Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

Passively Q -switched Ytterbium-Doped Double-Clad Fiber Laser With a Cr4+:YAG Saturable Absorber

A high-power and high-repetition-rate passively Q -switched ytterbium-doped single-mode double-clad fiber laser was built using a Cr⁴⁺:YAG saturable absorber (SA). Two different SAs with initial transmissions of T_omicron = 30% and T_omicron = 50% were studied. At the maximum coupled pump power of 9.8 W, an output power of 4.7 W, pulse duration of 143 ns, pulse repetition rate of 253 KHz, pulse energy of 18.5 muJ, and slope efficiency of 49% were obtained with the T_omicron = 30% SA.     

"What is in a word? No versus Yes differentially engage the lateral orbitofrontal cortex": Correction.

Reports an error in "What is in a word? No versus Yes differentially engage the lateral orbitofrontal cortex" by Nelly Alia-Klein, Rita Z. Goldstein, Dardo Tomasi, Lei Zhang, Stephanie Fagin-Jones, Frank Telang, Gene-Jack Wang, Joanna S. Fowler and Nora D. Volkow (Emotion, 2007[Aug], Vol 7[3], 649-659). The supplemental materials link should appear as follows: http://dx.doi.org/10.1037/1528-3542.7.3.649.supp. (The following abstract of the original article appeared in record 2007-11660-018.) The words "No" and "Yes" are involved in conditioning to prohibit or encourage behavior, respectively. The authors, therefore, hypothesized that these words would be attributed to endogenous valence, activating neuronal circuits involved with valence and emotional control. Functional MRI (fMRI) at 4 Tesla was used to record regional brain activity while participants were exposed to emphatic vocalizations of the words. Results showed that No and Yes were associated with opposite brain-behavior responses; while No was negatively valenced, produced slower response times, and evoked a negative signal in the right lateral orbitofrontal cortex (OFC), Yes was positively valenced, produced faster response times, and evoked a positive signal in a contiguous region of the OFC. Attribution of negative valence to No and trait anger control were associated with increased responsivity of the OFC to No. Inasmuch as sensitivity to the prohibitive command No develops during childhood through interaction with primary caregivers as the first social objects, our findings may implicate the lateral OFC in the neurobiology of emotion regulation and subsequent social development. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

新型刮刀钻头的设计及现场试验研究

在理论分析的基础上，综合PDC钻头和刮刀钻头的优点，设计了一种新型的刮刀钻头，并进行了现场试验。现场试验结果表明，该钻头运转平稳，采用低钻压、高转速，钻进速度快，井眼规则通畅，有较明显的防斜作用，该种钻头的推广应用对提高钻井工程的整体效益具有十分重要的意义。     

高压水射流射孔井眼应力数值模拟研究

水力射孔技术是一种新型完井方式,利用深穿透水力射孔技术辅助定向压裂,可实现油层改造和油井增产。考虑套管水泥环的影响,采用有限元理论结合ANSYS软件计算了高压水射流水力射孔井眼周围的应力,重点分析了水力射孔参数对井周应力的影响规律,初步研究了直井水力压裂时水力射孔对裂缝起裂的影响。计算结果表明,沿最大水平地应力方向布孔时,孔眼根部的周向拉应力最大,裂缝将会在孔眼根部起裂;选择合理水力射孔参数可有效降低地层破裂压力。研究结果可为高压水射流水力射孔辅助定向压裂提供参数优选的依据。     

铣制三元流叶轮时产生误差的原因分析及解决方法

对在五坐标数控加工中心上铣制三元流叶轮时出现的叶轮附面尺寸误差问题，进行了详细分析，并提出了问题的解决方法，有效地避免了加工中产生的超差。     

SQL性能优化——表连接的分析

介绍两个表连接的几种常用方式和不同方式的内部机制.在比较3种不同表连接方式的优缺点基础上,选择一种好的方式来优化表连接,以提高查询速度,并结合中国邮政报刊发行系统数据库开发中遇到的生产实际,分析3种表连接方式的优劣.     

液晶光阀光电导层光吸收系数的研究

用化学气相沉积法制备了液晶光阀中光电导层———非晶硅薄膜,从实验中得出最佳制备工艺的参数取值。给出了用包络线法测量非晶硅薄膜光吸收系数的原理,测量了样品的光吸收系数随波长的变化规律。得到样品在最佳工艺条件下的光吸收系数高于1×103cm-1。     

行政权力腐败的模型分析及治理对策

腐败是与政府行政权力相伴生的痼疾，既是一个历史现象又是一个国际现象。贪污腐败和寻租腐败是委托一代理模型中最典型的腐败方式，文章在此基础上对贪污腐败和寻租腐败进行成本一收益分析和市场均衡分析，并探讨治理行政权力腐败的有效途径。     

基于Delphi的报童模型的实现与动态仿真

已往库存论中的决策模型,它是把现实过程用数学的方法进行分析,得到决策值,但不能看到决策的过程,不能反映出现实生活中的不确定性、动态性。运用Delphi 7.0和SQL server 2000对销售过程进行了动态仿真,利用Newsboy模型的推广(S,s)订购策略来监控库存并做出决策,这样就体现出此过程的不确定性、动态性;且举出了一个仿真商品销售的实例,对其中的一些关键技术,如何仿真、算法的实现等进行了阐述。