-3151
A supermolecular photosensitizer with excellent anticancer behavior when used for photodynamic therapy (PDT) is fabricated by the incorporation of zinc phthalocyanines (ZnPc) into the gallery of a layered double hydroxide (LDH). The composite material possesses uniform particle size (hydrodynamic diameter ~120 nm), and the host–guest and guest–guest interactions result in a high dispersion of ZnPc in a monomeric state in the interlayer region of the LDH matrix, with high singlet oxygen production efficiency. In vitro tests performed with HepG2 cells reveal a satisfactory PDT effectiveness of the ZnPc(1.5%)/LDH composite photosensitizer: a cellular damage as high as 85.7% is achieved with a rather low dosage of ZnPc (10 μg/mL). An extraordinarily high specific efficacy is demonstrated (31.59 μg?1 (J/cm2)?1), which is over 185.5% enhancement compared with the previously reported photosensitizers under similar test conditions. Furthermore, an in vivo study of the ZnPc(1.5%)/LDH demonstrates excellent PDT performance with an ultra‐low dose (0.3 mg/kg) and a low optical fluence rate (54 J/cm2). In addition, the ZnPc/LDH photosensitizer displays high stability, good biocompatibility, and low cytotoxicity, which would guarantee its practical application. Therefore, this work provides a facile approach for design and fabrication of inorganic–organic supermolecular materials with greatly enhanced anticancer behavior. 相似文献
74.
提出了一种通过加载开口谐振环隔离板来抑制微带天线阵元之间耦合的方法。首先设计了一款工作频率在6GHz的微带天线阵,然后在其阵列单元间加载单环SRR隔离板结构。该结构在特定频段具有带阻特性,可以有效抑制天线单元间的互耦,增加天线单元间的隔离度。最后利用HFSS软件进行了仿真与优化。仿真结果证明:该结构的引入能使微带天线单元间的互耦因子降低10d B左右,体现了较好的互耦抑制特性。 相似文献
75.
结合国家重要专项测试项目对网络的评估要求,从TD-SCDMA网络评估内容与测试方法出发,详细介绍了TD-SCDMA网络所需要评估的内容,以及评估指标的定义。最后,对TD-SCDMA网络指标的量化评估进行了研究分析,结合网络和项目实际情况,选取了若干个关键网络指标,通过加权平均的方法建立网络评估模型。 相似文献
76.
通过多输入阻抗准确描述当代高速平面电源分配网络(PDN).该阻抗能够同时探查多个激励源输入及准确估量其他端口对PDN的影响.多输入阻抗是一种新颖的输入阻抗,它有两种表现形式:多输入自阻抗和多输入叠加阻抗.前者用于描述同一IC内各个电源端口之间的影响,后者用于描述不同IC之间的影响.经时频域仿真,该多输入阻抗能同时精确地... 相似文献
77.
Zhongquan Wan Chunyang Jia Yandong Duan Ximing Chen Yuan Lin Yu Shi 《Organic Electronics》2013,14(9):2132-2138
In order to increase electron-donating ability of the donor part of the organic dye, two dithiafulvenyl (DTF) units were introduced into a triphenylamine unit to form dithiafulvenyl-substituted triphenylamine hybrid donor for dye-sensitized solar cells (DSSCs) for the first time. Novel donor–acceptor organic dye WD-10 containing this hybrid donor and 2-cyanoacetic acid acceptor has been designed, synthesized and applied in DSSCs. The influence of the substituent unit DTF in the dye on the device performance has been investigated. It was found that the dye with dithiafulvenyl-substituted triphenylamine hybrid donor gave higher photocurrent, open-circuit voltage, and efficiency value. The DSSC based on organic dye WD-10 displayed a short-circuit current (Jsc) of 9.58 mA cm?2, an open-circuit voltage (Voc) of 648 mV, and a fill factor (ff) of 0.71, corresponding to an overall conversion efficiency of 4.41%. An increase in η of about 79% was obtained from simple triphenylamine dye L0 to WD-10. The different photovoltaic behaviors of the solar cells based on the organic dyes were further elucidated by the electrochemical impedance spectroscopy. This work identifies that the introduction of DTF unit into the simple triphenylamine dye could significant improve the photovoltaic performance. 相似文献
78.
Jiayang Liao Xiang Lv Xi-xi Sun Junhua Li Haomin Wang Qiang Chen Hanpeng Lu Duan Wang Jian Bi Jiagang Wu 《Advanced functional materials》2023,33(34):2303637
Although the piezo-catalysis is promising for the environmental remediation and biomedicine, the piezo-catalytic properties of various piezoelectric materials are limited by low carrier concentrations and mobility, and rapid electron-hole pair recombination, and reported regulating strategies are quite complex and difficult. Herein, a new and simple strategy, integrating phase boundary engineering and defect engineering, to boost the piezo-catalytic activity of potassium sodium niobate ((K, Na)NbO3, KNN) based materials is innovatively proposed. Tur strategy is validated by exampling 0.96(K0.48Na0.52)Nb0.955Sb0.045O3-0.04(BixNa4-3x)0.5ZrO3-0.3%Fe2O3 material having phase boundary engineering and conducted the defect engineering via the high-energy sand-grinding. A high reaction rate constant k of 92.49 × 10−3 min−1 in the sand-grinding sample is obtained, which is 2.40 times than that of non-sand-grinding one and superior to those of other representative lead-free perovskite piezoelectric materials. Meanwhile, the sand-grinding sample has remarkable bactericidal properties against Escherichia coli and Staphylococcus aureus. Superior piezo-catalytic activities originate from the enhanced electron-hole pair separation and the increased carrier concentration. This study provides a novel method for improving the piezo-catalytic activities of lead-free piezoelectric materials and holds great promise for harnessing natural energy and disease treatment. 相似文献
79.
Xiaolin Tian Licheng Jiao Ying Duan Xiaohua Zhang 《Signal, Image and Video Processing》2014,8(5):901-912
Many video denoising methods originated from methods designed for processing static two-dimensional images. Videos would be processed frame by frame, a process with a relatively high computational complexity, without taking into account the correlation information between frames. In this paper, a video denoising method using coefficient shrinkage and threshold adjustment based on Surfacelet transform (CSTA-ST) is proposed, which processes multiple frames of a video as an ensemble. Spatial correlation is used to define a weighted spatial energy. Each Surfacelet transform (ST) coefficient has a corresponding estimated energy value, in which the ST coefficients are grouped by. The similarity of the ST coefficients in a group determines the threshold of each ST coefficient. In addition, according to the neighborhood information of ST coefficients, the threshold is adjusted by a threshold adjustment factor. The coefficient shrinkage parameter is determined based on the adjusted threshold, and the ST coefficients are shrunk. Finally, the denoised video is obtained by the inverse ST using the shrunk coefficients. In experiments, video sequences with noise are tested, and the denoised results of the proposed method are compared with that of current denoising methods. The experimental results show that the proposed method significantly improves the peak signal-to- noise ratio (PSNR) and the structural similarity (SSIM) for various levels of noise and motion, and the ideal denoised visual effect is obtained. 相似文献
80.
本文先介绍了分支线正交定向耦合器的概念与工作原理;然后根据该原理在ADS2009软件下设计仿真了工作在Ka波段的微带线定向耦合器,并对Ka波段的耦合器模型进行了改良,使之实际面积缩小的同时能达到原有的性能。 相似文献