Phase transition of lithiated-spinel Li2Mn2O4 at high temperature

1 Introduction Lithium manganese oxides are the most attractive cathode materials for rechargeable lithium-ion batteries because of their low-cost and less toxicity when compared with either cobaltates or nickelates[1?3]. Among these oxides, the spinel-fr…     

Calculation of cooling rate of amorphous aluminum alloy melt-spun ribbons

Based on the heat transfer theory and liquid solidification theory, the heat transfer during the rapid solidification process of amorphous ribbons prepared by melt spinning was approximately modeled by one-dimensional heat conduction equation. Besides, integration with the temperature gradient, the relationship between the ribbon thickness and solidification time was derived according to the boundary conditions of ribbon-copper wheel. A simply theoretical model was obtained to calculate the cooling rates of aluminum amorphous ribbons. According to the above theoretical model, the critical cooling rate of aluminum amorphous ribbons by melt spinning is above 10^6 K/s, which proves that the aluminum based alloys belong to the marginal glass forming ability of alloys. The calculated results are in good agreement with other estimated values reported previously.     

气缸低速运动摩擦力模型的研究

对气缸摩擦力进行了全面和深入的分析，通过仿真模拟和实验拟合，提出了符合气缸低速运动摩擦特性的模型——指数函数模型。结果表明，采用该摩擦力模型，气缸运动的仿真模型精度更高，能够更好地描述气缸低速运动过程，对于气缸优化设计和气缸正常使用具有参考价值。     

电感电容损耗电阻的讨论

通过对电容电感阻抗的测量，发现实验值偏离理论值。定性地分析了误差的来源，得出的结论是电感电容内部的损耗电阻随着频率的变化而变化，变化方向相反而并非相同。     

义齿CAD/CAM系统中标准牙冠数据库的建立

CAD／CAM技术应用广泛，将其应用于口腔修复学中则是一个全新的课题。文章结合标准牙冠数据库的建库实践，从设计与制造技术层面上阐述了义齿CAD／CAM系统中标准牙冠数据库建立的过程，主要包括：利用三维机械式扫描仪扫描全口牙列28颗标准牙冠模型、利用图形处理软件对获得的数据进行处理、重建牙冠三维曲面模型，并根据国人恒牙统计数据调整模型。从而建立了具有标准解剖形态的牙冠图形数据库(动态)，并可以通过调整模型，使模型在任意方向产生位移，旋转和形变。文章最后指出数据库的建立为后阶段义齿的计算机辅助设计和制造(CAD／CAM)打下了基础。     

Magnetic and mechanical properties of FeSi alloys with high Si content

The chemical vapor（CVD） deposition-diffusion method was applied to prepare FeSi alloys with high silicon content up to 6.5%. In spite of various deposition and post-annealing, the sample remains α-Fe bcc structure. The cross section of the composition was analyzed to evaluate the Si content and distribution before and after annealing. The results show that the soft magnetic properties are improved by increasing the silicon content. For the samples containing about 6.5% Si, the coercivity decreases to 60 from 237.3 A/m of the original. It is also obtained that, in addition to the Si content, Si distribution has a large influence on the core loss due to the effect of resistivity. The micro-hardnesses were also evaluated along the cross-section after various annealings.     

Preparation of alumina-doped yttria-stabilized zirconia nanopowders by microwave-assisted peroxyl-complex coprecipitation

Alumina-doped yttria-stabilized zirconia （ADYSZ） nanopowders were prepared by microwave-assisted peroxyl-complex coprecipitation （MAPCC） using ZrOCl2-8H2O, Y2O3 and AICly6H2O as starting materials, NH2-H2O as precipitant and H2O2 as complexant. The effects of adding H2O2 and microwave drying on the preparation and properties of ADYSZ were investigated. The precursors and nanopowders were studied by EDX, XRD, SEM and TEM techniques. The results show that the uniformity of component distribution within ADYSZ nanopowders is improved by adding appropriate dosage of H2O2. Complexing reaction between H2O2 and Zr^4＋ ion restrains the hydrolyzation and precipitation of Zr^4＋ ion. With the addition of H2O2, Al^3＋, y^3＋ and Zr^4＋ ions can be precipitated synchronously in a relatively narrow range of pH value. H2O2 also improves the filterability of the wet precipitate. The highly hydrophilic precipitates can be quickly and effectively separated from aqueous solution. During microwave drying process, the moisture of wet precursors is selectively heated. Quick expansion of steam vapor within the wet colloidal particles causes the aggregations burst into numerous tiny lumps. Compared with oven drying, microwave drying can not only shorten drying time but also reduce aggregation intensity of the resultant ADYSZ nanopowders.     

碳纳米管承载氧化锆纳米粒子的研究

在液相沉淀法制备超细粉的工艺中引入碳纳米管，作为ZrO2的承载体。TEM观察发现添加表面活性剂可以实现碳纳米管对ZrO2的有效承载，未加表面活性剂出现了两者的分离。液相中Zeta电位分布的变化表明表面活性剂的添加有利于碳纳米管在水相中的分散，对工艺机理的研究揭示了表面活性剂其疏水基吸附在碳纳米管表面，而其亲水基与ZrO2水合物结合，在碳纳米管承载氧化锆纳米粒子复合材料制备中起到了桥接作用。