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Yuling Liu Shuhong Liu Cong Zhang Yong Du Jiong Wang Yiwei Li 《Journal of Phase Equilibria and Diffusion》2017,38(2):121-134
The Cu-Zr binary system is re-investigated via experiment and thermodynamic modeling. Four alloys were prepared by arc melting in order to check the controversial phase equilibria reported in the literature. Both as-cast and annealed alloys were examined by optical microscopy, x-ray diffraction and electron probe microanalysis, and the phase transformation temperatures were measured by differential scanning calorimetry. The intermetallic compounds, Cu24Zr13, Cu2Zr and Cu5Zr8, were demonstrated to be not the stable phases. Based on the literature information and present experimental data, the Cu-Zr system was critically evaluated by means of CALculation of PHAse Diagram approach. A set of self-consistent thermodynamic parameters was obtained, and the calculated phase diagram and thermodynamic properties are in a satisfactory agreement with the experimental data. 相似文献
125.
In this report, a combination of the diffusion multiple technique and the recently developed pragmatic numerical inverse method was employed for a high-throughput determination of interdiffusivity matrices in Co-Cr-FeMn-Ni high-entropy alloys (HEAs). Firstly, one face-centered cubic (fcc) quinary Co-Cr-Fe-Mn-Ni diffusion multiple at 1373 K was carefully prepared by means of the hot-pressing technique. Based on the composition profiles measured by the field emission electron probe micro analysis (FE-EPMA), the composition-dependent interdiffusivity matrices in quinary Co-Cr-Fe-Mn-Ni system at 1373 K were then efficiently determined using the pragmatic numerical inverse method. The determined interdiffusivities show good agreement with the limited results available in the literature. Moreover, the further comparison with the interdiffusivities in the lower-order systems indicates the sluggish diffusion effect in Co-Cr-Fe-Mn-Ni HEAs, which is however not observed in tracer diffusivities. In order for the convenience in further analysis, a generalized transformation relation among interdiffusivities with different dependent components in multicomponent systems was finally derived. 相似文献
126.
Yb_2O_3纳米晶的制备及其若干性质的研究 总被引:5,自引:1,他引:5
用溶胶 -凝胶法制备了不同粒径的 Yb2 O3纳米晶。XRD分析表明 :所合成的 Yb2 O3纳米晶属于立方晶系 ,空间群为 Ia3。TEM分析表明 :所合成的 Yb2 O3粒子基本呈球形。计算表明 :Yb2 O3的平均晶粒度随焙烧温度的升高而增大 ,而平均晶格畸变率随焙烧温度的升高和晶粒度的增大而减小 ,表明晶粒越小 ,晶格畸变越大 ,微晶发育越不完整。溶解性试验表明 :Yb2 O3晶粒度减小 ,表面活性增加。FTIR光谱分析表明 :纳米 Yb2 O3比普通的 Yb2 O3具有更高的表面活性 ,Yb- O键的吸收强度减弱 ,有微小的蓝移。 相似文献
127.
T. Karthikeyan Arup Dasgupta S. Saroja M. Vijayalakshmi 《Journal of Materials Engineering and Performance》2005,14(2):241-248
The successful replacement of the present generation of corrosion-resistant materials (nitric acid-grade stainless steel and
Ti) by Ti-5Ta-1.8Nb, which has better corrosion resistance, depends on its weldability characteristics. This article presents
the results of a study on the fabrication, qualification, and microstructural characterization of the welds. Welding was carried
out using the direct current electrode negative (DCEN) polarity tungsten inert gas (TIG) (manual) welding method with high-purity
Ar shielding. Testing was carried out as per the ASME standard (section IX, welding and brazing). Qualification tests found
that the weldment met the required properties. The weldment showed heterogeneous microstructures, which are rationalized based
on differences in phase transformation mechanisms that are dictated by the thermal cycles experienced by various microscopic
regions. The results, described in this article, confirm that the weldability of the developmental Ti-Ta-Nb alloy is excellent.
A preliminary evaluation of the corrosion behavior of the welds showed rates comparable to that of the base metal, establishing
that this alloy could be considered as an alternative material for use in highly corrosive environments. 相似文献
128.
Aluminium corrosion is a significant concern in the aqueous chemical environment of the reactor containment building following a hypothetical loss-of-coolant accident (LOCA) at a nuclear power plant. Aluminium corrosion may lead to the formation of precipitates that can, in combination with insulation debris, block the recirculation sump screens. This study investigated aluminium corrosion experimentally at both bench and pilot scale under conditions representative of several types of nuclear power plants. Evidence of corrosion was determined using aqueous concentrations measured with inductively-coupled plasma (ICP) spectrometry and surface examinations using scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray photoelectron spectrometry (XPS), X-ray fluorescence (XRF), and X-ray diffraction (XRD). Corrosion proceeded slowly at pH near 7, but more rapidly at higher pH when the representative pipe insulation material was fibreglass. However, when calcium silicate pipe insulation was introduced into the system, corrosion became insignificant even at pH values near 10. Experimental evidence indicates that the calcium silicate insulation released a significant amount of silicate to the solution. Silicate formed a passivation layer composed of Al2OSiO4 with a thickness of more than 10 nm, and this layer effectively inhibited corrosion. 相似文献
129.
Large-scale single-crystalline SnO2 nanocauliflowers were successfully synthesized using a hydrothermal growth method without any template. The samples were
characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy
(EDS), transmission electron microscopy (TEM), and selected area electron diffraction (SAED). FE-SEM images show that the
as-grown SnO2 nanocauliflowers are constructed of tetragonal prisms with a width of 500–600 nm. XRD, EDS, and SAED results indicate that
the as-grown SnO2 nanocauliflowers are single crystalline with the tetragonal rutile crystalline structure. The growth mechanism of SnO2 nanocauliflowers is also preliminarily discussed on the basis of different Sn(OH)62− concentrations, and it is found that Sn(OH)62− concentration plays an important role in determining the shape of the prepared SnO2. Room temperature photoluminescence was further carried out on SnO2 nanocauliflowers to investigate their optical properties. An intense blue luminescence centered at a wavelength of 424 nm
is observed in the as-grown SnO2 nanocauliflowers. 相似文献
130.
For the multi-item and small lot size production mode and single machine job shop scheduling sequence independent setup time, many setup times are difficult to estimate accurately, which influences the ability to achieve accurate production cycles and costs of products. The survey shows that the length of the setup time depends on the level of employee’s knowledge. Therefore, a method for determining the standard setup time quota based on the level of employees’ knowledge is proposed. First, an evaluation index system for the level of employee’s knowledge is built; the level of employee’s knowledge is estimated by the masses and experts fuzzy comprehension evaluation and entropy method. Second, the range and definition of the level of employees’ knowledge index are developed. Third, the relational model of the employee’s knowledge level and the level of employees’ knowledge index is constructed through the least squares method. Finally, an example application is presented to verify the feasibility and effectiveness of the proposed model. 相似文献