固载于SBA-15分子筛中的同双核金属配合物催化剂

合成了3种同双核金属配合物[M2LCl3]Cl(L代表配体三亚乙基四胺,M代表Co,Cu,Cr),采用微波加热法合成了SBA-15分子筛,采用浸渍法将3种同双核金属配合物分别固载在表面官能化的SBA-15分子筛(SBA-15-NH2分子筛)中制得负载型催化剂。傅里叶变换红外光谱、X射线衍射、紫外可见光谱和热分析表征结果表明,同双核金属配合物被固载后,其结构仍保持完整。以环己烷氧化反应为探针反应,考察了[Co2LCl3]Cl/SBA-15-NH2,[Cu2LCl3]Cl/SBA-15-NH2,[Cr2LCl3]Cl/SBA-15-NH2催化剂的活性,环己烷转化率分别为11.0%,49.5%,57.9%;对于[Cr2LCl3]Cl/SBA-15-NH2催化剂,当分别以乙睛、丙酮和冰醋酸为溶剂时,环己烷转化率分别为57.9%,52.1%,34.2%,3次重复实验的环己烷转化率分别为57.9%,47.8%,46.5%,表明该催化剂具有较好的活性和重复使用性。     

Study of Density Behavior During LHCD and IBW Heating in the HT-7 Superconducting Tokamak

A new method using special shape parameters has been introduced to study density behavior with synergy of lower hybrid current drive (LHCD) and ion Bernstein wave (IBW) heating in the HT-7 superconducting tokamak. During the synergy of the LHCD and IBW heating an improved confinement plasma was achieved, and the electron density was increased and peaked.     

CAPP系统中工艺卡片生成过程的研究

以AutoCAD2 0 0 0为开发平台、VC + + 6 0为开发环境、ObjectARX2 0 0 0为开发工具、SQLServer为后台数据库 ,通过编写writeText、fillGykztb、fillGykjtb等自定义函数 ,生成工艺卡片 ,并实现工序内容在工艺卡片中的分页显示等功能。     

The integral representations of solutions for circular plate problems without any hold

In this article, the following results are obtained: (1) a special solution and a general solution (non-series form) for circular plate problems are given; (2) integral representations of solutions for circular plate problems without any hold with built-in edge conditions and simply supported edge conditions are found.     

新型光电混合式电流互感器设计

设计了一种光电混合式电流互感器,它由传感头、光纤传输和光电转换器、信号处理电路和工作电源4部分组成。这种结构具有绝缘性能高、可靠性强、质量小等特点,并对误差情况进行了分析。     

Efficient fine granularity scalability using adaptive leaky factor

Fine Granularity Scalability (FGS) video coding has been adopted by the MPEG-4 standard for video streaming applications. In this paper, we propose a novel FGS coding scheme, which applied adaptive leaky factors for the enhancement layer prediction to further improve the coding efficiency of FGS. A flexible method that can dynamically determine the leaky factors according to the network conditions is also presented. With the proposed method, a better trade-off between the coding efficiency and drifting reduction can be achieved, and the coding performance is further improved compared with using a fixed leaky factor. Experimental results show that the proposed method can further improve the coding efficiency over a wide range of bitrate and packet loss ratio, and still keep the original characteristics, such as fine granularity, and bandwidth adaptation.     

AOI技术在激光微孔产品检查中的应用

在过去几年里,小型PCB诸如硅芯片级以及便携式移动电话的生产者和设计者们已经发现:如果要保持自己的竞争力并具备生产高密度封装板能力,就必须采用微孔技术。微孔技术的出现要求针对微孔缺陷的有效检测手段对工艺进行过程控制。本文对激光微孔的自动光学检测进行了详细介绍。     

Effects of Process Conditions on Desalting and Demetalization of Crude Oil

The efficiency of desalting for six crude oils was studied with a SY-1 dynamic simulation experimental installation. The demulsifier DC2 was examined for 1#, 2#, and 4# crude oil and DC4 was used for 3#, 5#, and 6# crude oil. The effects of temperature, electric field gradient, dosage of demulsifier, and washing water on the desalting efficiency of six crude oils were investigated. The results showed that at the optimization process condition after desalting, the desalting efficiency and the salt content of 1# crude oil reached 89.17% and 1.92 mg/L; that of 2# crude oil reached 85.08% and 1.04 mg/L; that of 3# crude oil reached 91.06% and 1.35 mg/L; that of 4# crude oil reached 81.67% and 1.51 mg/L; that of 5# crude oil reached 81.03% and 2.32 mg/L; and that of 6# crude oil reached 86.64% and 2.67 mg/L. Different crude oils have different metal contents. Three assistants, ammonium nitrate (TJ1), nitric acid (TJ3), and polyamine carboxylate (TJ4), were used to improve the efficiencies of desalting and demetalization of six crude oils. TJ4 was more efficient in removing calcium and iron for 1# and 2# crude oil. TJ1 was more efficient in desalting and demetalizing 5# crude oil. The efficiencies for removal of calcium, iron, nickel, and vanadium respectively reached 99.89%, 98.33%, 20.58%, and 43.02%. TJ3 has better efficiency desalting and demetalizing for 6# crude oil. With the concentration of TJ3 increasing from 0 to 80 mg/L, the desalting efficiency increases from 31.22% to 73.54%, and the iron removal efficiency increases from 56.0% to 74.05%.     

Preparation and adsorption behavior of a cellulose‐based,mixed‐mode adsorbent with a benzylamine ligand for expanded bed applications

A novel mixed‐mode expanded bed adsorbent with anion‐exchange properties was explored with benzylamine as the functional ligand. The cellulose composite matrix, densified with stainless steel powder, was prepared with the method of water‐in‐oil suspension thermal regeneration. High activation levels of the cellulose matrix were obtained with allyl bromide because of the relative inertness of the allyl group under the conditions of the activation reaction. After the formation of the bromohydrin with N‐bromosuccinimide and coupling with benzylamine, the activated matrix was derived to function as a mixed‐mode adsorbent containing both hydrophobic and ionic groups. The protein adsorption capacity was investigated with bovine serum albumin as a model protein. The results indicated that the prepared adsorbent could bind bovine serum albumin with a high adsorption capacity, and it showed salt tolerance. Effective desorption was achieved by a pH adjustment across the isoelectric point of the protein. The interactions between the cell and adsorbent were studied, and the bioadhesion was shielded by the adjustment of the salt concentration above 0.1M. Stable fluidization in the expanded bed was obtained even in a 2% (dry weight) yeast suspension. The direct capture of target proteins from a biomass‐containing feedstock without extra dilution steps could be expected with the mixed‐mode adsorbent prepared in this work, and this would be especially appropriate for expanded bed adsorption applications. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008