Crystal growth and characterization of CuI single crystals by solvent evaporation technique

Cuprous iodide (CuI) crystals are grown by slow evaporation technique in three different solvents. Large CuI single crystals with dimensions of 7.5 mm × 5 mm × 3 mm are obtained in pure acetonitrile solvent at 40 °C. The as-grown crystals are analyzed by X-ray diffraction, energy-dispersive X-ray analysis, differential scanning calorimetry, current-voltage characteristic and photoluminescence spectrum. The results show that the CuI crystal has the zinc-blende structure with no secondary phase. The elemental Cu/I ratio is 1.09:1. The melting point of the crystal is 875 K and two phase transitions occur from room temperature to its melting point. The electrical conductivity of CuI platelet crystal is in the range of 1.11-2.38 Ω⁻¹ cm⁻¹. Under ultraviolet excitation, the CuI crystals exhibit three emission bands with peak positions at 426, 529 and 671 nm. The nature of the luminescence is discussed.     

珠三角港口群竞合态势及广州市现代物流业发展策略解析

阐述了现代物流业的内涵及其对区域经济发展的影响,根据珠三角现代物流业统计资料,深入剖析了珠三角现代海运物流业和现代航空物流业的竞合态势,并对广州市现代物流业发展所面临的挑战和机遇以及可能采取的发展策略进行了具体论述。     

Effects of niobium content on electrical and mechanical properties of (Na0.85K0.15)0.5Bi0.5Ti(1-x)Nb x O3 thin films

(Na_0.85K_0.15)_0.5Bi_0.5Ti_(1-x)Nb _x O₃ (NKBT-N100x) thin films were deposited on Pt/Ti/SiO₂/Si(100) substrates by metal–organic decomposition method and annealed in oxygen atmosphere at 750 °C. The effects of niobium concentration on the microstructures, ferroelectric, piezoelectric, leakage current and mechanical properties of the NKBT-N100x (x = 0, 0.01, 0.03, 0.05) thin films have been investigated in detail. The NKBT-3N thin film has the largest remnant polarization (7 μC/cm²) and statistically averaged d _33eff (140 pm/V), the smallest leakage current, elasticity modulus (102.0 Gpa), hardness (5.1 Gpa) and residual stress (297.0 Mpa). The evaluation of residual stresses of these thin films will offer useful guidelines of safe working condition for their potential application in microelectromechanical system.     

数字电视节目推荐系统结构及推荐算法研究

针对数字电视信息过载问题进行了数字电视节目推荐系统的结构和推荐算法研究。构造了包含信息摄取单元、系统分析单元和推荐信息发送单元的数字电视节目推荐系统结构。提出了节目类型分析法,采用节目类型阈值和节目类型聚类两种形式,分别实现了根据经验值的人工分级和任意簇数的自动聚类,达到了有效寻找观众收视兴趣与所观看节目之间的联系的效果。提出了收视行为分析法,采用收视个体行为分析和收视群体行为分析两种形式,通过观众收视数据推测观众收视兴趣,实现了给观众个体或群体推荐感兴趣的电视节目的目的。     

Piezoresistive Pressure Sensor Based on Synergistical Innerconnect Polyvinyl Alcohol Nanowires/Wrinkled Graphene Film

Piezoresistive sensor is a promising pressure sensor due to its attractive advantages including uncomplicated signal collection, simple manufacture, economical and practical characteristics. Here, a flexible and highly sensitive pressure sensor based on wrinkled graphene film (WGF)/innerconnected polyvinyl alcohol (PVA) nanowires/interdigital electrodes is fabricated. Due to the synergistic effect between WGF and innerconnected PVA nanowires, the as‐prepared pressure sensor realizes a high sensitivity of 28.34 kPa^?1. In addition, the device is able to discern lightweight rice about 22.4 mg (≈2.24 Pa) and shows excellent durability and reliability after 6000 repeated loading and unloading cycles. What is more, the device can detect subtle pulse beat and monitor various human movement behaviors in real‐time.     

喷涂法制备超疏水涂层及其在多种基底表面的应用研究

采用喷涂法,将硅藻土和纳米氧化铝经十六烷基三甲氧基硅烷修饰后,加入树脂液配制成喷涂液涂覆在多种基底表面,经固化后,可获得表面水静态接触角高达163.4°的超疏水表面.该涂层具有优异的拒水、耐腐蚀、减阻、油水分离、表面自清洁性及抗覆冰性能.在防水自清洁纺织品、金属表面的防腐、流体机械的减阻及电力网络的防覆冰领域均有一定的...     

Research on the structure-performance relationship of thermal reduced graphene oxide based supercapacitors

Journal of Materials Science - The electrochemical performance of RGO-based super-capacitors are highly dependent on the exfoliation and surface functionalization degree of RGO, which of them...     

Homogeneous reinforcement as a strategy for the efficient preparation of high-strength,insulating and high heat-resistant PBO composite paper

Journal of Materials Science - Poly(p-phenylene benzobisoxazole) (PBO) fibre-based specialty paper has become a promising candidate for high-performance insulating materials due to the remarkable...     

Multi-Carrier Generation in Organic-Passivated Black Silicon Solar Cells with Industrially Feasible Processes

The innate inverse Auger effect within bulk silicon can result in multiple carrier generation. Observation of this effect is reliant upon low high-energy photon reflectance and high-quality surface passivation. In the photovoltaics industry, metal-assisted chemical etching (MACE) to afford black silicon (b-Si) can provide a low high-energy photon reflectance. However, an industrially feasible and cheaper technology to conformally passivate the outer-shell defects of these nanowires is currently lacking. Here, a technology is introduced to infiltrate black silicon nanopores with a simple and vacuum-free organic passivation layer that affords millisecond-level minority carrier lifetimes and matches perfectly with existing solution-based processing of the MACE black silicon. Advancements such as the demonstration of an excellent passivation effect whilst also being low reflectance provide a new technological route for inverse Auger multiple carrier generation and an industrially feasible technical scheme for the development of the MACE b-Si solar cells.