A Two‐Stage Annealing Strategy for Crystallization Control of CH3NH3PbI3 Films toward Highly Reproducible Perovskite Solar Cells

The solvent‐engineering method is widely used to fabricate top‐performing perovskite solar cells, which, however, usually exhibit inferior reproducibility. Herein, a two‐stage annealing (TSA) strategy is demonstrated for processing of perovskite films, namely, annealing the intermediate phase at 60 °C for the first stage then at 100 °C for the second stage. Compared to conventional direct annealing temperature (DHA) at 100 °C, using this strategy, MAPbI₃ films become more controllable, leading to superior film uniformity and device reproducibility with the champion device efficiency reaching 19.8%. More specifically, the coefficient of variation of efficiency for 49 cells is reduced to 5.9%, compared to 9.8% for that using DHA. The TSA process is carefully studied using Fourier transform infrared spectroscopy, X‐ray diffraction, and UV–vis absorption spectroscopy. It is found that in comparison with DHA the formation of hydrogen bonding and crystallization of perovskite are much slower and can be better controlled when using TSA. The improvements in film uniformity and device reproducibility are attributed to: 1) controllable MAPbI₃ crystal growth stemming from the progressive formation of hydrogen bonding between methylammonium and halide; 2) suppression of intermediate phase film dewetting, which is believed to be due to its decreased mobility at the initial low‐temperature annealing stage.     

Graphene oxide-decorated Fe<Subscript>2</Subscript>(MoO<Subscript>4</Subscript>)<Subscript>3</Subscript> microflowers as a promising anode for lithium and sodium storage

Mixed transition metal oxides (MTMOs) have received intensive attention as promising anode materials for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). In this work, we demonstrate a facile one-step water-bath method for the preparation of graphene oxide (GO) decorated Fe₂(MoO₄)₃ (FMO) microflower composite (FMO/GO), in which the FMO is constructed by numerous nanosheets. The resulting FMO/GO exhibits excellent electrochemical performances in both LIBs and SIBs. As the anode material for LIBs, the FMO/GO delivers a high capacity of 1,220 mAh·g^–1 at 200 mA·g^–1 after 50 cycles and a capacity of 685 mAh·g^–1 at a high current density of 10 A·g^–1. As the anode material for SIBs, the FMO/GO shows an initial discharge capacity of 571 mAh·g^–1 at 100 mA·g^–1, maintaining a discharge capacity of 307 mAh·g^–1 after 100 cycles. The promising performance is attributed to the good electrical transport from the intimate contact between FMO and graphene oxide. This work indicates that the FMO/GO composite is a promising anode for high-performance lithium and sodium storage.

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Fabrication of Titanium Aluminides via Powder-Cored Wire Arc Additive Manufacturing: Microstructural and Mechanical Characterization

Herein, an innovative powder-cored wire arc additive manufacturing (PC-WAAM) process is proposed to fabricate γ-TiAl thin-walled intermetallic alloy. The metallography, phase composition, and mechanical properties at different thin-wall locations are characterized. The results show that the alternatively distributed layer-like microstructure composed of α₂ (Ti₃Al) and γ (TiAl) phases is obtained along the building direction. The content of α₂ phase exhibits the tendency of decreasing from the bottom to top region. This unique microstructure characteristic is closely related to the typical thermal cycling history during deposition. Moreover, the tensile strength and microhardness of the top region are lower than the middle and bottom region. In general, the current PC-WAAM technique shows promising capability of fabricating γ-TiAl intermetallic alloy with low cost. This work becomes a valuable reference for understanding the evolution mechanism of microstructure and paves the way for the flexible and customized additive manufacturing of γ-TiAl alloy.     

Computational Parametric Analysis of Cellular Solids with the Miura-Ori Metamaterial Geometry under Quasistatic Compressive Loads

Origami-based metamaterials have widespread application prospects in various industries including aerospace, automotive, flexible electronics, and civil engineering structures. Among the wide range of origami patterns, the fourfold tessellation known as Miura-ori is of particular attraction to engineers and designers. More specifically, researchers have proposed different 3D structures and metamaterials based on the geometric characteristics of this classic origami pattern. Herein, a computational modeling approach for the design and evaluation of 3D cellular solids with the Miura-ori metamaterial geometry which can be of zero or nonzero thicknesses is presented. To this end, first, a range of design alternatives generated based on a numerical parametric model is designed. Next, their mechanical properties and failure behavior under quasistatic axial compressive loads along three perpendicular directions are analyzed. Then, the effects of various geometric parameters on their energy absorption behavior under compression in the most appropriate direction are investigated. The findings of this study provide a basis for future experimental investigations and the potential application of such cellular solids for energy-absorbing purposes.     

Experimental study on fitness of one-piece casting osseointegrated implant frameworks with relation to fixture abutment positions

An experiment on fitness of one-piece casting osseointegrated implant frameworks was performed among three fixture abument positions where other conditions were controlled. The result revealed that there was statistically significant differences in dimensional change among the three fixture abument positions. In terms of the relation between abument position and fitness, the more backward the abument position was, the worse the osseointegrated framework fitness was. The frameworks showed deformations in "arch form" and "warp" in three dimensions.     

从法律视角看网络泄密

随着互联网用户的剧增,网络安全成为困扰中国互联网健康发展的重要问题之一。与此同时,日趋严重的网络泄密问题已逐渐成为与黑客入侵、病毒袭击、垃圾邮件、流氓插件并行的第五大网络安全隐患．从法律角度来看,网路泄密实质上是对网络隐私权的侵犯,笔者通过对网路隐私权的分析,从现行法律制度与未来法律制度来解读网络泄密。     

Theory and techniques of data mining in CGF behavior modeling

For the large quantity of data,rules and models generated in the course of computer generated forces (CGFs) behavior modeling,the common analytical methods are statistical methods based on the tactical rules,tactical doctrine and empirical knowledge.However,from the viewpoint of data mining,we can find many of these analytical methods are also each-and-every different data mining methods.In this paper,we survey the data mining theory and techniques that have appeared in the course of CGF behavior modeling f...     

嵌入式水电气在线遥监控系统研究

该文介绍了一个基于CNA总线的嵌入式Web监控水、电、气在线遥控监控系统的架构方案,重点阐述其监控水、电、气管理系统的设计思路,对其中涉及的关键技术进行了较为详细的叙述。     

Direct raycasting of unstructured cell-centered data by discontinuity Roe-average computation

In the field of computational fluid dynamics (CFD), the upwind finite volume method (FVM) is widely applied to solve 3D flows with discontinuity phenomena (e.g., shock waves). It produces unstructured data at the center of each cell (cell-centered data) with the flow discontinuity constraint on the inner-face between face-neighboring cells. For visualization, existing approaches with interpolation usually pre-extrapolate cell-centered data into cell-vertexed data (data values given at cell vertices) and only handle cell-vertexed data during actual rendering, which unconsciously depress the rendering accuracy and violate the discontinuity constraint. In this paper, we propose a novel method to visualize cell-centered data directly avoiding extrapolation and keep the discontinuity in the rendering data on the framework of multi-pass raycasting. During resampling, the field is reconstructed using the original cell-centered data value and the cell-gradient estimated by Green–Gauss theorem. To keep the discontinuity, we reconstruct the field at an inner-face resampled point using both the face-adjacencies and get two discontinuous field values. Then the field is obtained by computing Roe-average of the two. The analysis and experiments demonstrate that our approach gains a high-accuracy reconstruction and leads to a high-quality image.