水溶性氨基丙烯酸漆的研制

研制了高温烘烤 (145～ 15 0℃ )和中温烘烤 (12 0～ 12 5℃ )两种水溶性氨基丙烯酸漆。当羟基树脂的玻璃化温度为 - 5～ 0℃ ,丙烯酸和丙烯酸羟乙酯占总单体的质量分数分别为 7 5 %～ 8 5 %和 8 0 %～ 12 0 % ,羟基树脂和氨基树脂的质量比为 (0 0 5∶1 0 0 )～ (0 10∶1 0 0 ) ,颜基质量比为 0 2 9∶1 0 0时 ,两种漆的附着力达到 1级 ,抗冲击强度 >490N·cm ,柔软性 <1mm ,硬度 >2H ,光泽度 >80 (45℃ ) ,耐水 (2 0～ 2 5℃ ) 1d以上 ,遮盖力及施工性能良好     

纸制备SiC/Si层状陶瓷复合材料的微观结构和性能

本文以纸为原料,通过叠层设计、低温碳化和高温渗硅制备了具有层状结构特征的SiC/Si陶瓷复合材料。并采用XRD、SEM和三点弯曲等分析测试手段对其相组成、微观结构和力学性能进行了分析。结果表明:纸碳化后为非晶形的碳;渗硅后试样的相组成为β-SiC相、自由Si相和残C相。叠层纸碳化后的微观结构为含有大量扁长空洞的碳骨架,渗硅后得到的SiC陶瓷复合材料具有明显的层状结构特征。三点弯曲实验表明,SiC/Si陶瓷复合材料的强度高达290MPa,达到了常规反应烧结SiC陶瓷的强度水平;且其断裂方式为非灾难性断裂,分析认为这与材料的层状结构形貌有关。     

环境因子对破乳优势菌生长的影响

从油田油泥中富集、培养筛选出两株具有破乳活性的优势菌，并对影响破乳菌生长的主要环境因素进行了试验研究。试验表明：这两株破乳优势菌的最佳生长周期为60～72h，最佳温度为30℃左右，最佳pH值为6-8之间。     

天然橡胶不同硫化体系磨耗微观结构的研究

通过对天然橡胶不同硫化体系硫化胶磨耗前后的红外光谱分析，得知常温下硫化胶的磨耗历程是具有氧化反应的力化学反应，单，双硫键较多的硫化胶具有较好的耐磨性。     

Mathematical model of shear rate of polymer melt dynamic extruding through capillary

With superimposing a sine vibration of displacement on the extruding direction of a polymer melt, the characterization formula of the shear rate of a polymer melt within a capillary was set up. By making use of the experimental equipment of a constant velocity type dynamic rheometer of capillary (CVDRC) designed by the authors, the calculating steps of the shear rate of the polymer melt at the wall of the capillary under a vibration force field were established. Through measuring and analyzing the instantaneous data of capillary entry pressure, capillary volume rate, and their phase‐difference under the superimposed vibration, the polymer melt's shear rate at the wall of the capillary can thus be calculated. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1056–1061, 2005     

MgO－B_2O_3－SiO_2系晶化分形的计算机模拟

采用两段热处理技术，利用Ｘ射线衍射分析、扫描电镜观察等方法研究广２ＭｇＯ－Ｂ＿２Ｏ＿３－ＳｉＯ＿２系的晶化过程，晶化析出相２ＭｇＯ·Ｂ＿２Ｏ＿３的微观形貌具有分形特征，采用密度－密度相关函数法计算其分形维数为１．６３。为揭示２ＭｇＯ·Ｂ＿２Ｏ＿３生长机制，采用Ｍｏｎｔｅ－Ｃａｒｌｏ方法及改进的ＤＬＡ模型对分形生长过程进入计算机模拟。模拟结果与实际分形结构、分形维数相符，表明２ＭｇＯ·Ｂ＿２Ｏ＿３生长是扩散控制凝聚过程。可以预见，分形理论与计算机模拟相结合，将会在探讨未知机理方面发挥重要作用。     

The Torque Transmission Capabilities of the Adhesively-Bonded Tubular Single Lap Joint and the Double Lap Joint

With the wide application of fiber-reinforced composite materials in aircraft, space structures and robot arms, the design and manufacture of composite joints have become a very important research area because they are often the weakest areas in composite structures.

In this paper, the stress and torque transmission capabilities of the adhesively-bonded tubular single lap joint and the double lap joint were experimentally tested. In order to compare the experimental results with the calculated results, the stress and torque transmission capabilities were analyzed by the 3-dimensional finite element method taking into consideration the nonlinear properties of the adhesive.

From the experiments it was found that the torque transmission capabilities of the adhesively-bonded double lap joint was 2.7 times as large as that of the single lap joint. Also, it was found that the fatigue limit of the double lap joint was 16 times as large as that of the single lap joint.     

Synthesis and dielectric properties of polystyrene‐clay nanocomposite materials

Polystyrene‐clay nanocomposite (PsCN) materials were synthesized and their properties of crystallinity, thermal behavior, and dielectric characteristics were investigated. A polymerizable cationic surfactant, [2‐(dimethylamino)ethyl]triphenylphonium bromide, was used for the intercalation of montmorillonite (MMT). The organophilic MMT was prepared by Na⁺‐exchanged MMT and ammonium cations of a cationic surfactant in an aqueous medium. Organophilic styrene monomers were intercalated into the interlayer regions of organophilic clay hosts followed by a free‐radical polymerization. Exfoliation to 2 wt % MMT in the polystyrene (PS) matrix was achieved as revealed by X‐ray diffraction (XRD) and transmission electron microscopy (TEM). Thermal properties by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were also studied. The dielectric properties of PsCNs in the form of film with clay loading from 1.0 to 5.0 wt % were measured under frequencies of 100 Hz–1 MHz at 25–70°C. A decreased dielectric constant and low dielectric loss were observed for PsCN materials. The dielectric response at low frequency that originated from dipole orientation was suppressed due to the intercalation of clay materials. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1368–1373, 2004     

单纯形法中确定主元素的两个新法则

给出了单纯形法中确定主元素的两个新法则,即"按使目标函数值增加得最多的原则确定主元素"和"按使目标函数值增加得最快的原则确定主元素",并以实例说明了应用这两个法则来确定主元素较应用"最大口法则"来确定主元素.具有迭代次数更少、收敛速度更快的特点.     

替硝唑在水溶液中溶解度的实验测定及关联

通过自制的固一液平衡装置,采用高效液相色谱法分别测定了温度在278.15～31.815 K时替硝唑在纯水、5%葡萄糖溶液和0.9%氯化钠溶液中的溶解度,并对实验数据分别采用理想溶液模型和经验方程进行了关联.对于纯水体系和0.9%氯化钠溶液体系,实验数据用理想溶液模型关联能较满意地表征实验结果.两种关联方法中,经验方程能较好地关联所测得的溶解度数据,误差较小.