Fabricating Water-Insoluble Polyelectrolyte into Multilayers with Layer-by-layer Self-assembly

Summary A water insoluble azo-containing polyelectrolyte (PEAPB6P-AC) was successfully fabricated into multilayer films based on the layer-by-layer adsorption technique by using N, N-dimethylformamide (DMF) as the assembling media. The multilayer growth and structure were studied with UV-vis spectroscopy, and the multilayer surface were imaged with Atomic Force Microscopy and compared with that fabricated in water. The results show that assembling PEAPB6P-AC in DMF can effectively eliminate the hydrophobic aggregation of the azo units and consequently results in a much smoother multilayer surface than that fabricated in water. This improvement to the layer-by-layer adsorption technique, which can avoid some major difficulties faced when assembling hydrophobic polyelectrolytes in aqueous solutions, seems to be a versatile way to fabricate high quality multilayer films when using the hydrophobic even water-insoluble polyelectrolytes as assembling units.     

Studies on membrane formation mechanism by the light transmission technique. I

New parameters, light transmission rate and minimum light transmissions, are proposed. These two parameters reflect the characteristics of the membrane‐forming system and the formation process of the membranes by phase inversion. The relationship between the light transmission and the porous structure of the membrane can be explained by the geometrical optics principles. Variation of the two parameters combining Reuvers's phase separation theory provided a convenient analytical method to predict effectively membrane morphologies. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 174–181, 2003     

Fabrication and amplification of Rhodamine B‐doped step‐index polymer optical fiber

A step‐index polymer optical fiber (SI POF) containing Rhodamine B in poly(methyl methacrylate) (PMMA) has been fabricated by a preform technique. Fluorescence of different fiber lengths were observed and discussed. A high gain (23 dB) for a SI POF with 60‐cm length, 400‐μm diameter was obtained. The Rhodamine B content of the doped SI POF is 5 ppm‐wt. The signal wavelength providing the highest gain for a 60 cm SI POF is around 630 nm, and the optimum fiber length is about 60 cm at 10 kW launched pump power. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 681–685, 2004     

干法/半干法高效脱硫吸附剂的制备研究

干法／半干法脱硫因占地小、投资小、费用低，能达到中等程度的脱硫效率而受到关注。脱硫剂影响脱硫效率的重要因素，Ca(OH)2作为一种优良的脱硫吸附剂，早已受到人们的重视。本文以比表面积为参数评价脱硫剂性能的优劣，研究选择制备高效脱硫剂的工艺方法。     

气体控制参数对气体辅助成型产品翘曲的影响

从气体辅助注射成型工艺的角度探讨了气体的延迟时间和第一段压力这两个关键的参数对槽的影响进而对产品翘曲变形的影响，结果表明：虽然通过使用气体辅助注射成型技术能改善产品变形，但并不能完全消除变形；造成产品变形的原因和机理十分复杂，只有进行从设计到工艺的全方位考察才能有效的控制变形，气体手指效应也是造成产品变形的一个重要因素，工艺上可以通过调整延迟时间和气体压力来减小产品的变形量。     

Telerobot-enabled HUB-CI model for collaborative lifecycle management of design and prototyping

The HUB-CI model is investigated in a telerobotic system in a client/server network to manage the lifecycle of engineering design and prototyping. The purpose of this platform is to support collaborative engineering design and proof of concept to enhance distributed team collaboration and resource utilization. The suggested platform is exemplified in two collaboration support tools and a physical prototyping platform. Structured Co-Insight Management is developed to support innovative idea exchanges and the consensus decision-making during the design process. Conflict/error detection management helps preventing conflicts and errors during the lifecycle of design and development. Physical collaboration over the network occurs when a team controls the telerobot operation during prototyping and testing in design cycles. A pilot system is implemented with a group project for the design of an electronic circuit (including both hardware and software designs). The functional assessment method is used to compare this platform to other collaborative design tools. The system presented offers unique qualitative advantages as an integrated collaboration support system.     

基于PLC的水泥生料配料控制系统研究

1 率值控制工艺结构 衡量生料质量的标准是水泥的三个率值．石灰石饱和系数KH、硅酸率SM、铝氧率IM，即在出磨生料中，、Fe2O3、Al2O3、SiO2诸氧化物的百分比含量必须满足以下二三式：     

Preparation of phenolic resin derived 3-D ordered macroporous carbon

Three-dimensionally ordered long-range macroporous carbon structures were prepared using commercially available phenolic resin by utilizing sacrificial colloidal silica crystalline arrays as templates that were subsequently removed by HF etching after pyrolysis in an argon atmosphere. SEM, TEM, and BET were employed to characterize the morphology and the surface area of the porous carbon structures. The pore size (150–1000 nm) and BET surface area, which reflect pore volume (298.6 m²/g (1.32 cm³/g) ∼ 93.7 m²/g (0.12 cm³/g)), of the macroporous carbon structures produced were approximately proportional to the size (150–1000 nm) of the sacrificial silica sphere templates used (annealing temp. 550°C). The achieved 550 nm porous carbon structures were examined to function as potential catalyst carriers and were successfully impregnated with Ag or Pt-Ru on their inner walls after borohydride reduction at room temperature. In addition, porous carbon patterns were fabricated using the ‘micromolding in capillary’ technique, which has potential applications in the microreaction technology.     

心理资本前因变量研究

采用心理资本问卷对分别属于医药、建筑、水利工程、电信、通讯运营和服务行业的6家企业的员工进行了调查.根据对回收的283份有效问卷的统计分析,认为员工的性别、受教育程度和所在企业的性质对员工心理资本不会产生显著性影响,而员工年龄的影响显著,50岁以上员工的总体心理资本水平高于其他年龄段员工.